Method for treating amonia-containing effluent water
    1.
    发明授权
    Method for treating amonia-containing effluent water 失效
    用于处理含有氨的含废水的方法

    公开(公告)号:US07160527B2

    公开(公告)日:2007-01-09

    申请号:US10343754

    申请日:2001-01-12

    IPC分类号: C01B21/02

    摘要: Disclosed are a method and an apparatus for treating an effluent containing ammonia in which method and apparatus N2O concentration in the gas at the outlet of a catalyst tower does not rise to a high level even when the NH3 concentration in the effluent was reduced and the amount of hazardous substances formed is small; in the method and apparatus, an NH3-containing effluent A and a carrier gas (steam C and combustion gas F) are contacted in stripping tower 7 to transfer the NH3 from the NH3-containing effluent to a gas phase, the gas containing the generated NH3 is heated with pre-heater 19 and then contacted with catalyst layer 13 placed in catalyst tower 12 to decompose the NH3 into nitrogen and water; and at that time, the oxygen concentration in the gas to be introduced into catalyst tower 12 and the N2O concentration in the gas discharged from catalyst tower 12 are determined by measuring instruments 21 and 22, respectively, and the oxygen concentration in the gas to be introduced into catalyst tower 12 is adjusted by adjusting valve 17 so that the N2O concentration becomes within a prescribed range.

    摘要翻译: 公开了一种用于处理含氨的流出物的方法和装置,其中催化剂塔出口处的气体中的N 2 O 2浓度的方法和装置即使在NH 流出液中的浓度降低,形成的有害物质的量少; 在该方法和装置中,含有NH 3的流出物A和载气(蒸汽C和燃烧气体F)在汽提塔7中接触以将NH 3 从含NH 3的流出物到气相,含有产生的NH 3的气体用预热器19加热,然后与放置在催化剂中的催化剂层13接触 塔12将NH 3分解成氮和水; 此时,从催化剂塔12排出的气体中的导入催化剂塔12的气体中的氧浓度和N 2 O 2 O浓度分别由测定装置21,22测定, 并且通过调节阀17调节导入催化剂塔12的气体中的氧浓度,使得N 2 O 2浓度变为规定范围。

    Process and apparatus for treating ammonia-containing waste water
    2.
    发明申请
    Process and apparatus for treating ammonia-containing waste water 审中-公开
    用于处理含氨废水的工艺和设备

    公开(公告)号:US20050047981A1

    公开(公告)日:2005-03-03

    申请号:US10343891

    申请日:2001-03-30

    摘要: Disclosed are methods and apparatuses for treating an ammonia-containing effluent in which the amount of hazardous substances such as NOx formed at the time of starting the operation of the apparatus or even at the time when the concentration of ammonia (NH3) in the gas to be subjected to an NH3 decomposing step (described below) was changed is extremely small; in which method an NH3-containing effluent A and vapor (carrier gas) C are contacted in stripping tower 7 to transfer the NH3 from the effluent to a gas phase, a gas containing the NH3 stripped in the tower is heated with pre-heater 1 and then contacted with catalyst 13 to decompose the NH3 into nitrogen and water, the concentration of the NOx (or N2O) contained in the gas resulted at the NH3 decomposing step is determined, and one or more of parameters (a) the amount of the effluent to be supplied to the stripping step, (b) the concentration of the NH3 contained in the effluent, and (c) the flow rate of the NH3-containing gas contacted with the catalyst (when the N2O concentration was determined, one or more of (e′) the flow rate of the carrier gas, (f′) the amount of a gas such as air to be added to the NH3-containing gas, and (g′) the amount of a part of the gas resulted at the NH3 decomposing step and to be circulated) are adjusted responding to the concentration of the NOx (or N2O).

