摘要:
A photo-curable transfer sheet having a photo-curable transfer layer comprising a photo-curable composition, the photo-curable composition being deformable by application of pressure and containing a reactive polymer having a photopolymerizable functional group, wherein the photo-curable transfer layer shows linearity in relationship between strain [β] (%) and time [t] (second) measured by a creep test using a dynamic viscoelasticity measuring apparatus under the conditions of an ordinary temperature, stress of 50 Pa and a time period of 120 seconds, and satisfies a following formula: log β=a+b·log t, in which “a” is a real number, and “b” is in the range of 0.10 to 0.53; and a process for the preparation of an optical information recording medium using the sheet and an optical information recording medium.
摘要翻译:一种光固化性转印片,其具有含有光固化性组合物的光固化性转印层,该光固化性组合物可通过施加压力而变形并含有具有光聚合性官能团的反应性聚合物,其中光固化性转印层显示 在常温,应力为50Pa,时间为120秒的条件下,通过使用动态粘弹性测定装置的蠕变试验测定的应变β(%)与时间[t](秒)的关系的线性关系, 并且满足下式:logβ= a + b.log t,其中“a”是实数,“b”在0.10至0.53的范围内; 以及使用该片材和光学信息记录介质制备光学信息记录介质的方法。
摘要:
A photo-curable transfer sheet having a photo-curable transfer layer comprising a photo-curable composition, the photo-curable composition being deformable by application of pressure and containing a reactive polymer having a photopolymerizable functional group, wherein the photo-curable transfer layer shows linearity in relationship between strain [γ] (%) and time [t] (second) measured by a creep test using a dynamic viscoelasticity measuring apparatus under the conditions of an ordinary temperature, stress of 50 Pa and a time period of 120 seconds, and satisfies a following formula: log γ=a+b·log t, in which “a” is a real number, and “b” is in the range of 0.10 to 0.53; and a process for the preparation of an optical information recording medium using the sheet and an optical information recording medium.
摘要翻译:一种光固化性转印片,其具有含有光固化性组合物的光固化性转印层,该光固化性组合物可通过施加压力而变形并含有具有光聚合性官能团的反应性聚合物,其中光固化性转印层显示 在常温,应力为50Pa,时间为120秒的条件下,通过使用动态粘弹性测定装置的蠕变试验测定的应变[γ](%)与时间[t](秒)的关系的线性关系, 并且满足以下公式:logγ= a + b·log t,其中“a”是实数,“b”在0.10至0.53的范围内; 以及使用该片材和光学信息记录介质制备光学信息记录介质的方法。
摘要:
The present invention provides a photo-curable transfer sheet by which an optical information recording medium (e.g., DVD) having small thickness and high capacity can be advantageously prepared, and which is improved in transferring property of pits and the like and curing property. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer having a glass transition temperature of not less than 80° C. and a reactive diluent having a photopolymerizable functional group. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.
摘要:
The present invention provides a photo-curable transfer sheet by which an optical information recording medium (e.g., DVD) having small thickness and high capacity can be advantageously prepared, and which is improved in transferring property of pits and the like and curing property. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer having a glass transition temperature of not less than 80° C. and a reactive diluent having a photopolymerizable functional group. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.
摘要:
The present invention provides a photo-curable transfer sheet by which an optical information recording medium having small thickness and high capacity can be advantageously prepared, the photo-curable transfer layer of the sheet cured in the production of the optical information recording medium having excellent adhesion to the reflective layer such silver alloy and easy peeling property from the stamper to easily bring about the transfer layer having an uneven surface such as pits, etc accurately formed along an uneven surface of the stamper. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer and a reactive diluent having a photopolymerizable functional group, and the reactive diluent has at least one hydroxyl group and an acryloyl group and/or methacryloyl group, the total of acryloyl group and/or methacryloyl group being at least two. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.
摘要:
A process for the preparation of an optical information recording medium comprises superposing two optical information recording substrates having an uneven surface of recorded pits and/or grooves on each other through a photo-curable adhesive sheet comprising a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and Tg of not more than 20° C., the photo-curable adhesive sheet having a light transmittance of not less than 70% in a wavelength range of 380 to 420 nm, such that the two uneven surfaces face each other, depressing the substrates and sheet to form a laminate, and curing the laminate by light. A process for the preparation of an optical information recording medium comprises placing a photo-curable transfer sheet comprising a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and Tg of not more than 20° C. on an optical information recording substrate having an uneven surface of recorded pits and/or grooves such that one side of the photo-curable transfer sheet is in contact with the uneven surface of the optical information recording substrate, depressing the sheet and substrate to form a laminate in which the one side of the photo-curable transfer sheet adheres closely to the uneven surface, and exposing the photo-curable transfer sheet of the laminate to ultraviolet rays to cure the transfer sheet. A photo-curable transfer sheet comprises a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and which is capable of deforming by application of pressure, at least one side of the photo-curable transfer sheet having a surface roughness (Ra) of not more than 30 nm.
