公开(公告)号：US20080308459A1

公开(公告)日：2008-12-18

申请号：US11664260

申请日：2005-09-30

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Hirofumi Konno

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Hirofumi Konno

IPC分类号： C10G45/00

CPC分类号： C10G45/52 ,  C10G65/12 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/06

摘要： A process of the present invention for producing a hydrotreated gas oil has a step for obtaining a product oil having a total aromatic content of 3% by volume or less by hydrogenating a hydrotreated oil including 95% by volume or more of fraction having a boiling point range of 150-380° C., a sulfur content of 2-15 ppm by mass, a total aromatic content of 10-25% by volume, and a naphthene of 20-60% by volume in the presence of a hydrogenation catalyst; and a step for obtaining, by hydrogenating the above-described product oil in the presence of a hydrogenation catalyst containing a crystalline molecular sieve component, a product oil satisfying the conditions that the content of petroleum fraction having a boiling point range of lower than 150° C. is 16% by volume or less, and the sum of the total aromatic content and the total naphthene content is 80% or less relative to the sum of these in the hydrotreated oil.

摘要翻译： 用于制备加氢处理瓦斯油的本发明方法具有以下步骤：通过氢化包含95体积％以上的沸点的加氢处理油，得到总芳烃含量为3体积％以下的产物油 在氢化催化剂的存在下，150-380℃的硫含量，2-15质量ppm的硫含量，10-25体积％的总芳族含量和20-60体积％的环烷烃; 以及通过在含有结晶分子筛组分的氢化催化剂存在下氢化上述产物油获得满足沸点范围低于150℃的石油馏分含量的产物的步骤 C为16体积％以下，芳香族化合物总量和总环烷烃含量的总和相对于加氢处理油中的总和为80％以下。

公开(公告)号：US20060260983A1

公开(公告)日：2006-11-23

申请号：US10548315

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

IPC分类号： C07C37/00 ,  C10G45/04 ,  C10G25/00 ,  C10G45/60

CPC分类号： C10G45/44 ,  B01J29/126 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃 含量不超过1％（体积）。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US20060211900A1

公开(公告)日：2006-09-21

申请号：US10548313

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

IPC分类号： C07C1/00

CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/20 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a gas oil fraction with a sulfur content of 0.8-2% by mass and a total aromatic content of 20-35% by volume as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst comprising at least one metal from among Group 6A metals and at least one metal from among Group 8 metals as active metals, and under reaction conditions with a reaction temperature of 330-390° C., a hydrogen partial pressure of 12-20 MPa and a liquid hourly space velocity of 0.1-1 h−1, to obtain an ultralow sulfur and low- aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于，使用硫含量为0.8〜2质量％，总芳烃含量为20〜35体积％的粗柴油馏分作为原料油， 在包含至少一种金属的6A族金属和至少一种金属作为活性金属的第8族金属中进行加氢处理，在反应温度为330-390℃的反应条件下，加氢处理 12-20MPa的分压和0.1-1小时-1的液时空速，得到硫含量不大于1ppm的超低硫和低芳烃瓦斯油馏分 并且总芳族含量不大于1体积％。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US20090223861A1

公开(公告)日：2009-09-10

申请号：US11992335

申请日：2006-09-21

申请人： Yukihiro Sugiura ,  Yasushi Mizuno

发明人： Yukihiro Sugiura ,  Yasushi Mizuno

IPC分类号： C10G35/04

CPC分类号： H01M8/0612 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/0811 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/127 ,  C01B2203/1288 ,  C01B2203/142 ,  C01B2203/1604 ,  C01B2203/82 ,  H01M8/04223 ,  Y10S585/943

摘要： For shortening the starting time of an autothermal reformer, the autothermal reformer is started by a method comprising: a first preheating step of heating a reforming catalyst up to a predetermined temperature with use of heating means, the heating means being positioned upstream of the reforming catalyst to heat the reforming catalyst; a second preheating step of stopping the heating after arrival at the predetermined temperature, feeding vaporized fuel and air to the reforming catalyst at the predetermined temperature, allowing the fuel to be oxidized by the reforming catalyst and thereby heating the reforming catalyst; and a starting step of also supplying steam to the reforming catalyst heated by the second preheating step and starting autothermal reforming under the condition for a steady state.

