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    Friedel-crafts preparation of aromatic ketones with an inoganic salt controlling agent
    4.
    发明授权
    Friedel-crafts preparation of aromatic ketones with an inoganic salt controlling agent 失效
    弗里德尔工艺制备芳香酮与无机盐控制剂

    公开(公告)号：US5068447A

    公开(公告)日：1991-11-26

    申请号：US550246

    申请日：1990-07-06

    申请人： Heinrich C. Gors ,  Patrick J. Horner ,  Viktors Jansons

    发明人： Heinrich C. Gors ,  Patrick J. Horner ,  Viktors Jansons

    IPC分类号： C07C45/46 ,  C07C45/47 ,  C07C49/813 ,  C07C49/84

    CPC分类号： C07C45/47 ,  C07C45/46 ,  C07C49/813 ,  C07C49/84

    摘要： Aromatic carbonyl compounds, in particular arylene ether ketones, are prepared by reacting an appropriate reagent system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and an inorganic salt controlling agent, for example, lithium chloride, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all para-linked arylene ether ketones as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution.

    摘要翻译： 芳族羰基化合物，特别是亚芳基醚酮，通过在游离路易斯酸和路易斯酸例如三氯化铝与无机盐控制剂例如锂之间的络合物存在下使适当的试剂体系反应来制备 氯化物和任选的稀释剂，例如二氯甲烷。 该方法对于制备基本上或全部对联的亚芳基醚酮是特别有利的，因为路易斯酸/路易斯碱配合物的存在显着降低烷基化并确保基本上不存在邻位取代。

    Preparation of poly(arylene ether ketones)
    5.
    发明授权
    Preparation of poly(arylene ether ketones) 失效
    聚（亚芳基醚酮）的制备

    公开(公告)号：US4698393A

    公开(公告)日：1987-10-06

    申请号：US922781

    申请日：1986-10-23

    申请人： Viktors Jansons ,  Heinrich C. Gors ,  Stephen Moore ,  Robert H. Reamey ,  Paul Becker

    发明人： Viktors Jansons ,  Heinrich C. Gors ,  Stephen Moore ,  Robert H. Reamey ,  Paul Becker

    IPC分类号： C08F4/00 ,  C08G61/12 ,  C08G67/00 ,  C08L65/00 ,  C08F293/00

    CPC分类号： C08G67/00 ,  C08G61/127 ,  C08L65/00

    摘要： The preparation of poly(arylene ether ketones) by Friedel-Crafts polymerization, in the presence of a Lewis acid catalyst and a diluent, is conducted under conditions in which the polymer and/or its complex with the catalyst is suspended in the diluent during at least part of the polyreaction mixture if desired. The dispersant may be a polymer or an organic compound containing at least eight carbon atoms and is preferably a Lewis base. The dispersant preferably contains at least one molecular segment substantially compatible with the poly(arylene ether ketone) or its complex with the Lewis acid and substantially incompatible with the diluent and at least one molecular segment substantially compatible with the diluent and substantially incompatible with the poly(arylene ether ketone) or its complex with the Lewis acid.

    摘要翻译： 在路易斯酸催化剂和稀释剂存在下，通过Friedel-Crafts聚合法制备聚（亚芳基醚酮）是在聚合物和/或其与催化剂的络合物悬浮在稀释剂中的条件下进行的 如果需要，最少部分的聚反应混合物。 分散剂可以是聚合物或含有至少8个碳原子的有机化合物，优选为路易斯碱。 分散剂优选含有至少一个基本上与聚（亚芳基醚酮）或其与路易斯酸的络合物相容的分子片段，并且与稀释剂基本上不相容，并且至少一个分子片段基本上与稀释剂相容并且与聚（ 亚芳基醚酮）或其与路易斯酸的络合物。

    Preparation of aromatic polymers using a specified quantity of Lewis acid
    6.
    发明授权
    Preparation of aromatic polymers using a specified quantity of Lewis acid 失效
    使用规定量的路易斯酸制备芳族聚合物

