公开(公告)号：US06890673B2

公开(公告)日：2005-05-10

申请号：US10068837

申请日：2002-02-11

申请人： Kazutoshi Higashiyama ,  Masahiro Komachiya ,  Kiyoshi Hiyama ,  Tomoichi Kamo ,  Noriyuki Imada ,  Tetsurou Okano ,  Hiroyuki Kaku

发明人： Kazutoshi Higashiyama ,  Masahiro Komachiya ,  Kiyoshi Hiyama ,  Tomoichi Kamo ,  Noriyuki Imada ,  Tetsurou Okano ,  Hiroyuki Kaku

IPC分类号： C01B3/02 ,  B01J19/00 ,  C01B3/32 ,  C01B3/34 ,  C01B3/38 ,  G05B5/01 ,  H01M8/04 ,  H01M8/06 ,  H01M8/10

CPC分类号： B01J19/0013 ,  B01J2219/00063 ,  B01J2219/00164 ,  B01J2219/00198 ,  B01J2219/00202 ,  B01J2219/00213 ,  B01J2219/00231 ,  C01B3/32 ,  C01B3/323 ,  C01B3/34 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0833 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1223 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/127 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/16 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1628 ,  C01B2203/1685 ,  C01B2203/169 ,  C01B2203/1695 ,  C01B2203/82 ,  G05B5/01 ,  H01M8/0612 ,  H01M8/0662

摘要： For the stabilization of the reaction, especially, for maintaining reaction temperature, the feedback control by the feedback unit is performed for to the supply of air (, oxygen, or oxidizing agent), whereas other materials are supplied by the open-loop control according to the instruction of the flow selection unit which indicates a preset value depending on the required hydrogen production volume. In addition, the continuous flow setting unit capable of changing the flow continuously is employed for the supply system of the air, whereas the flow control of the other materials is performed by use of the discrete flow setting units each of which provides the discretized flow by use of the on-off combination of two or more on-off valves.

摘要翻译： 为了稳定反应，特别是为了维持反应温度，反馈单元的反馈控制被执行用于供应空气（，氧气或氧化剂），而其他材料通过开环控制提供，根据 涉及流量选择单元的指示，其指示取决于所需氢气产生量的预设值。 此外，能够连续地改变流量的连续流量设定单元用于空气的供给系统，而其他材料的流量控制通过使用离散流量设定单元进行，每个离散流量设定单元通过离散流量设定单元提供离散流量 使用两个或多个开关阀的开 - 关组合。

公开(公告)号：US20120272626A1

公开(公告)日：2012-11-01

申请号：US13509693

申请日：2010-11-19

申请人： Yoshiaki Mitsui ,  Hidehisa Yoshizako ,  Noriyuki Imada ,  Naoki Oda

发明人： Yoshiaki Mitsui ,  Hidehisa Yoshizako ,  Noriyuki Imada ,  Naoki Oda

IPC分类号： B01D50/00

CPC分类号： F23L7/007 ,  B01D53/343 ,  B01D53/346 ,  B01D53/504 ,  B01D53/508 ,  B01D53/56 ,  B01D53/62 ,  B01D53/75 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/404 ,  B01D2251/606 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  F23C9/003 ,  F23J15/006 ,  F23J15/06 ,  F23J15/08 ,  F23J2215/20 ,  F23J2215/50 ,  F23J2217/10 ,  F23J2217/50 ,  F23J2219/20 ,  F23J2219/70 ,  Y02E20/326 ,  Y02E20/344 ,  Y02E20/346 ,  Y02E20/348 ,  Y02E20/363