摘要翻译： 为了缩短自热重整器的开始时间，自热重整器通过以下方法开始，该方法包括：使用加热装置将重整催化剂加热至预定温度的第一预热步骤，加热装置位于重整催化剂的上游 加热重整催化剂; 第二预热步骤，在到达预定温度之后停止加热，在预定温度下将蒸发的燃料和空气供给到重整催化剂，允许燃料被重整催化剂氧化，从而加热重整催化剂; 以及向在第二预热步骤加热的重整催化剂供给蒸汽并在稳定状态下开始自热重整的起始步骤。

公开(公告)号：US08841039B2

公开(公告)日：2014-09-23

申请号：US13338584

申请日：2011-12-28

申请人： Yukihiro Sugiura

发明人： Yukihiro Sugiura

IPC分类号： H01M8/06 ,  H01M8/04 ,  H01M8/10 ,  H01M8/12 ,  H01M8/24

CPC分类号： H01M8/1246 ,  H01M8/04007 ,  H01M8/04089 ,  H01M8/04223 ,  H01M8/04302 ,  H01M8/0618 ,  H01M8/0625 ,  H01M8/2425 ,  H01M8/2475 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56

摘要： The indirect internal reforming solid oxide fuel cell system includes an indirect internal reforming solid oxide fuel cell that has a first reformer which produces a reformed gas from a hydrocarbon-based fuel by using a steam reforming reaction, a solid oxide fuel cell which generates electric power by using the reformed gas obtained in the first reformer, and a container which houses the first reformer and the solid oxide fuel cell, the first reformer being disposed in a position to receive heat radiation from the solid oxide fuel cell; a second reformer which is disposed outside the container and produces a reformed gas by reforming a hydrocarbon-based fuel; and a line which leads the reformed gas obtained in the second reformer from the second reformer to an anode of the solid oxide fuel cell.

摘要翻译： 间接内部重整固体氧化物燃料电池系统包括间接内部重整固体氧化物燃料电池，其具有通过使用蒸汽重整反应从烃类燃料产生重整气体的第一重整器，产生电力的固体氧化物燃料电池 通过使用在第一重整器中获得的重整气体和容纳第一重整器和固体氧化物燃料电池的容器，第一重整器设置在接收来自固体氧化物燃料电池的热辐射的位置; 第二重整器，其设置在容器外部并通过重整烃类燃料产生重整气体; 以及将在第二重整器中获得的重整气体从第二重整器引导至固体氧化物型燃料电池的阳极的管线。

公开(公告)号：US20130011758A1

公开(公告)日：2013-01-10

申请号：US13338584

申请日：2011-12-28

申请人： Yukihiro Sugiura

发明人： Yukihiro Sugiura

IPC分类号： H01M8/06

CPC分类号： H01M8/1246 ,  H01M8/04007 ,  H01M8/04089 ,  H01M8/04223 ,  H01M8/04302 ,  H01M8/0618 ,  H01M8/0625 ,  H01M8/2425 ,  H01M8/2475 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56

摘要： The indirect internal reforming solid oxide fuel cell system includes an indirect internal reforming solid oxide fuel cell that has a first reformer which produces a reformed gas from a hydrocarbon-based fuel by using a steam reforming reaction, a solid oxide fuel cell which generates electric power by using the reformed gas obtained in the first reformer, and a container which houses the first reformer and the solid oxide fuel cell, the first reformer being disposed in a position to receive heat radiation from the solid oxide fuel cell; a second reformer which is disposed outside the container and produces a reformed gas by reforming a hydrocarbon-based fuel; and a line which leads the reformed gas obtained in the second reformer from the second reformer to an anode of the solid oxide fuel cell.