    公开(公告)号：US4912195A

    公开(公告)日：1990-03-27

    申请号：US376974

    申请日：1989-07-06

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C08G61/12 ,  C08G67/00

    CPC分类号： C08G61/127 ,  C08G67/00

    摘要： A process for producing an aromatic polyketone which comprises polymerizing an appropriate monomer or monomers by a Friedel-Crafts polymerization reaction using a Lewis acid catalyst. A controlling agent such as a Lewis base may be added to the reaction medium and/or the reaction is conducted under specified conditions to control the reaction. The reaction medium comprises, for example, aluminum trichloride as the Lewis acid, an organic Lewis base such as N,N-dimethylformamide or an inorganic Lewis base such as sodium or lithium chloride, and a diluent such as methylene chloride or dichloroethane. The amount of Lewis acid, the amount of Lewis base, the temperature of the reaction and the monomer to diluent molar ratio are varied depending on the monomer system to obtain melt-processable, high molecular weight, substantially linear polymers, for example poly(carbonyl-p-phenylene-oxy-p-phenylene), poly(carbonyl-p-phenylene-oxy-p-phenylene-oxy-p-phenylene), and the like. Copolymers containing up to 30% by weight of an aromatic sulfonyl halide comonomer can also advantageously be produced by this process.

    摘要翻译： 一种制备芳族聚酮的方法，其包括使用路易斯酸催化剂通过弗瑞德 - 克来福特聚合反应聚合合适的单体或单体。 可以将控制剂如路易斯碱加入到反应介质中和/或反应在特定条件下进行以控制反应。 反应介质包括例如三氯化铝作为路易斯酸，有机路易斯碱如N，N-二甲基甲酰胺或无机路易斯碱如钠或氯化锂，以及稀释剂如二氯甲烷或二氯乙烷。 路易斯酸的量，路易斯碱的量，反应温度和单体与稀释剂的摩尔比取决于单体体系而变化，以获得可熔融加工的高分子量基本上线性的聚合物，例如聚（羰基 对 - 亚苯基 - 氧 - 对亚苯基），聚（羰基 - 对 - 亚苯基 - 氧 - 对亚苯基 - 氧 - 对 - 亚苯基）等。 含有高达30重量％芳族磺酰卤共聚单体的共聚物也可以通过该方法有利地产生。

    Preparation of 4,4'-diphenoxybenzophenone
    7.
    发明授权
    Preparation of 4,4'-diphenoxybenzophenone 失效
    4,4'-二苯氧基二苯甲酮的制备

    公开(公告)号：US4843179A

    公开(公告)日：1989-06-27

    申请号：US141017

    申请日：1988-01-05

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： B01J27/08 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/84 ,  C07C67/00

    CPC分类号： C07C49/84 ,  C07C45/00

    摘要： A method of preparing 4,4'-diphenoxybenzophenone, comprising reacting diphenyl ether and carbon dioxide in the presence of a Friedel-Crafts catalyst and a promoting agent, preferably selected from the group consisting of phosphoryl chloride, phosphorus pentoxide, tetrachlorosilane, methyltrichlorosilane, dimethyldichlorosilane, titanium tetrachloride, zirconium tetrachloride, zirconium oxyhalide, and phosphorus pentachloride. In a preferred embodiment, the Friedel-Crafts catalyst is aluminum chloride and the promoting agent is phosphoryl chloride.

    Preparation of aromatic ketone-sulfone copolymers
    8.
    发明授权
    Preparation of aromatic ketone-sulfone copolymers 失效
    芳香酮砜共聚物的制备

    公开(公告)号：US4593086A

    公开(公告)日：1986-06-03

    申请号：US659742

    申请日：1984-10-11

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C08G75/00 ,  C08F4/14 ,  C08F4/22 ,  C08G2/06 ,  C08G2/18 ,  C08G61/12 ,  C08G67/00 ,  C08G75/20 ,  C08G75/23

    CPC分类号： C08G75/20 ,  C08G61/127

    摘要： A process for producing aromatic ketone-sulfone copolymers which comprises polymerizing appropriate monomers by a Friedel-Crafts polymerization reaction using a Lewis acid catalyst. A controlling agent such as a Lewis base is added to the reaction medium. The reaction medium comprises, for example, aluminum trichloride as the Lewis acid, an organic Lewis base such as N,N-dimethylformamide or an inorganic Lewis base such as sodium or lithium chloride as the controlling agent, and a diluent such as methylene chloride or 1,2-dichloroethane. The amount of Lewis acid, the amount of Lewis base, the temperature of the reaction and the monomer to diluent molar ratio are varied depending on the monomer system to obtain melt-processable, high molecular weight, substantially linear polymers, for example prepared from copolymerization of p-phenoxybenzoyl chloride and p-phenoxybenzenesulfonyl chloride or of terephthaloyl chloride, 1,4-benzenedisulfonyl chloride and diphenyl ether, or of like monomers.