摘要:
A photo-curable transfer sheet having a photo-curable layer comprising a photo-curable composition, the photo-curable composition being deformable by application of pressure and containing a reactive polymer having a photopolymerizable functional group. The photo-curable transfer sheet preferably has a light transmittance of not less than 70% in a wavelength rang of 380 to 420 nm. An optical information recording substrate and medium prepared by the sheet. The sheet easily and precisely enables transfer of unevenness of the surface of a stamper by pressing.
摘要:
The present invention is to provide a photo-curable transfer sheet suitable for the preparation of an intermediate stamper in a nanoimprint method, in which the peeling property from a mold having a fine concave-convex pattern used in the preparation of the intermediate stamper and the peeling property of a cured photo-curable resin that is a product having a fine concave-convex pattern transferred from the intermediate stamper are excellent, and the adhesion to a base film is good; and a method for forming a concave-convex pattern by using the above-mentioned photo-curable transfer sheet. The photo-curable transfer sheet 10 having a photo-curable transfer layer 11 comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises as a lubricant a silicone resin and/or a fluorine-atom-containing ethylenic compound, and a surface energy of the photo-curable transfer layer 11 is more than 20 mN/m and less than 30 mN/m; and a method for forming a concave-convex pattern by using the sheet.
摘要翻译:本发明提供一种适用于制备纳米压印法中的中压模的光固化性转印片,其中从具有用于制备中间印模的精细凹凸图案的模具的剥离性能和 作为从中间压模转印的具有微细凹凸图案的产品的固化光固化树脂的剥离性优异,对基膜的粘合性良好; 以及通过使用上述光固化性转印片形成凹凸图案的方法。 具有光固化性转印层11的光固化性转印片10,其包含通过施加压力而变形的光固化性组合物,其中,光固化性组合物含有硅树脂和/或含氟原子的烯属 化合物,光固化性转印层11的表面能大于20mN / m且小于30mN / m; 以及通过使用该片形成凹凸图案的方法。
摘要:
The present invention is to provide a photo-curable transfer sheet suitable for the preparation of an intermediate stamper in a nanoimprint method, in which the mold release properties from a mold having a fine concave-convex pattern used in the preparation of the intermediate stamper and the mold release properties of a cured photo-curable resin that is a product having a fine concave-convex pattern transferred from the intermediate stamper are excellent, and the transfer property of the fine concave-convex pattern is good; and a method for forming a concave-convex pattern by using the above-mentioned photo-curable transfer sheet. The photo-curable transfer sheet 10 having a photo-curable transfer layer 11 comprising a photo-curable composition deformable by application of pressure which comprises a polymer and a reactive diluent having a photopolymerizable functional group, wherein the polymer is an acrylic resin comprising a recurring unit derived from (meth)acrylate having an alicyclic group.
摘要:
The present invention provides a method for forming concave-convex pattern corresponding to a nanoimprint method which is advantageously utilized in the preparation of electronic devices, optical parts and recording media, and enabling the preparation of the product having the fine pattern mentioned above in cheapness and high speed. The method for forming a concave-convex pattern comprises of the steps: a step of placing and depressing a stamper having a fine concave-convex pattern surface thereon on a photo-curable transfer layer of a photo-curable transfer sheet to form a laminate; a step of exposing the photo-curable transfer layer of the laminate having the stamper to ultraviolet rays to cure the photo-curable transfer layer, and removing the stamper from the laminate to form the inverted fine concave-convex pattern on a surface of the photo-curable transfer layer; a step of placing and depressing the intermediate stamper on a photo-curable transfer layer of another photo-curable transfer sheet to form a laminate; and a step of exposing the photo-curable transfer layer of the laminate having the intermediate stamper to ultraviolet rays to cure the photo-curable transfer layer, and removing the intermediate stamper, whereby the photo-curable transfer sheet having the fine concave-convex pattern surface is obtained.