摘要翻译： 间接内部重整固体氧化物燃料电池系统包括间接内部重整固体氧化物燃料电池，其具有通过使用蒸汽重整反应从烃类燃料产生重整气体的第一重整器，产生电力的固体氧化物燃料电池 通过使用在第一重整器中获得的重整气体和容纳第一重整器和固体氧化物燃料电池的容器，第一重整器设置在接收来自固体氧化物燃料电池的热辐射的位置; 第二重整器，其设置在容器外部并通过重整烃类燃料产生重整气体; 以及将在第二重整器中获得的重整气体从第二重整器引导至固体氧化物型燃料电池的阳极的管线。

公开(公告)号：US5580000A

公开(公告)日：1996-12-03

申请号：US276493

申请日：1994-07-18

申请人： Hideo Kiuchi ,  Katsuhisa Shimokawa ,  Tatsuo Sakai ,  Yukihiro Sugiura

发明人： Hideo Kiuchi ,  Katsuhisa Shimokawa ,  Tatsuo Sakai ,  Yukihiro Sugiura

IPC分类号： F02B1/04 ,  F02M51/06 ,  F02M51/08 ,  F02M61/06 ,  F02M61/10 ,  F02M61/16

CPC分类号： F02M51/0678 ,  F02M61/06 ,  F02B1/04 ,  F02M2051/08

摘要： A fuel injector comprises, a fuel flow adjustment throttle for determining a flow rate of a fuel passing through the fuel injector, a first member having a cylindrical surface for defining partially the fuel flow adjustment throttle, and a second member including a first surface and a second surface both of which extend toward the first member and join each other at a pointed edge defining the fuel flow adjustment throttle together with the cylindrical surface of the first member, and at least one of which forms a space expanding gradually in a fuel flow direction.

摘要翻译： 燃料喷射器包括用于确定通过燃料喷射器的燃料的流量的燃料流量调节节气门，具有用于部分地限定燃料流量调节节气门的圆柱形表面的第一构件，以及包括第一表面和 第二表面两者都朝着第一构件延伸并且与第一构件的圆柱形表面一起限定燃料流量调节节流阀的尖锐边缘彼此连接，并且其中的至少一个形成沿燃料流动方向逐渐扩大的空间 。

公开(公告)号：US07837858B2

公开(公告)日：2010-11-23

申请号：US11992335

申请日：2006-09-21

申请人： Yukihiro Sugiura ,  Yasushi Mizuno

发明人： Yukihiro Sugiura ,  Yasushi Mizuno

IPC分类号： C10G35/04

CPC分类号： H01M8/0612 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/0811 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/127 ,  C01B2203/1288 ,  C01B2203/142 ,  C01B2203/1604 ,  C01B2203/82 ,  H01M8/04223 ,  Y10S585/943

摘要： For shortening the starting time of an autothermal reformer, the autothermal reformer is started by a method comprising: a first preheating step of heating a reforming catalyst up to a predetermined temperature with use of heating means, the heating means being positioned upstream of the reforming catalyst to heat the reforming catalyst; a second preheating step of stopping the heating after arrival at the predetermined temperature, feeding vaporized fuel and air to the reforming catalyst at the predetermined temperature, allowing the fuel to be oxidized by the reforming catalyst and thereby heating the reforming catalyst; and a starting step of also supplying steam to the reforming catalyst heated by the second preheating step and starting autothermal reforming under the condition for a steady state.

摘要翻译： 为了缩短自热重整器的开始时间，自热重整器通过以下方法开始，该方法包括：使用加热装置将重整催化剂加热至预定温度的第一预热步骤，加热装置位于重整催化剂的上游 加热重整催化剂; 第二预热步骤，在到达预定温度之后停止加热，将蒸发的燃料和空气以预定温度供给到重整催化剂，允许燃料被重整催化剂氧化，从而加热重整催化剂; 以及向在第二预热步骤加热的重整催化剂供给蒸汽并在稳定状态下开始自热重整的起始步骤。