    摘要翻译： 一种制备芳族酮砜共聚物的方法，其包括使用路易斯酸催化剂通过Friedel-Crafts聚合反应使合适的单体聚合。 向反应介质中加入路易斯碱等控制剂。 反应介质包括例如三氯化铝作为路易斯酸，有机路易斯碱如N，N-二甲基甲酰胺或无机路易斯碱如氯化钠或氯化锂作为控制剂，以及稀释剂如二氯甲烷或 1,2-二氯乙烷。 路易斯酸的量，路易斯碱的量，反应温度和单体与稀释剂的摩尔比取决于单体体系而变化，以获得可熔融加工的高分子量基本上线性的聚合物，例如由共聚合制备 对苯氧基苯甲酰氯和对苯氧基苯磺酰氯或对苯二甲酰氯，1,4-苯二磺酰氯和二苯醚或类似单体。

    Preparation of aromatic oligomers
    9.
    发明授权
    Preparation of aromatic oligomers 失效
    芳族低聚物的制备

    公开(公告)号：US4879366A

    公开(公告)日：1989-11-07

    申请号：US296907

    申请日：1989-01-11

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C08G61/12 ,  C08G67/00

    CPC分类号： C08G67/00 ,  C08G61/127

    摘要： Aromatic oligomers, in particular arylene ketone and arylene sulfone oligomers, are prepared by reacting an appropriate monomer system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and a Lewis base, for example, N,N-dimethylformamide, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all paralinked arylene ether ketone oligomers as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution. The monomer system can be, for example, a self-reacting monomer such as p-phenoxy-benzoyl chloride or a two-monomer system such as 1,4-diphenoxybenzene and terephthaloyl chloride.

    摘要翻译： 芳族低聚物，特别是亚芳基酮和亚芳基砜低聚物，通过使游离路易斯酸和路易斯酸例如三氯化铝与路易斯碱（例如N ，N-二甲基甲酰胺和任选的稀释剂，例如二氯甲烷。 由于路易斯酸/路易斯碱配合物的存在明显降低烷基化并确保基本上不存在邻位取代，所以该方法特别有利于制备基本上或全部分子链的亚芳基醚酮低聚物。 单体体系可以是例如对苯氧基苯甲酰氯等自身反应性单体，1,4-二苯氧基苯，对苯二甲酰氯等双系单体体系。

    Preparation of aromatic polymers
    10.
    发明授权
    Preparation of aromatic polymers 失效
    芳族聚合物的制备

    公开(公告)号：US4721771A

    公开(公告)日：1988-01-26

    申请号：US790030

    申请日：1985-10-22

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C07C45/46 ,  C08G61/12 ,  C08G67/00 ,  C08G75/20 ,  C08G2/00 ,  C08G4/00

    CPC分类号： C07C45/46 ,  C08G61/127 ,  C08G67/00 ,  C08G75/20

    摘要： Aromatic oligomers, in particular arylene ketone and arylene sulfone oligomers, are prepared by reacting an appropriate monomer system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and a Lewis base, for example, N,N-dimethylformamide, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all paralinked arylene ether ketone oligomers as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution. The monomer system can be, for example, a self-reacting monomer such as p-phenoxy-benzoyl chloride or a two-monomer system such as 1,4-diphenoxybenzene and terephthaloyl chloride.

    摘要翻译： 芳族低聚物，特别是亚芳基酮和亚芳基砜低聚物，通过使游离路易斯酸和路易斯酸例如三氯化铝与路易斯碱（例如N ，N-二甲基甲酰胺和任选的稀释剂，例如二氯甲烷。 由于路易斯酸/路易斯碱配合物的存在明显降低烷基化并确保基本上不存在邻位取代，所以该方法特别有利于制备基本上或全部分子链的亚芳基醚酮低聚物。 单体体系可以是例如对苯氧基苯甲酰氯等自身反应性单体，1,4-二苯氧基苯，对苯二甲酰氯等双系单体体系。