公开(公告)号：US20060260983A1

公开(公告)日：2006-11-23

申请号：US10548315

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

IPC分类号： C07C37/00 ,  C10G45/04 ,  C10G25/00 ,  C10G45/60

CPC分类号： C10G45/44 ,  B01J29/126 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃 含量不超过1％（体积）。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US20080308459A1

公开(公告)日：2008-12-18

申请号：US11664260

申请日：2005-09-30

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Hirofumi Konno

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Hirofumi Konno

IPC分类号： C10G45/00

CPC分类号： C10G45/52 ,  C10G65/12 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/06

摘要： A process of the present invention for producing a hydrotreated gas oil has a step for obtaining a product oil having a total aromatic content of 3% by volume or less by hydrogenating a hydrotreated oil including 95% by volume or more of fraction having a boiling point range of 150-380° C., a sulfur content of 2-15 ppm by mass, a total aromatic content of 10-25% by volume, and a naphthene of 20-60% by volume in the presence of a hydrogenation catalyst; and a step for obtaining, by hydrogenating the above-described product oil in the presence of a hydrogenation catalyst containing a crystalline molecular sieve component, a product oil satisfying the conditions that the content of petroleum fraction having a boiling point range of lower than 150° C. is 16% by volume or less, and the sum of the total aromatic content and the total naphthene content is 80% or less relative to the sum of these in the hydrotreated oil.

摘要翻译： 用于制备加氢处理瓦斯油的本发明方法具有以下步骤：通过氢化包含95体积％以上的沸点的加氢处理油，得到总芳烃含量为3体积％以下的产物油 在氢化催化剂的存在下，150-380℃的硫含量，2-15质量ppm的硫含量，10-25体积％的总芳族含量和20-60体积％的环烷烃; 以及通过在含有结晶分子筛组分的氢化催化剂存在下氢化上述产物油获得满足沸点范围低于150℃的石油馏分含量的产物的步骤 C为16体积％以下，芳香族化合物总量和总环烷烃含量的总和相对于加氢处理油中的总和为80％以下。

公开(公告)号：US20060211900A1

公开(公告)日：2006-09-21

申请号：US10548313

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

IPC分类号： C07C1/00

CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/20 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a gas oil fraction with a sulfur content of 0.8-2% by mass and a total aromatic content of 20-35% by volume as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst comprising at least one metal from among Group 6A metals and at least one metal from among Group 8 metals as active metals, and under reaction conditions with a reaction temperature of 330-390° C., a hydrogen partial pressure of 12-20 MPa and a liquid hourly space velocity of 0.1-1 h−1, to obtain an ultralow sulfur and low- aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于，使用硫含量为0.8〜2质量％，总芳烃含量为20〜35体积％的粗柴油馏分作为原料油， 在包含至少一种金属的6A族金属和至少一种金属作为活性金属的第8族金属中进行加氢处理，在反应温度为330-390℃的反应条件下，加氢处理 12-20MPa的分压和0.1-1小时-1的液时空速，得到硫含量不大于1ppm的超低硫和低芳烃瓦斯油馏分 并且总芳族含量不大于1体积％。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US20070175797A1

公开(公告)日：2007-08-02

申请号：US11626074

申请日：2007-01-23

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

IPC分类号： C10G45/04 ,  C10G45/60 ,  B01J27/00 ,  B01J27/188 ,  B01J27/19 ,  B01J27/182

CPC分类号： C10G45/08 ,  B01J27/19

摘要： The present invention provides a hydrodesulfurization that can attain an extremely high depth of desulfurization to a sulfur content of 10 ppm by mass and maintain such a high desulfurization activity for a long period of time. The catalyst comprises an inorganic porous support containing alumina and phosphorus, at least one active metal selected from the metals of Group 8 of the periodic table, and at least one metal selected from the metals of Group 6A of the periodic table, the Group 8 metal and the Group 6A metal being contained in a molar ratio defined by (oxide of the Group 8 metal)/(oxide of the Group 6A metal) ranging from 0.055 to 0.150, and the content of the Group 6A metal in terms of oxide being in the range of 30 to 40 percent by mass based on the mass of the catalyst.