公开(公告)号：US20090291336A1

公开(公告)日：2009-11-26

申请号：US12296418

申请日：2007-04-04

申请人： Yasushi Mizuno ,  Osamu Sadakane ,  Yukihiro Sugiura ,  Iwao Anzai

发明人： Yasushi Mizuno ,  Osamu Sadakane ,  Yukihiro Sugiura ,  Iwao Anzai

IPC分类号： H01M8/04 ,  H01M8/18

CPC分类号： H01M8/0668 ,  C01B3/38 ,  C01B3/586 ,  C01B2203/0233 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1064 ,  C01B2203/1247 ,  H01M8/04007 ,  H01M8/0618 ,  H01M8/0637 ,  H01M2008/1293 ,  Y02E60/566

摘要： There are provided an SOFC system using kerosene as a reforming raw material, the SOFC system being capable of effectively cooling the cell and capable of being stably operated with no decreased efficiency, and an operating method thereof. The solid oxide fuel cell system includes reforming means for reforming kerosene to obtain a reformed gas, a methanation catalyst layer disposed downstream of the reforming means and capable of promoting a methanation reaction, cooling means for cooling the methanation catalyst layer, and a solid oxide fuel cell disposed downstream of the methanation catalyst layer. The operating method of a solid oxide fuel cell system includes reforming kerosene to obtain a reformed gas, performing a methanation reaction to increase a methane amount in the reformed gas, and supplying a gas obtained in the methanation to a solid oxide fuel cell.

摘要翻译： 提供了使用煤油作为重整原料的SOFC系统，该SOFC系统能够有效地冷却电池并且能够在不降低效率的情况下稳定运行，以及其操作方法。 固体氧化物燃料电池系统包括用于重整煤油以获得重整气体的重整装置，设置在重整装置下游并能够促进甲烷化反应的甲烷化催化剂层，用于冷却甲烷化催化剂层的冷却装置和固体氧化物燃料 设置在甲烷化催化剂层的下游。 固体氧化物燃料电池系统的操作方法包括重整煤油以获得重整气体，进行甲烷化反应以增加重整气体中的甲烷量，并将在甲烷化中获得的气体供应给固体氧化物燃料电池。

公开(公告)号：US20090197131A1

公开(公告)日：2009-08-06

申请号：US12307520

申请日：2007-06-18

申请人： Yukihiro Sugiura

发明人： Yukihiro Sugiura

IPC分类号： H01M8/18

CPC分类号： H01M8/1246 ,  H01M8/04007 ,  H01M8/04089 ,  H01M8/04223 ,  H01M8/04302 ,  H01M8/0618 ,  H01M8/0625 ,  H01M8/2425 ,  H01M8/2475 ,  Y02P70/56

摘要： An indirect inside reforming SOFC system that enables elimination of the use of hydrogen storage equipment for anode protection at start-up, etc. There is provided an indirect inside reforming solid oxide fuel cell comprising a first reformer for producing a reformate gas from a hydrocarbon fuel with the use of steam reforming reaction; a solid oxide fuel cell for power generation from the reformate gas obtained by the first reformer; and a container for housing both of the first reformer and the solid oxide fuel cell, wherein the first reformer is disposed at a position receiving heat radiation from the solid oxide fuel cell. Further, there is provided an indirect inside reforming solid oxide fuel cell system comprising the indirect inside reforming solid oxide fuel cell and further comprising a second reformer for reforming a hydrocarbon fuel to thereby produce a reformate gas, disposed outside the container; and a line leading the reformate gas obtained by the second reformer from the second reformer to an anode of the solid oxide fuel cell.

摘要翻译： 一种间接内部重整SOFC系统，能够消除在启动等时使用阳极保护的氢存储设备。提供了一种间接内部重整固体氧化物燃料电池，其包括用于从烃燃料生产重整气体的第一重整器 利用蒸汽重整反应; 由第一重整器得到的由重整产气产生的固体氧化物燃料电池; 以及用于容纳所述第一重整器和所述固体氧化物型燃料电池的容器，其中，所述第一重整器设置在从所述固体氧化物型燃料电池接受热辐射的位置。 此外，提供了一种间接内部重整固体氧化物燃料电池系统，其包括间接内部重整固体氧化物燃料电池，并且还包括用于重整烃燃料的第二重整器，从而产生置于容器外部的重整气体; 以及将由第二重整器得到的重整气体从第二重整器引导至固体氧化物型燃料电池的阳极的线。