公开(公告)号：US20050245701A1

公开(公告)日：2005-11-03

申请号：US11044183

申请日：2005-01-28

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： B01J31/00 ,  C08F4/02 ,  C08F4/44 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16

CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65912 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.

摘要翻译： 一种改性粒子的制造方法，其特征在于，包括使式（a）所定义的化合物（a）与M 1〜 ，由下式定义的化合物（b）：R 1，T-1 TH，由式R定义的化合物（c）或（e） （OH）2或R 2 - 4 - n - （OH）n N，和颗粒（d）; 包含由所述方法生产的改性颗粒的载体; 包含由所述方法生产的改性颗粒的催化剂组分（A） 一种制备用于加成聚合的催化剂的方法，其包括使所述催化剂组分（A），过渡金属化合物（B）和任选的有机铝化合物（C）彼此接触的步骤; 以及加成聚合物的制造方法，其特征在于，在上述工序生成的加成催化剂用催化剂的存在下，进行加成聚合加成聚合性单体的工序。

公开(公告)号：US07524789B2

公开(公告)日：2009-04-28

申请号：US10934504

申请日：2004-09-07

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： B01J31/06 ,  B01J31/14 ,  C08F4/52

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, a carrier or a catalyst component for addition polymerization, which comprises the steps of (1) contacting a compound (a) represented by the defined formula M1L13 with a compound (b) represented by the defined formula R1t-1TH, thereby producing a contact product, and (2) contacting the contact product with a porous particle (d) and then with a compound (c) represented by the defined formula R2t-2TH2; a process for producing a pre-polymerized catalyst component or a catalyst for addition polymerization, which comprises the steps of (1) contacting the above modified particle with a transition metal compound and optionally an organoaluminum compound, thereby producing a primary catalyst, and (2) pre-polymerizing an olefin in the presence of the primary catalyst; a process for producing a catalyst for addition polymerization, which comprises the step of contacting the above catalyst component with a transition metal compound and optionally an organoaluminum compound; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of the above catalyst.

摘要翻译： 一种制备用于加成聚合的改性颗粒，载体或催化剂组分的方法，其包括以下步骤：（1）使由定义的式M1L13表示的化合物（a）与由定义的式R1t表示的化合物（b） -1TH，从而产生接触产物，和（2）使接触产物与多孔颗粒（d）接触，然后与由定义的式R2t-2TH2表示的化合物（c）接触; 一种制备预聚合催化剂组分或加成聚合催化剂的方法，其包括以下步骤：（1）使上述改性颗粒与过渡金属化合物和任选的有机铝化合物接触，由此制备主催化剂，和（2 ）在主催化剂存在下预聚烯烃; 一种制备用于加成聚合的催化剂的方法，其包括使上述催化剂组分与过渡金属化合物和任选的有机铝化合物接触的步骤; 和加成聚合物的制造方法，该方法包括在上述催化剂的存在下加成聚合上述可加聚单体的工序。

公开(公告)号：US07115539B2

公开(公告)日：2006-10-03

申请号：US10753451

申请日：2004-01-09

申请人： Kazuo Takaoki ,  Hideki Oshima ,  Makoto Satoh

发明人： Kazuo Takaoki ,  Hideki Oshima ,  Makoto Satoh

IPC分类号： C08F4/60 ,  C08F4/602 ,  C08F4/606

CPC分类号： C07F17/00 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65912 ,  C08F2500/10 ,  C08F2500/12

摘要： A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula M1L1r, a compound represented by the formula R1s−1TH, and a compound represented by the formula R24−nJ(OH)n; a catalyst component for addition polymerization comprising the metal compound; a catalyst for addition polymerization using the catalyst component; and a process for producing an addition polymer using the catalyst.

摘要翻译： 一种金属化合物，其通过以下步骤获得，该方法包括以特定比例接触式M 1 L 1，L 2， ，由式R 1 S-1 TH表示的化合物和由式R 2〜4-n表示的化合物， J（OH）n N; 包含金属化合物的加成聚合催化剂组分; 使用催化剂组分的加成聚合催化剂; 以及使用该催化剂制造加成聚合物的方法。

公开(公告)号：US20050222351A1

公开(公告)日：2005-10-06

申请号：US11041954

申请日：2005-01-26

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C07F5/00 ,  C07F5/06 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F15/00 ,  C07F15/02 ,  C07F17/02 ,  C08F4/42 ,  C08F4/44 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/00 ,  C08F210/16

CPC分类号： C07F5/066 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65912 ,  C08F2500/12 ,  C08F2500/10 ,  C08F210/08

摘要： There are provided (1) a process for producing a compound, which comprises the step of contacting a compound (A) defined by the formula, M1L13, a compound (B) defined by the formula, R1t-1TH, and a compound (C) defined by the formula, R2t-2TH2; (2) a catalyst component for addition polymerization, which comprises a compound produced by said process; (3) a process for producing a polymerization catalyst, which comprises the step of contacting said catalyst component with a transition metal compound and an optional organoaluminum compound; and (4) a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of a catalyst produced by said process.

