摘要:
Disclosed are a method and an apparatus for treating an effluent containing ammonia in which method and apparatus N2O concentration in the gas at the outlet of a catalyst tower does not rise to a high level even when the NH3 concentration in the effluent was reduced and the amount of hazardous substances formed is small; in the method and apparatus, an NH3-containing effluent A and a carrier gas (steam C and combustion gas F) are contacted in stripping tower 7 to transfer the NH3 from the NH3-containing effluent to a gas phase, the gas containing the generated NH3 is heated with pre-heater 19 and then contacted with catalyst layer 13 placed in catalyst tower 12 to decompose the NH3 into nitrogen and water; and at that time, the oxygen concentration in the gas to be introduced into catalyst tower 12 and the N2O concentration in the gas discharged from catalyst tower 12 are determined by measuring instruments 21 and 22, respectively, and the oxygen concentration in the gas to be introduced into catalyst tower 12 is adjusted by adjusting valve 17 so that the N2O concentration becomes within a prescribed range.
摘要翻译:公开了一种用于处理含氨的流出物的方法和装置,其中催化剂塔出口处的气体中的N 2 O 2浓度的方法和装置即使在NH 流出液中的浓度降低,形成的有害物质的量少; 在该方法和装置中,含有NH 3的流出物A和载气(蒸汽C和燃烧气体F)在汽提塔7中接触以将NH 3 从含NH 3的流出物到气相,含有产生的NH 3的气体用预热器19加热,然后与放置在催化剂中的催化剂层13接触 塔12将NH 3分解成氮和水; 此时,从催化剂塔12排出的气体中的导入催化剂塔12的气体中的氧浓度和N 2 O 2 O浓度分别由测定装置21,22测定, 并且通过调节阀17调节导入催化剂塔12的气体中的氧浓度,使得N 2 O 2浓度变为规定范围。
摘要:
Disclosed are methods and apparatuses for treating an ammonia-containing effluent in which the amount of hazardous substances such as NOx formed at the time of starting the operation of the apparatus or even at the time when the concentration of ammonia (NH3) in the gas to be subjected to an NH3 decomposing step (described below) was changed is extremely small; in which method an NH3-containing effluent A and vapor (carrier gas) C are contacted in stripping tower 7 to transfer the NH3 from the effluent to a gas phase, a gas containing the NH3 stripped in the tower is heated with pre-heater 1 and then contacted with catalyst 13 to decompose the NH3 into nitrogen and water, the concentration of the NOx (or N2O) contained in the gas resulted at the NH3 decomposing step is determined, and one or more of parameters (a) the amount of the effluent to be supplied to the stripping step, (b) the concentration of the NH3 contained in the effluent, and (c) the flow rate of the NH3-containing gas contacted with the catalyst (when the N2O concentration was determined, one or more of (e′) the flow rate of the carrier gas, (f′) the amount of a gas such as air to be added to the NH3-containing gas, and (g′) the amount of a part of the gas resulted at the NH3 decomposing step and to be circulated) are adjusted responding to the concentration of the NOx (or N2O).
摘要:
A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.
摘要:
A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.
摘要:
A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.
摘要:
Exhaust gas from combustion equipment such as a boiler is brought into contact with an absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid. Limestone particles having larger diameters are selectively retained in a zone wherein the absorbing liquid that has absorbed the sulfur oxide from the exhaust gas is neutralized. The absorbing liquid containing water and the gypsum thereby formed, as main constituents, are selectively drained from the neutralizing zone and recycled for renewed contact with the exhaust gas. Because of the possibility of a large decrease of desulfurizing performance due to a variation in the load on the boiler, etc., at least one of the following is monitored: pressure drop across the neutralizing zone, torque of a stirring device, solids concentration in the absorbing liquid, specific gravity of the absorbing liquid and viscosity of the absorbing liquid. Responsive to the monitored parameters outlet SO.sub.2 concentration is controlled within a predetermined range by regulation of at least one of the following: flow rate of the absorbing liquid circulated into contact with the exhaust gas, amount of the solid desulfurizing agent added to the absorbing liquid, particle diameter of the solid desulfurizing agent and speed of agitation of the solid desulfurizing agent in the neutralizing zone.
摘要:
An elongated absorber housing, including an inlet duct and an outlet duct, is integrally provided on an upper portion of a circulation tank. The absorber is a self-supporting structure supported by only the circulation tank. At least the furthest upstream spraying stage in a spraying zone in the inlet duct includes spray pipes provided with spray nozzles for spraying an absorbing liquid in a direction cocurrent with gas flow, and at least the furthest downstream spraying stage includes spray nozzles for spraying the absorbing liquid in a direction countercurrent to the gas flow. The absorber is an integral structure in which the upper portion of the circulation tank forms a part of the duct, whereby the absorber is self-supportable and, moreover, is of a simple structure, giving it high strength and eliminating of the need for provision of fitments for supporting the absorber.
摘要:
A system is provided that prevents inhibition of adsorption of Hg and other heavy metals by activated carbon or other heavy metal adsorbent due to prior adsorption of sulfur trioxide (SO3) in an exhaust gas containing SO3. As it has been found that while SO3 is adsorbed, the adsorption of SO3 precedes the adsorption of Hg and other heavy metals onto activated carbon, a basic substance injection system is disposed along an exhaust gas flow channel at an upstream side of an activated carbon injection system, thereby attaining effective removal of Hg and other heavy metals from the exhaust gas by adsorption thereof onto surface pores of the activated carbon. The SO3 concentration after removal by basic substance conversion is computed from the SO3 concentration before removal, and the activated carbon injection rate can be controlled based on the concentration after removal.
摘要:
A desulfurization device releases exhaust gas into the atmosphere without reduction in CO2 recovery rate and without mercury components. Because the absorbent of the desulfurization device is drawn from an absorbent reservoir by a circulating pump and sprayed through spray nozzles into a desulfurization-absorption unit and is mainly circulated outside the wall of a water seal tube by a stirrer in the absorbent reservoir, the flow of the absorbent that falls from the desulfurization-absorption unit into the water seal tube flows in a single direction from top to bottom and hinders the ascension of gas bubbles. Intermixing of the gas for oxidizing the sulfur dioxide with the desulfurization device exhaust gas is thereby prevented, efficient CO2 recovery is possible without reduction in the CO2 concentration recovered from the exhaust gas after desulfurization and mercury in the combustion exhaust gas is absorbed in the absorbent of the desulfurization device.
摘要:
An exhaust smoke processing system comprises air preheater for heating combustion air by exhaust smoke discharged from a boiler, a heat recoverer for heating a heat medium by exhaust smoke discharged from the air preheater, a dust collector for collecting soot and dust in exhaust smoke discharged from the heat recoverer, a wet-type exhaust smoke processing apparatus for processing exhaust smoke discharged from the dust collector, a reheater for heating exhaust smoke discharged from the wet-type exhaust smoke processing apparatus by the heat medium, and a heat medium circulation pipe passage for circulating the heating medium between the reheater and the heat recoverer. the system measures a heavy metal concentration in the exhaust smoke and adjusts the temperature of exhaust smoke at an outlet of the heat recoverer such that the measured value falls within a predetermined range.