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公开(公告)号:US20170190852A1
公开(公告)日:2017-07-06
申请号:US15465966
申请日:2017-03-22
申请人: Henkel AG & Co. KGaA
发明人: Andreas Ferencz , Olaf Lammerschop , Tamara Schmidt , Andrew Slark , Dirk Kasper
CPC分类号: C08J5/043 , C08G18/4018 , C08G18/4202 , C08G18/4211 , C08G18/4216 , C08G18/4829 , C08G18/664 , C08G18/6674 , C08G18/7671 , C08J5/04 , C08J5/24 , C08J2375/06 , C08J2375/08
摘要: The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer (A), wherein said thermoplastic polyurethane polymer (A) comprises a reaction product of (i) at least one polyester polyol and (ii) at least one polyisocyanate, optionally at least one diol (iii) which is different from the polyester polyol (i) is contained. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) and said optionally containing diol (iii) is less than 1.00:1. Said polyester polyol (i) comprises (a) at least one semi-crystalline polyester polyol having a melting point (Tm) of from 40 to 180° C., and (b) at least one non-crystalline polyester polyol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
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公开(公告)号:US20140232041A1
公开(公告)日:2014-08-21
申请号:US13770295
申请日:2013-02-19
发明人: Qiwen Han , Andreas Ferencz , Olaf Lammerschop , Yongxia Wang
IPC分类号: C08K5/521
摘要: An internal mold release agent (IMRA) which effectively releases a cured polyurethane (PU) material from a metal, in particular steel, mold. The IMRA is a surface active agent containing phosphorus or a combination (blend or reaction product) of the agent with other chemicals. In one embodiment the agent is a phosphate ester. In one embodiment the agent is polyoxyethylene alkyl phosphate ester. A polyurethane formulation comprising the IMRA has high formulation stability, clean release, low release strength, and high product transparency.
摘要翻译: 内部脱模剂(IMRA),其有效地从金属,特别是钢模具中释放固化的聚氨酯(PU)材料。 IMRA是含有磷或其他化学物质的组合(共混物或反应产物)的表面活性剂。 在一个实施方案中,试剂是磷酸酯。 在一个实施方案中,试剂是聚氧乙烯烷基磷酸酯。 包含IMRA的聚氨酯配方具有高配方稳定性,清洁释放,低释放强度和高产品透明度。
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公开(公告)号:US20170015883A1
公开(公告)日:2017-01-19
申请号:US15279504
申请日:2016-09-29
申请人: Henkel AG & Co. KGaA
IPC分类号: C09J175/04 , B65D65/40 , B32B7/12 , C08G71/04 , C08J7/04
CPC分类号: C09J175/04 , B32B7/12 , B32B2439/70 , B65D65/40 , C07D317/36 , C08G71/00 , C08G71/04 , C08J7/047 , C08J2375/04 , C08L75/12
摘要: The present invention relates to a binder system containing a resin component and a curing agent component, wherein the resin comprises at least one compound carrying at least two cyclic carbonate groups and at least one compound carrying at least two epoxy groups, and the curing agent comprises at least one multifunctional amine as well as the use of the binder system as an adhesive/sealant and the use of this adhesive/sealant.
摘要翻译: 本发明涉及含有树脂组分和固化剂组分的粘合剂体系,其中树脂包含至少一种携带至少两个环状碳酸酯基团的化合物和至少一种携带至少两个环氧基团的化合物,并且固化剂包括 至少一种多官能胺以及使用粘合剂体系作为粘合剂/密封剂以及使用该粘合剂/密封剂。
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公开(公告)号:US20190202965A1
公开(公告)日:2019-07-04
申请号:US16298456
申请日:2019-03-11
申请人: Henkel AG & Co. KGaA
CPC分类号: C08G18/3212 , B29C70/18 , B29C70/48 , B29K2075/00 , C08G18/3206 , C08G18/7664 , C08G18/7671 , C08J5/04 , C08J2375/04
摘要: The invention relates to a thermoplastic polyurethane matrix resin composition, comprising (i) at least one bridged and/or fused and/or Spiro polycyclic alcohol compound; (ii) at least one polyisocyanate; and (iii) at least one diol, which is different from the at least one bridged and/or fused and/or spiro polycyclic alcohol compound (i). The at least one bridged and/or fused and/or Spiro polycyclic alcohol compound (i) is present in the thermoplastic polyurethane matrix resin composition in an amount of at least 10 wt.-% by weight, preferably at least 20 wt-%, most preferably at least 25 wt.-%. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, e.g., skis, snowboards, rackets, golf clubs, fishing rods, baseball bats, hockey sticks, arrows, archery bows, surfboards, javelins, exercise equipment, cell phone and laptop housings, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
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公开(公告)号:US10526460B2
公开(公告)日:2020-01-07
申请号:US15465966
申请日:2017-03-22
申请人: Henkel AG & Co. KGaA
发明人: Andreas Ferencz , Olaf Lammerschop , Tamara Schmidt , Andrew Slark , Dirk Kasper
摘要: The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer (A), wherein said thermoplastic polyurethane polymer (A) comprises a reaction product of (i) at least one polyester polyol and (ii) at least one polyisocyanate, optionally at least one diol (iii) which is different from the polyester polyol (i) is contained. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) and said optionally containing diol (iii) is less than 1.00:1. Said polyester polyol (i) comprises (a) at least one semi-crystalline polyester polyol having a melting point (Tm) of from 40 to 180° C., and (b) at least one non-crystalline polyester polyol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