    摘要翻译: 公开了用于处理含氨废水的方法和装置,其中在开始操作装置时形成的有害物质如NOx形成的量甚至在气体中的氨(NH 3)浓度为 经受N​​H3分解步骤(如下所述)变化极小; 在该方法中,含NH 3的流出物A和蒸汽(载气)C在汽提塔7中接触以将NH 3从流出物转移到气相,含有在塔中汽提的NH 3的气体用预热器1 然后与催化剂13接触以将NH 3分解成氮和水,确定包含在气体中的NO x(或N 2 O)在NH 3分解步骤中的浓度,并且参数(a)中的一个或多个 供应到汽提步骤的流出物,(b)流出物中所含的NH 3的浓度,和(c)与催化剂接触的含NH 3气体的流量(当确定N 2 O浓度时,一个或多个 (e')载气的流量,(f')要添加到含NH 3的气体中的诸如空气的气体的量,(g')得到的一部分气体的量 NH 3分解步骤并循环)根据NOx(或N 2 O)的浓度来调节 )。

    Wet-type flue gas desulfurization plant and method making use of a solid
desulfurizing agent
    4.
    发明授权
    Wet-type flue gas desulfurization plant and method making use of a solid desulfurizing agent 失效
    湿式烟气脱硫装置及使用固体脱硫剂的方法

    公开(公告)号:US5686053A

    公开(公告)日:1997-11-11

    申请号:US532759

    申请日:1995-10-11

    摘要: A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.

    摘要翻译: PCT No.PCT / JP95 / 00921 Sec。 371 1995年10月11日第 102(e)1995年10月11日日期PCT提交1995年5月11日PCT公布。 公开号WO95 / 31272 日期:1995年11月23日一种湿式烟气脱硫方法和使用固体脱硫剂的设备,其中从锅炉等燃烧装置排出的废气与吸收液体接触以从排气中吸收硫氧化物 进入吸收液体,然后中和含有如此吸收的硫氧化物的吸收液体。 选择性地将固体脱硫剂保持在吸收液中和区中,从中和区选择性地除去以水为主要成分的吸收液和由吸收的硫氧化物形成的固体产物。 在中和区中,任选地通过向上的空气或水流增加的吸收液体的向上流动形成石灰石颗粒的流化床,从而防止石膏被石膏包覆,从而保持石灰石的反应性。 根据本发明,吸收液中Al和F的共存很少使脱硫性能下降。 此外,可以降低研磨石灰石所需的功率和成本,并且实现更高的脱硫性能。

    Wet-type flue gas desulfurization plant and method making use of a solid
desulfurizing agent
    5.
    发明授权
    Wet-type flue gas desulfurization plant and method making use of a solid desulfurizing agent 失效
    湿式烟气脱硫装置及使用固体脱硫剂的方法

    公开(公告)号:US6080370A

    公开(公告)日:2000-06-27

    申请号:US207152

    申请日:1998-12-08

    摘要: A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.

    摘要翻译: 使用固体脱硫剂的湿式烟道气脱硫方法和设备,其中从锅炉等燃烧装置排出的废气与吸收液体接触,从废气中吸收硫氧化物进入吸收液体,随后 通过中和含有如此吸收的硫氧化物的吸收液体。 选择性地将固体脱硫剂保持在吸收液中和区中,从中和区选择性地除去以水为主要成分的吸收液和由吸收的硫氧化物形成的固体产物。 在中和区中,任选地通过向上的空气或水流增加的吸收液体的向上流动形成石灰石颗粒的流化床,从而防止石膏被石膏包覆,从而保持石灰石的反应性。 根据本发明,吸收液中Al和F的共存很少使脱硫性能下降。 此外,可以降低研磨石灰石所需的功率和成本,并且实现更高的脱硫性能。

    Wet-type flue gas desulfurization plant and method making use of a solid
desulfurizing agent
    6.
    发明授权
    Wet-type flue gas desulfurization plant and method making use of a solid desulfurizing agent 失效
    湿式烟气脱硫装置及使用固体脱硫剂的方法