摘要翻译： 本发明提供一种能够达到非常高的脱硫深度至硫酸含量为10质量ppm的加氢脱硫，并且长期保持如此高的脱硫活性。 催化剂包括含有氧化铝和磷的无机多孔载体，选自元素周期表第8族金属的至少一种活性金属和选自元素周期表第6A族金属中的至少一种金属，第8族金属 并且6A族金属以（由第8族金属的氧化物）/（6A族金属的氧化物）定义的摩尔比包含在0.055〜0.150的范围内，6A族金属的含量以氧化物为单位 相对于催化剂的质量为30〜40质量％的范围。

公开(公告)号：US06251262B1

公开(公告)日：2001-06-26

申请号：US09377087

申请日：1999-08-19

申请人： Shigeto Hatanaka ,  Osamu Sadakane ,  Hideshi Iki

发明人： Shigeto Hatanaka ,  Osamu Sadakane ,  Hideshi Iki

IPC分类号： C10G6504

CPC分类号： C10G65/04 ,  C10G2400/04

摘要： Diesel gas oil feedstock with 1-3 wt % sulfur can be hydrodesulfurized to a diesel gas oil with 0.05 wt % or less sulfur and a Saybolt color of +20 or higher, by defining a hydrogenation region in a fixed bed reactor with a first hydrogenation zone for dibenzothiophene, 1-, 2- and 3-methyldibenzothiophenes, a second hydrogenation zone for 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene and a third hydrogenation zone for thiols, sulfides and other sulfur-containing substances.

摘要翻译： 通过在具有第一氢化的固定床反应器中限定氢化区域，可以将具有1-3重量％硫的柴油瓦斯油原料加氢脱硫至具有0.05重量％或更少硫并且Saybolt颜色为+ 20以上的柴油瓦斯油 二苯并噻吩，1-，2-和3-甲基二苯并噻吩的区域，4-甲基二苯并噻吩和4,6-二甲基二苯并噻吩的第二氢化区和用于硫醇，硫化物和其它含硫物质的第三氢化区。

公开(公告)号：US09447333B2

公开(公告)日：2016-09-20

申请号：US13130155

申请日：2009-11-19

申请人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

发明人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

IPC分类号： C10L1/24 ,  C10L1/26 ,  C10G3/00 ,  C10L1/04

CPC分类号： C10G3/44 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： The present invention provides an environment friendly aviation fuel base oil having combustibility, oxidation stability and excellent life cycle characteristics and contributing to diversification of primary energy, which is produced by hydrotreating a feedstock comprising a mixed oil of an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat and a sulfur-containing hydrocarbon compound or a feedstock comprising said mixed oil and a petroleum base oil produced by refining crude oil and an aviation fuel composition comprising the aviation fuel base oil, and an aviation fuel composition containing such an aviation fuel base oil.

摘要翻译： 本发明提供一种具有可燃性，氧化稳定性和优异的寿命周期特性的环境友好的航空燃料基础油，并且有助于一次能量的多样化，其通过加氢处理包含源自 动物或植物脂肪和含硫烃化合物或包含所述混合油的原料和通过精炼原油生产的石油基础油和包含航空燃料基础油的航空燃料组合物，以及含有这种航空燃料的航空燃料组合物 基础油

公开(公告)号：US09283552B2

公开(公告)日：2016-03-15

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C07C1/00 ,  B01J29/74 ,  B01J23/883 ,  C10G3/00 ,  C10G45/64 ,  C10L1/04 ,  B01J23/85 ,  B01J29/85

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base, including: a first step of obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6B of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and a second step of obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种生产航空燃料油基料的方法，包括：第一步骤，通过将包含来源于动物或植物油脂的含氧烃化合物的原料与一种原料接触而将原料加氢处理获得第一产生的油 具有脱氢和氢化功能的第一双官能催化剂，其包含周期表第6B族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及第二步骤，通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触，并且包括该组的金属，获得包含航空燃料油基的第二产生的油， 8和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US07914593B2