摘要： In an exhaust gas treatment device provided with: an exhaust gas treatment unit in which an oxygen combustion boiler 1 using coal as fuel, a denitration device 3, an air preheater 4, a dust-collection device 5, a desulfurization device 6, and a carbon dioxide recovery device 8 are sequentially arranged from the upstream side to the downstream side of an exhaust gas duct; and an exhaust gas circulation unit which branches off from the exhaust gas duct at an outlet of the dust-collection device 5 or an outlet of the desulfurization device 6 and through which the exhaust gas is preheated by the air preheater 4 and returned to the oxygen combustion boiler 1, a heat-recovery heat exchanger 13 that adjusts a gas temperature at an inlet of the dust-collection device 5 to be not greater than an acid dew point of SO3 and not lower than a water dew point is provided between the air preheater 4 and the dust-collection device 5, a reheating heat exchanger 13 that adjusts a gas temperature to be not lower than the acid dew point of SO3 is provided in the vicinity of a branch of the exhaust gas circulation unit, adjusting the gas temperature at the inlet of the dust-collection device 4 to be not greater than the acid dew point of SO3 makes it possible to prevent corrosion of pipes in the exhaust gas circulation unit and to avoid a decrease in fluidity or combustibility of the pulverized coal in the pipes in the mill.

摘要翻译： 在具有：利用煤作为燃料的氧气燃烧锅炉1，脱硝装置3，空气预热器4，集尘装置5，脱硫装置6以及脱硫装置6的废气处理装置的排气处理装置中， 二氧化碳回收装置8从废气导管的上游侧向下游侧依次配置; 以及废气循环单元，其在集尘装置5的出口或脱硫装置6的出口处从废气导管分支，并且废气通过空气预热器4预热并返回到氧气 燃烧锅炉1，将在尘埃捕集装置5的入口处的气体温度调节为不大于SO3的酸露点且不低于露点的热回收热交换器13设置在空气 预热器4和集尘装置5，在废气循环装置的分支附近设置有调节不低于SO3的酸露点的气体温度的再热交换器13，调整气体温度 在集尘装置4的入口处不大于SO3的酸露点使得可以防止废气循环装置中管道的腐蚀并避免流动性或可燃性的降低 在磨机管道中的粉煤。

公开(公告)号：US20130055937A1

公开(公告)日：2013-03-07

申请号：US13697118

申请日：2010-12-27

申请人： Yoshiaki Mitsui ,  Hirofumi Kikkawa ,  Noriyuki Imada ,  Naoki Oda ,  Takanori Nakamoto ,  Hiroyuki Nosaka

发明人： Yoshiaki Mitsui ,  Hirofumi Kikkawa ,  Noriyuki Imada ,  Naoki Oda ,  Takanori Nakamoto ,  Hiroyuki Nosaka

IPC分类号： F23J15/02 ,  B01D53/50

CPC分类号： F23C9/003 ,  B01D53/504 ,  B01D2251/404 ,  B01D2251/602 ,  F23C9/00 ,  F23J15/003 ,  F23J15/006 ,  F23J15/04 ,  F23J2215/10 ,  F23J2215/20 ,  F23J2215/50 ,  F23J2215/60 ,  F23J2217/10 ,  F23J2219/40 ,  F23J2900/15061 ,  F23L7/007 ,  Y02E20/326 ,  Y02E20/344

摘要： A desulfurization device releases exhaust gas into the atmosphere without reduction in CO2 recovery rate and without mercury components. Because the absorbent of the desulfurization device is drawn from an absorbent reservoir by a circulating pump and sprayed through spray nozzles into a desulfurization-absorption unit and is mainly circulated outside the wall of a water seal tube by a stirrer in the absorbent reservoir, the flow of the absorbent that falls from the desulfurization-absorption unit into the water seal tube flows in a single direction from top to bottom and hinders the ascension of gas bubbles. Intermixing of the gas for oxidizing the sulfur dioxide with the desulfurization device exhaust gas is thereby prevented, efficient CO2 recovery is possible without reduction in the CO2 concentration recovered from the exhaust gas after desulfurization and mercury in the combustion exhaust gas is absorbed in the absorbent of the desulfurization device.