摘要翻译： 提供了（1）一种化合物的制备方法，其包括使式（A）所定义的化合物（A）与M 1〜 3，由式R 1〜T TH定义的化合物（B）和由式定义的化合物（C） 2＆gt;＆lt; 2＆gt;＆lt; t-2＆gt; 2＆lt; 2＆gt; （2）用于加成聚合的催化剂组分，其包含通过所述方法制备的化合物; （3）聚合催化剂的制备方法，其包括使所述催化剂组分与过渡金属化合物和任选的有机铝化合物接触的步骤; （4）加成聚合物的制造方法，其特征在于，在上述工序生成的催化剂存在下，加成聚合上述可加聚单体的工序。

公开(公告)号：US07932330B2

公开(公告)日：2011-04-26

申请号：US12078855

申请日：2008-04-07

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C08F4/52 ,  C08F4/03 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65912 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.

摘要翻译： 一种制备改性颗粒的方法，其包括使式M1定义的化合物（a），由式R1t-1TH定义的化合物（b），定义的化合物（c）或（e） 分别为R2m-uM2（OH）u或R24-nJ（OH）n，和颗粒（d）彼此之间; 包含由所述方法生产的改性颗粒的载体; 包含由所述方法生产的改性颗粒的催化剂组分（A） 一种制备用于加成聚合的催化剂的方法，其包括使所述催化剂组分（A），过渡金属化合物（B）和任选的有机铝化合物（C）彼此接触的步骤; 以及加成聚合物的制造方法，其特征在于，在上述工序生成的加成催化剂用催化剂的存在下，进行加成聚合加成聚合性单体的工序。

公开(公告)号：US07592402B2

公开(公告)日：2009-09-22

申请号：US11044183

申请日：2005-01-28

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C08F4/58 ,  C08F4/52

CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65912 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.

摘要翻译： 一种制备改性颗粒的方法，其包括使式M1定义的化合物（a），由式R1t-1TH定义的化合物（b），定义的化合物（c）或（e） 分别为R2m-uM2（OH）u或R24-nJ（OH）n，和颗粒（d）彼此之间; 包含由所述方法生产的改性颗粒的载体; 包含由所述方法生产的改性颗粒的催化剂组分（A） 一种制备用于加成聚合的催化剂的方法，其包括使所述催化剂组分（A），过渡金属化合物（B）和任选的有机铝化合物（C）彼此接触的步骤; 以及加成聚合物的制造方法，其特征在于，在上述工序生成的加成催化剂用催化剂的存在下，进行加成聚合加成聚合性单体的工序。

公开(公告)号：US07122691B2

公开(公告)日：2006-10-17

申请号：US11041954

申请日：2005-01-26

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C07F5/06 ,  B01J31/00 ,  C08F4/44 ,  C07F17/00

CPC分类号： C07F5/066 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65912 ,  C08F2500/12 ,  C08F2500/10 ,  C08F210/08

摘要： There are provided (1) a process for producing a compound, which comprises the step of contacting a compound (A) defined by the formula, M1L13, a compound (B) defined by the formula, R1t-1TH, and a compound (C) defined by the formula, R2t-2TH2; (2) a catalyst component for addition polymerization, which comprises a compound produced by said process; (3) a process for producing a polymerization catalyst, which comprises the step of contacting said catalyst component with a transition metal compound and an optional organoaluminum compound; and (4) a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of a catalyst produced by said process.

摘要翻译： 提供了（1）一种化合物的制备方法，其包括使式（A）所定义的化合物（A）与M 1〜 3，由式R 1〜T TH定义的化合物（B）和由式定义的化合物（C） 2＆gt;＆lt; 2＆gt;＆lt; t-2＆gt; 2＆lt; 2＆gt; （2）用于加成聚合的催化剂组分，其包含通过所述方法制备的化合物; （3）聚合催化剂的制备方法，其包括使所述催化剂组分与过渡金属化合物和任选的有机铝化合物接触的步骤; （4）加成聚合物的制造方法，其特征在于，在上述工序生成的催化剂存在下，加成聚合上述可加聚单体的工序。

公开(公告)号：US20050148459A1

公开(公告)日：2005-07-07

申请号：US10934504

申请日：2004-09-07

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  C08F4/44

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, a carrier or a catalyst component for addition polymerization, which comprises the steps of (1) contacting a compound (a) represented by the defined formula M1L13 with a compound (b) represented by the defined formula R1t-1TH, thereby producing a contact product, and (2) contacting the contact product with a compound (c) represented by the defined formula R2t-2TH2 in the presence of a particle (d); a process for producing a pre-polymerized catalyst component or a catalyst for addition polymerization, which comprises the steps of (1) contacting the above modified particle with a transition metal compound and optionally an organoaluminum compound, thereby producing a primary catalyst, and (2) pre-polymerizing an olefin in the presence of the primary catalyst; a process for producing a catalyst for addition polymerization, which comprises the step of contacting the above catalyst component with a transition metal compound and optionally an organoaluminum compound; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of the above catalyst.