公开(公告)日：2011-03-29

申请号：US12294110

申请日：2007-02-22

申请人： Masanori Hirose ,  Hideshi Iki

发明人： Masanori Hirose ,  Hideshi Iki

IPC分类号： C10L1/10

CPC分类号： C10G47/16 ,  C10G2/00 ,  C10G45/08 ,  C10G65/14 ,  C10G69/04 ,  C10G2300/1022 ,  C10G2300/1096 ,  C10G2300/301 ,  C10L1/04

摘要： The present invention provides a fuel composition capable of suppressing reduction of fuel consumption, maintaining the excellent exhaust gas properties of a Fischer-Tropsch synthetic oil. The fuel composition comprises a Fischer-Tropsch synthetic oil and a petroleum-based hydrocarbon mixture A having the following properties (1) to (5) in an amount of 10 to 30 percent by volume on the basis of the total mass of the composition: (1) 15° C. density: 800 Kg/cm3 or greater and 900 Kg/m3 or less; (2) 10 volume % distillation temperature (T10): 150° C. or higher and 200° C. or lower; (3) 97 volume % distillation temperature (T97): 270° C. or lower; (4) aromatic content: 40 percent by volume or more and 70 percent by volume or less; and (5) sulfur content: 30 ppm by mass or less.

摘要翻译： 本发明提供能够抑制燃料消耗的降低，维持费 - 托合成油优异的废气性能的燃料组合物。 燃料组合物包含基于组合物的总质量的10至30体积％的具有以下性质（1）至（5）的费 - 托合成油和石油基烃混合物A： （1）15℃密度：800Kg / cm 3以上900kg / m 3以下; （2）10体积％蒸馏温度（T10）：150℃以上且200℃以下; （3）97体积％蒸馏温度（T97）：270℃以下; （4）芳香族含量：40体积％以上且70体积％以下; 和（5）硫含量：30质量ppm以下。

公开(公告)号：US20100219102A1

公开(公告)日：2010-09-02

申请号：US12681787

申请日：2008-10-06

申请人： Shigeto Hatanaka ,  Koji Shimada ,  Hideshi Iki

发明人： Shigeto Hatanaka ,  Koji Shimada ,  Hideshi Iki

IPC分类号： C10G69/02

CPC分类号： C10G11/00 ,  C10G45/02 ,  C10G45/04 ,  C10G65/04 ,  C10G69/04 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/02 ,  C10L1/06

摘要： The production process of the invention comprises a first step of hydrodesulfurizing of catalytically-cracked gasoline so as to result in an olefin hydrogenation rate of no greater than 25 mol % in the catalytically-cracked gasoline, a total sulfur content of no greater than 20 ppm by weight based on the product oil weight, a sulfur content derived from thiophenes and benzothiophenes of no greater than 5 ppm by weight and a sulfur content derived from thiacyclopentanes of no greater than 0.1 ppm by weight, and a second step of further hydrodesulfurizing of the product oil obtained by the first step so as to result in a total of no greater than 30 mol % for the olefin hydrogenation rate in the first step and the olefin hydrogenation rate in the second step, a total sulfur content of no greater than 10 ppm by weight based on the product oil weight, and a sulfur content derived from thiols of no greater than 5 ppm by weight.

摘要翻译： 本发明的制造方法包括催化裂化汽油的加氢脱硫的第一步骤，使催化裂化汽油中的烯烃氢化率不大于25mol％，总硫含量不大于20ppm 基于产品油重量，来自噻吩和苯并噻吩的硫含量不大于5ppm重量，硫代环戊烷的硫含量不大于0.1ppm重量，第二步是进一步加氢脱硫 通过第一步获得的产物油，以使第一步中的烯烃氢化速率和第二步中的烯烃氢化速率总共不大于30mol％，总硫含量不大于10ppm 基于产品油重量，和硫醇的硫含量不大于5重量ppm。

公开(公告)号：US20120217186A1

公开(公告)日：2012-08-30

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。