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    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia
    1.
    发明授权
    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia 失效
    CMS / SiO2 / Al2O3催化剂，用于提高从甲醇和/或二甲醚和氨合成胺的选择性

    公开(公告)号：US5482909A

    公开(公告)日：1996-01-09

    申请号：US278644

    申请日：1994-07-21

    申请人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  Davis S. Lafyatis

    发明人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  Davis S. Lafyatis

    IPC分类号： C07C209/16 ,  B41J21/18

    CPC分类号： C07C209/16

    摘要： The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.

    摘要翻译： 本发明涉及用于甲醇和/或二甲醚和氨的起始原料以三甲胺（TMA）为代价选择性合成一甲胺（MMA）和二甲胺（DMA）的改进的催化剂。 目前用于该工艺的工业催化剂是标准的SiO 2 / Al 2 O 3材料。 本发明将该标准催化剂与微孔碳分子筛（CMS）组合以形成对所需产物MMA和DMA具有较高选择性的复合材料（即，CMS / SiO 2 / Al 2 O 3材料）。 本发明还涉及制备改进的催化剂的方法以及在制备MMA和DMA中使用改进的催化剂材料的方法。

    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia
    2.
    发明授权
    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia 失效
    CMS / SiO2 / Al2O3催化剂，用于提高从甲醇和/或二甲醚和氨合成胺的选择性

    公开(公告)号：US5354893A

    公开(公告)日：1994-10-11

    申请号：US100463

    申请日：1993-07-30

    申请人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  David S. Lafyatis

    发明人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  David S. Lafyatis

    IPC分类号： C07C209/16

    CPC分类号： C07C209/16

    摘要： The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.

    摘要翻译： 本发明涉及用于甲醇和/或二甲醚和氨的起始原料以三甲胺（TMA）为代价选择性合成一甲胺（MMA）和二甲胺（DMA）的改进的催化剂。 目前用于该工艺的工业催化剂是标准的SiO 2 / Al 2 O 3材料。 本发明将该标准催化剂与微孔碳分子筛（CMS）组合以形成对所需产物MMA和DMA具有较高选择性的复合材料（即，CMS / SiO 2 / Al 2 O 3材料）。 本发明还涉及制备改进的催化剂的方法以及在制备MMA和DMA中使用改进的催化剂材料的方法。

    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia
    3.
    发明授权
    CMS/SiO.sub.2 /Al.sub.2 O.sub.3 catalysts for improved selectivity in the synthesis of amines from methanol and/or dimethyl ether and ammonia 失效
    CMS / SiO2 / A12O3催化剂，用于提高从甲醇和/或二甲醚和氨合成胺的选择性

    公开(公告)号：US5470814A

    公开(公告)日：1995-11-28

    申请号：US278643

    申请日：1994-07-21

    申请人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  David S. Lafyatis

    发明人： Henry C. Foley ,  George C. Sonnichsen ,  Loren D. Brake ,  Ravindra K. Mariwala ,  David S. Lafyatis

    IPC分类号： C07C209/16 ,  B01J21/18 ,  B01J21/04

    CPC分类号： C07C209/16

    摘要： The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.

    摘要翻译： 本发明涉及用于甲醇和/或二甲醚和氨的起始原料以三甲胺（TMA）为代价选择性合成一甲胺（MMA）和二甲胺（DMA）的改进的催化剂。 目前用于该工艺的工业催化剂是标准的SiO 2 / Al 2 O 3材料。 本发明将该标准催化剂与微孔碳分子筛（CMS）组合以形成对所需产物MMA和DMA具有较高选择性的复合材料（即，CMS / SiO 2 / Al 2 O 3材料）。 本发明还涉及制备改进的催化剂的方法以及在制备MMA和DMA中使用改进的催化剂材料的方法。

    Process of preparing formaldehyde/amine adducts
    5.
    发明授权
    Process of preparing formaldehyde/amine adducts 失效
    制备甲醛/胺加合物的方法

