摘要:
A process for the manufacture of acicular gamma-iron(III) oxide which, because of its improved dispersibility in organic binders, is suitable for the manufacture of magnetic recording media exhibiting a particularly high orientation ratio. For this purpose, the non-magnetic acicular .alpha.-iron(III) oxide or goethite pigment is treated with from 0.5 to 10% by weight, based on the pigment, of a compound of the formula I: ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are hydrogen, alkyl of 1 to 24 carbon atoms or alkenyl of 1 to 24 carbon atoms and (RX).sup.- is selected from the group consisting of an aliphatic carboxylic acid of 1 to 18 carbon atoms, an aromatic carboxylic acid of 1 to 18 carbon atoms, a sulfonic acid and an ester of phosphoric acid and is then further processed by conventional methods to give gamma-iron(III) oxide.
摘要翻译:用于制造针状γ-氧化铁(III)的方法,其由于其在有机粘合剂中的分散性的改善而适用于制造表现出特别高取向比的磁记录介质。 为此,非磁性针状α-铁(III)氧化物或针铁矿颜料以基于颜料的0.5至10重量%的式I化合物处理:其中 R 1,R 2和R 3是氢,1至24个碳原子的烷基或1至24个碳原子的链烯基和(RX) - 选自1至18个碳原子的脂族羧酸,芳族羧酸 1至18个碳原子,磺酸和磷酸酯,然后通过常规方法进一步加工,得到γ-铁(III)氧化物。
摘要:
Goethite is obtained by reacting an aqueous solution of an iron (II) salt with an aqueous solution of an alkali metal hydroxide and oxidizing the resulting iron(II) hydroxide. The oxidation is carried out in three stages. In the first stage, from 4 to 15% by weight are oxidized in the course of from 0.4 to 5 hours, in the second stage from 60 to 85% by weight are oxidized in the course of from 1.5 to 6 hours and in a third stage the remaining amount of iron is oxidized.
摘要:
Chromium dioxide magnetic pigments are stabilized against loss of their magnetic properties by treating them, in aqueous and/or alcoholic suspension, with a block copolymer consisting of siloxane units and alkyleneoxy units of 2 to 4 carbon atoms, the alkyleneoxy units being bonded to the polysiloxane radical by a Si--O--C or Si--C group, in an amount of from 1 to 40% by weight based on the chromium dioxide, after which the latter is separated off and dried at from 50.degree. to 200.degree. C. The stabilized chromium dioxide magnetic pigments may be used for the manufacture of magnetic recording media exhibiting improved stability of the magnetic properties under adverse climatic conditions.
摘要:
Flexible multi-layer magnetic recording media comprising a non-magnetic flexible base and, applied thereto, two superposed magnetizable layers which contain a homogeneous mixture of acicular magnetic chromium dioxide in an organic binder.According to the invention, the magnetizable layer adjacent to the base contains a chromium dioxide having a specific surface area, measured by the BET method, of from 15 to 25 m.sup.2 /g, while the outer magnetic layer contains a chromium dioxide having a specific surface area, measured by the BET method, of from 26 to 35 m.sup.2 /g.Such magnetic recording media are distinguished by uniformly high sensitivity over the entire audible frequency range even if close manufacturing tolerances are not maintained.
摘要:
Acicular .gamma.-iron(III) oxide is manufactured by reacting an iron(II) salt solution with aqueous solutions of alkali metal hydroxides and oxidizing the resulting suspension of iron(II) hyroxides in 3 stages. In the first stage not more than 8 percent by weight of the iron(II) hydroxide originally present is oxidized over a period of 0.5 to 4 hours, in the second stage from 25 to 55 percent by weight over a period of 1.5 to 6 hours and the remainder thereof in a third stage. Following this oxidation, the goethite formed is reduced to magnetite, which is then oxidized to acicular .gamma.-iron(III) oxide.
摘要:
Acicular gamma-iron(III) oxide is manufactured by reacting an iron(II) salt solution with an aqueous solution of an alkali metal hydroxide and oxidizing the resulting suspension of iron(II) hydroxide in three stages. In a first stage, at most from 0.1 to 4% by weight of the amount of iron(II) hydroxide originally present is oxidized in the course of from 0.1 to 4 hours, in a second stage from 10 to 25% by weight of the said original amount are oxidized in the course of from 1.5 to 6 hours and in a third stage the remaining amount is oxidized. After the oxidation, the goethite formed is reduced to magnetite and the latter is then oxidized to acicular gamma-iron(III) oxide.
摘要:
Chromium dioxide magnetic pigments can be stabilized against the loss of their magnetic properties by treating them, in alcoholic aqueous suspension, with a silane or a hydrolysis product thereof, so that when the pigment is isolated from the suspension medium the particles bear at least partially hydrolyzed silane on their surfaces, and then drying the magnetic pigment at from 50.degree. to 200.degree. C.
摘要:
A magnetic dispersion which can be applied to a non-magnetic base to produce a recording medium is prepared by dispersing a magnetically anisotropic material in a polymer binder and in an organic solvent by a method wherein the magnetically anisotropic material is worked in a jet mill before and/or during dispersing.
摘要:
Abstract of the Disclosure: Magnetic recording media comprise a nonmagnetic substrate and a magnetizable layer arranged thereon and essentially consisting of a magnetic material from the group consisting of the cobalt-modified iron oxides and of the hexagonal ferrites and inorganic fillers finely dispersed in organic binders, the inorganic filler used being ferromagnetic chromium dioxide.
摘要:
The invention relates to a process for improving the magnetic properties, especially the remanent magnetization, of gamma-iron(III) oxide which can be used advantageously as the magnetic component in magnetic recording media exhibiting reduced print-through. For this purpose, a gamma-iron(III) oxide manufactured according to known processes is heated at temperatures of from 400.degree. to 700.degree. C., the magnetic pigment having basic compounds on the crystal surface during this heat treatment and retaining a pH value above 8 until heating is over. Gamma-iron(III) oxide magnetic pigments treated in this way are particularly suitable for the manufacture of low-noise magnetic recording media with high remanent magnetization and particularly low print-through.