    公开(公告)号:US5788944A

    公开(公告)日:1998-08-04

    申请号:US532758

    申请日:1995-10-11

    摘要: Exhaust gas from combustion equipment such as a boiler is brought into contact with an absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid. Limestone particles having larger diameters are selectively retained in a zone wherein the absorbing liquid that has absorbed the sulfur oxide from the exhaust gas is neutralized. The absorbing liquid containing water and the gypsum thereby formed, as main constituents, are selectively drained from the neutralizing zone and recycled for renewed contact with the exhaust gas. Because of the possibility of a large decrease of desulfurizing performance due to a variation in the load on the boiler, etc., at least one of the following is monitored: pressure drop across the neutralizing zone, torque of a stirring device, solids concentration in the absorbing liquid, specific gravity of the absorbing liquid and viscosity of the absorbing liquid. Responsive to the monitored parameters outlet SO.sub.2 concentration is controlled within a predetermined range by regulation of at least one of the following: flow rate of the absorbing liquid circulated into contact with the exhaust gas, amount of the solid desulfurizing agent added to the absorbing liquid, particle diameter of the solid desulfurizing agent and speed of agitation of the solid desulfurizing agent in the neutralizing zone.

    摘要翻译: PCT No.PCT / JP95 / 00922 Sec。 371 1995年10月11日第 102(e)1995年10月11日日期PCT提交1995年5月11日PCT公布。 出版物WO96 / 26785 日期1996年6月9日将诸如锅炉的燃烧设备的废气与吸收液体接触,以从废气中吸收硫氧化物进入吸收液体。 具有较大直径的石灰石颗粒选择性地保留在从废气中吸收硫氧化物的吸收液中和的区域中。 作为主要成分的含水和石膏的吸收液体被选择性地从中和区排出并再循环再次与废气接触。 由于锅炉等负荷变化导致脱硫性能大幅下降的可能性在以下至少一项被监测:中和区上的压降,搅拌装置的转矩,固体浓度 吸收液体,吸收液的比重和吸收液体的粘度。 响应于所监测的参数,出口SO2浓度通过调节以下至少一个来控​​制在预定范围内:循环与废气接触的吸收液体的流量,加入吸收液体中的固体脱硫剂的量, 固体脱硫剂的粒径和固体脱硫剂在中和区的搅拌速度。

    Exhaust smoke-processing system
    10.
    发明授权
    Exhaust smoke-processing system 有权
    排烟处理系统

    公开(公告)号:US07651389B2

    公开(公告)日:2010-01-26

    申请号:US10527034

    申请日:2003-09-08

    IPC分类号: B01D47/06

    摘要: An exhaust smoke processing system comprises air preheater for heating combustion air by exhaust smoke discharged from a boiler, a heat recoverer for heating a heat medium by exhaust smoke discharged from the air preheater, a dust collector for collecting soot and dust in exhaust smoke discharged from the heat recoverer, a wet-type exhaust smoke processing apparatus for processing exhaust smoke discharged from the dust collector, a reheater for heating exhaust smoke discharged from the wet-type exhaust smoke processing apparatus by the heat medium, and a heat medium circulation pipe passage for circulating the heating medium between the reheater and the heat recoverer. the system measures a heavy metal concentration in the exhaust smoke and adjusts the temperature of exhaust smoke at an outlet of the heat recoverer such that the measured value falls within a predetermined range.

    摘要翻译: 排气烟处理系统包括用于通过从锅炉排出的排气烟加热燃烧空气的空气预热器,用于通过从空气预热器排出的排气烟加热热介质的热回收器,用于收集从烟气排出的废烟中的烟灰和灰尘的集尘器 热回收器,用于处理从集尘器排出的排气烟的湿式排烟处理装置,用于加热由湿式排气烟处理装置从热介质排出的排气烟的再热器;以及热介质循环管道 用于在加热器和热回收器之间循环加热介质。 该系统测量排气烟雾中的重金属浓度,并调节热回收器出口处的排烟温度,使得测量值落在预定范围内。