    公开(公告)号：US5091584A

    公开(公告)日：1992-02-25

    申请号：US631267

    申请日：1990-12-20

    申请人： Loren D. Brake

    发明人： Loren D. Brake

    IPC分类号： C07C209/78 ,  C07C215/08 ,  C07C217/08

    CPC分类号： C07C217/08 ,  C07C209/78 ,  C07C215/08

    摘要： A formaldehyde/amine adduct useful in water treatment having improved stability made by reacting formaldehyde and a secondary amine, limiting the water content of the adduct to no more than 30 weight percent, optionally, adding an alcohol.

    摘要翻译： 可用于水处理的甲醛/胺加合物具有通过使甲醛和仲胺反应而改进的稳定性，将加合物的水含量限制在不超过30重量％，任选地加入醇。

    Catalytic preparation of dimethyl ether
    6.
    发明授权
    Catalytic preparation of dimethyl ether 失效
    催化二甲醚的制备

    公开(公告)号：US4605788A

    公开(公告)日：1986-08-12

    申请号：US768936

    申请日：1985-08-26

    申请人： Loren D. Brake

    发明人： Loren D. Brake

    IPC分类号： C07C41/09 ,  C07C43/04

    CPC分类号： C07C41/09

    摘要： In the preparation of dimethyl ether by the catalytic dehydration of methanol, reaction rate is enhanced and catalyst coking and byproduct formation are significantly reduced when an aluminosilicate containing a high level of alumina is used as the catalyst.

    摘要翻译： 在通过甲醇催化脱水制备二甲醚时，当使用含有高含量氧化铝的铝硅酸盐作为催化剂时，反应速率提高，催化剂焦化和副产物形成显着降低。

    Preparation of dimethyl ether by catalytic dehydration of methanol
    8.
    发明授权
    Preparation of dimethyl ether by catalytic dehydration of methanol 失效
    通过甲醇催化脱水制备二甲醚

    公开(公告)号：US4595785A

    公开(公告)日：1986-06-17

    申请号：US707606

    申请日：1985-03-04

    申请人： Loren D. Brake

    发明人： Loren D. Brake

    IPC分类号： B01J21/06 ,  C07C41/09

    CPC分类号： B01J21/063 ,  C07C41/09

    摘要： In the preparation of dimethyl ether by the catalytic dehydration of methanol, reaction rate is enhanced and catalyst coking and byproduct formation are significantly reduced when an aluminotitanate containing 0.1-20% of titania and 80-99.9% of alumina is used as the catalyst.

    摘要翻译： 在甲醇催化脱水制备二甲醚时，当使用含0.1-20％二氧化钛和80-99.9％氧化铝的铝钛酸盐作为催化剂时，反应速率提高，催化剂焦化和副产物形成显着降低。

    Catalyst for methylamines production
    10.
    发明授权
    Catalyst for methylamines production 失效
    甲胺生产催化剂

    公开(公告)号：US4370503A

    公开(公告)日：1983-01-25

    申请号：US247136

    申请日：1981-03-24

    申请人： Loren D. Brake

    发明人： Loren D. Brake

    IPC分类号： B01J21/12 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/16 ,  C07C211/04 ,  C07C85/02 ,  C07C85/06

    CPC分类号： B01J21/12

    摘要： In the catalytic preparation of methylamines from methanol or dimethyl ether and ammonia using a silica-alumina catalyst, catalyst coking and byproduct formation are reduced and reaction speed and catalyst thermal stability are enhanced when a catalyst containing a high level of alumina is used.

    摘要翻译： 在使用二氧化硅 - 氧化铝催化剂从甲醇或二甲醚和氨催化制备甲胺时，催化剂焦化和副产物形成降低，当使用含有高含量氧化铝的催化剂时，反应速度和催化剂热稳定性得到提高。