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公开(公告)号:US20180051119A1
公开(公告)日:2018-02-22
申请号:US15622750
申请日:2017-06-14
申请人: Henkel AG & Co. KGaA
发明人: Christian Holtgrewe , Harald Küster , Thomas Bachon , Andreas Ferencz , Olaf Lammerschop , Rainer Schönfeld , Claudia Mai
摘要: The present invention relates to a method for producing a cured composition, which has at least one oxazolidinone ring and at least one isocyanurate ring and is crosslinked thereby, starting from a liquid reaction mixture comprising: (a) at least one liquid, aromatic epoxy resin; (b) at least one liquid, aromatic polyisocyanate; and (c) a catalyst composition; relative to the at least one polyisocyanate, the at least one epoxy resin is used in amounts such that the molar equivalent ratio of epoxide groups to isocyanate groups is at least 0.4; and curing the reaction mixture to give a cured polymer composition comprising at least one oxazolidinone ring and at least one isocyanurate ring, and also to the cured compositions obtainable by these methods.
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公开(公告)号:US10829582B2
公开(公告)日:2020-11-10
申请号:US15342449
申请日:2016-11-03
申请人: Henkel AG & Co. KGaA
IPC分类号: C08G18/08 , C08G18/48 , C08J5/04 , C08G18/20 , C08G18/42 , C08G18/76 , B29C70/48 , C08K5/103 , C08K5/10 , C08K5/49 , B29L31/30
摘要: The present invention relates to a two-component polyurethane composition composed of at least one polyol, at least one polyisocyanate, and at least one emulsifier which is not homogeneously miscible with the at least one polyol. The present invention further relates to the use of this polyurethane composition as a binder for producing fiber composites, a method for producing these fiber composites, the fiber composites themselves, and use thereof.
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公开(公告)号:US10689476B2
公开(公告)日:2020-06-23
申请号:US15622750
申请日:2017-06-14
申请人: Henkel AG & Co. KGaA
发明人: Christian Holtgrewe , Harald Küster , Thomas Bachon , Andreas Ferencz , Olaf Lammerschop , Rainer Schönfeld , Claudia Mai
IPC分类号: C08G18/00 , C08G18/20 , C08J5/04 , C08G18/76 , C08G18/22 , C08G18/16 , B29C70/48 , B29K63/00 , B29K105/00
摘要: The present invention relates to a method for producing a cured composition, which has at least one oxazolidinone ring and at least one isocyanurate ring and is crosslinked thereby, starting from a liquid reaction mixture comprising: (a) at least one liquid, aromatic epoxy resin; (b) at least one liquid, aromatic polyisocyanate; and (c) a catalyst composition; relative to the at least one polyisocyanate, the at least one epoxy resin is used in amounts such that the molar equivalent ratio of epoxide groups to isocyanate groups is at least 0.4; and curing the reaction mixture to give a cured polymer composition comprising at least one oxazolidinone ring and at least one isocyanurate ring, and also to the cured compositions obtainable by these methods.
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公开(公告)号:US10179871B2
公开(公告)日:2019-01-15
申请号:US15279504
申请日:2016-09-29
申请人: Henkel AG & Co. KGaA
IPC分类号: C08L75/12 , C09J175/04 , C07D317/36 , C08G71/00 , C08G71/04 , B32B7/12 , B65D65/40 , C08J7/04
摘要: The present invention relates to a binder system containing a resin component and a curing agent component, wherein the resin comprises at least one compound carrying at least two cyclic carbonate groups and at least one compound carrying at least two epoxy groups, and the curing agent comprises at least one multifunctional amine as well as the use of the binder system as an adhesive/sealant and the use of this adhesive/sealant.
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公开(公告)号:US20170152367A1
公开(公告)日:2017-06-01
申请号:US15426409
申请日:2017-02-07
IPC分类号: C08K5/521
摘要: An internal mold release agent (IMRA) which effectively releases a cured polyurethane (PU) material from a metal, in particular steel, mold. The IMRA is a surface active agent containing phosphorus or a combination (blend or reaction product) of the agent with other chemicals. In one embodiment the agent is a phosphate ester. In one embodiment the agent is polyoxyethylene alkyl phosphate ester. A polyurethane formulation comprising the IMRA has high formulation stability, clean release, low release strength, and high product transparency.
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