摘要翻译： 一种用于加成聚合的改性颗粒，载体或催化剂组分的制备方法，包括以下步骤：（1）使由定义的式M表示的化合物（a） 1与由定义式R 1〜T-1 TH表示的化合物（b）反应，由此制备接触产物 ，和（2）使接触产物与由式R 2表示的化合物（c）接触，其中R 1，R 2，R 2，R 2， 颗粒的存在（d）; 一种制备预聚合催化剂组分或加成聚合催化剂的方法，其包括以下步骤：（1）使上述改性颗粒与过渡金属化合物和任选的有机铝化合物接触，由此制备主催化剂，和（2 ）在主催化剂存在下预聚烯烃; 一种制备用于加成聚合的催化剂的方法，其包括使上述催化剂组分与过渡金属化合物和任选的有机铝化合物接触的步骤; 和加成聚合物的制造方法，该方法包括在上述催化剂的存在下加成聚合上述可聚合单体的步骤。

公开(公告)号：US20080319148A1

公开(公告)日：2008-12-25

申请号：US12078855

申请日：2008-04-07

申请人： Hideki Oshima ,  Makoto Satoh

发明人： Hideki Oshima ,  Makoto Satoh

IPC分类号： C08F4/52 ,  B01J31/02 ,  B01J31/12 ,  C08F4/44

CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65912 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10

摘要： A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.

摘要翻译： 一种制备改性颗粒的方法，其包括使式M1定义的化合物（a），由式R1t-1TH定义的化合物（b），定义的化合物（c）或（e） 分别为R2m-uM2（OH）u或R24-nJ（OH）n，和颗粒（d）彼此之间; 包含由所述方法生产的改性颗粒的载体; 包含由所述方法生产的改性颗粒的催化剂组分（A） 一种制备用于加成聚合的催化剂的方法，其包括使所述催化剂组分（A），过渡金属化合物（B）和任选的有机铝化合物（C）彼此接触的步骤; 以及加成聚合物的制造方法，其特征在于，在上述工序生成的加成催化剂用催化剂的存在下，进行加成聚合加成聚合性单体的工序。

公开(公告)号：US08563673B2

公开(公告)日：2013-10-22

申请号：US12301784

申请日：2007-05-29

申请人： Takafumi Iwata ,  Hideki Oshima ,  Satoru Moritomi

发明人： Takafumi Iwata ,  Hideki Oshima ,  Satoru Moritomi

IPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  B29C47/36

CPC分类号： C08F10/06 ,  B29C47/385 ,  B29C49/0005 ,  C08F110/06 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/21 ,  C08F210/16

摘要： A propylene-based resin molded article satisfying the following requirements (1) through (4): Requirement (1) Lc/La≦1.50 Requirement (2) Lc≧10.0 Requirement (3) F1≧0.07 Requirement (4) F2≧0.06 wherein in Requirements (1) through (4), La denotes the distance (unit: nm) between crystalline lamellae calculated from the long-period distance calculated from a small-angle X-ray scattering profile and the degree of crystallization calculated from the amount of heat of fusion measured by differential scanning calorimetry, Lc denotes the thickness (unit: nm) of a crystalline lamella calculated from the distance between crystalline lamellae and the long-period distance, F1 denotes the degree of orientation calculated from the infrared dichroic ratio measured at a wave number of 997 cm−1, and F2 denotes the degree of orientation calculated from the infrared dichroic ratio measured at a wave number of 973 cm−1.

摘要翻译： 满足以下要求（1）〜（4）的丙烯类树脂成形品：要件（1）Lc / La @ 1.50要求（2）Lc> = 10.0要求（3）F1> = 0.07要求（4）F2> = 0.06其中在要求（1）至（4）中，La表示从由小角度X射线散射曲线计算的长周期距离计算的晶片之间的距离（单位：nm）和从 通过差示扫描量热法测量的熔化热量，Lc表示从晶片与长周期距离之间的距离计算的结晶薄片的厚度（单位：nm），F1表示从红外二色性计算出的取向度 在波数为997cm-1时测量的比率，F2表示由波数为973cm -1测量的红外二色性比计算出的取向度。