摘要翻译： 脱硫装置将废气排放到大气中，而不会降低二氧化碳回收率，没有汞成分。 因为脱硫装置的吸收剂由循环泵从吸收容器中抽出，并且通过喷嘴喷射到脱硫吸收单元中，并且主要通过吸收容器中的搅拌器在水封管的壁外循环， 从脱硫吸收单元落入水封管的吸收剂从上到下沿单一方向流动，并阻止气泡的上升。 因此，防止用于氧化二氧化硫的气体与脱硫装置废气的混合，能够有效地进行二氧化碳回收，而不会降低脱硫后的废气中回收的二氧化碳浓度，并且吸收废气中的汞 脱硫装置。

公开(公告)号：US08778041B2

公开(公告)日：2014-07-15

申请号：US13509693

申请日：2010-11-19

申请人： Yoshiaki Mitsui ,  Hidehisa Yoshizako ,  Noriyuki Imada ,  Naoki Oda

发明人： Yoshiaki Mitsui ,  Hidehisa Yoshizako ,  Noriyuki Imada ,  Naoki Oda

IPC分类号： B01D50/00 ,  B01D39/20 ,  B01D39/06 ,  B01D39/14 ,  B01D24/00 ,  B01D53/34 ,  F23J15/08 ,  B01D53/50 ,  B01D53/75 ,  F23L7/00 ,  F23J15/06 ,  F23J15/00 ,  F23C9/00 ,  B01D53/56 ,  B01D53/62

CPC分类号： F23L7/007 ,  B01D53/343 ,  B01D53/346 ,  B01D53/504 ,  B01D53/508 ,  B01D53/56 ,  B01D53/62 ,  B01D53/75 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/404 ,  B01D2251/606 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  F23C9/003 ,  F23J15/006 ,  F23J15/06 ,  F23J15/08 ,  F23J2215/20 ,  F23J2215/50 ,  F23J2217/10 ,  F23J2217/50 ,  F23J2219/20 ,  F23J2219/70 ,  Y02E20/326 ,  Y02E20/344 ,  Y02E20/346 ,  Y02E20/348 ,  Y02E20/363

摘要： In an exhaust gas treatment device provided with: an exhaust gas treatment unit in which an oxygen combustion boiler 1 using coal as fuel, a denitration device 3, an air preheater 4, a dust-collection device 5, a desulfurization device 6, and a carbon dioxide recovery device 8 are sequentially arranged from the upstream side to the downstream side of an exhaust gas duct; and an exhaust gas circulation unit which branches off from the exhaust gas duct at an outlet of the dust-collection device 5 or an outlet of the desulfurization device 6 and through which the exhaust gas is preheated by the air preheater 4 and returned to the oxygen combustion boiler 1, a heat-recovery heat exchanger 13 that adjusts a gas temperature at an inlet of the dust-collection device 5 to be not greater than an acid dew point of SO3 and not lower than a water dew point is provided between the air preheater 4 and the dust-collection device 5, a reheating heat exchanger 13 that adjusts a gas temperature to be not lower than the acid dew point of SO3 is provided in the vicinity of a branch of the exhaust gas circulation unit, adjusting the gas temperature at the inlet of the dust-collection device 4 to be not greater than the acid dew point of SO3 makes it possible to prevent corrosion of pipes in the exhaust gas circulation unit and to avoid a decrease in fluidity or combustibility of the pulverized coal in the pipes in the mill.

摘要翻译： 在具有：利用煤作为燃料的氧气燃烧锅炉1，脱硝装置3，空气预热器4，集尘装置5，脱硫装置6以及脱硫装置6的废气处理装置的排气处理装置中， 二氧化碳回收装置8从废气导管的上游侧向下游侧依次配置; 以及废气循环单元，其在集尘装置5的出口或脱硫装置6的出口处从废气导管分支，并且废气通过空气预热器4预热并返回到氧气 燃烧锅炉1，将在尘埃捕集装置5的入口处的气体温度调节为不大于SO3的酸露点且不低于露点的热回收热交换器13设置在空气 预热器4和集尘装置5，在废气循环装置的分支附近设置有调节不低于SO3的酸露点的气体温度的再热交换器13，调整气体温度 在集尘装置4的入口处不大于SO3的酸露点使得可以防止废气循环装置中管道的腐蚀并避免流动性或可燃性的降低 在磨机管道中的粉煤。