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1.发明授权Aluminum product having metal diffusion layer, process for producing the same, and paste for metal diffusion treatment 失效具有金属扩散层的铝制品，其制造方法和用于金属扩散处理的糊料
公开(公告)号：US5989734A
公开(公告)日：1999-11-23
申请号：US934754
申请日：1997-09-22
CPC分类号： C23C12/02 , C23C10/30 , Y10T428/12778
摘要： An aluminum product having the metal diffusion layer in the present invention has, on the surface thereof, a metal diffusion layer comprising aluminum and a diffusion metal which is diffused setting aluminum as a matrix and which includes at least one selected from the group consisting of Ni, Cr, Cu, Zn, Mg, Ti and Ag; wherein the diffusion layer is formed by diffusing inclinatorily not less than 1 .mu.m from the surface thereof; and the diffusion metal is not less than 1.0% by weight when the whole of the metal diffusion layer is set to be 100% by weight. Also, in a process for producing an aluminum product having a metal diffusion layer, the surface of the aluminum product is brought into contact with the processing agent including at least the diffusion metal powder; and in this state by conducting heat treatment in the atmosphere including nitrogen, the diffusion metal is diffused on the surface of the aluminum product and the metal diffusion layer is formed. Thus, the present invention supplies the aluminum product having the metal diffusion layer on the surface thereof and the process for producing the aluminum product having this kind of metal diffusion layer on the surface thereof.
摘要翻译： 本发明的具有金属扩散层的铝制品在其表面上具有包含铝和扩散金属的金属扩散层，扩散金属以铝为基质扩散，并且包括选自Ni ，Cr，Cu，Zn，Mg，Ti和Ag; 其特征在于，所述扩散层通过从其表面不均匀地扩散至少1μm而形成。 并且当全部金属扩散层设定为100重量％时，扩散金属不小于1.0重量％。 此外，在具有金属扩散层的铝制品的制造方法中，使铝制品的表面与至少包含扩散金属粉末的处理剂接触， 通过在包括氮的气氛中进行热处理，在该状态下，扩散金属扩散到铝制品的表面，形成金属扩散层。 因此，本发明在其表面上提供具有金属扩散层的铝制品及其表面上具有这种金属扩散层的铝制品的制造方法。
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2.发明授权
公开(公告)号：US6074494A
公开(公告)日：2000-06-13
申请号：US849555
申请日：1997-06-02
申请人： Hirohisa Miura , Yasuhiro Yamada , Haruzo Katoh
发明人： Hirohisa Miura , Yasuhiro Yamada , Haruzo Katoh
IPC分类号： C23C8/24
CPC分类号： C23C8/24
摘要： This invention aims to provide a nitriding method of forming a relatively thick nitride layer on the surface of an aluminum material containing silicon, and an auxiliary agent for nitriding. By using a nitriding auxiliary agent mainly comprising aluminum containing a metal such as lithium or boron, which has a high bonding strength with oxygen, coexists with silicon to form substantially no silicide, or a nitriding auxiliary agent mainly comprising an Al--Mg--Cu alloy or an Mg--Zn--Cu alloy, heat treatment is applied by nitrogen gas with the aluminum material to be nitrided contacted with the nitriding auxiliary agent. Hence, a thick nitride layer can be easily formed even on the surface of an aluminum material containing silicon, and this is most suitable to surface nitride aluminum-silicon alloys, which possess superior castability.
摘要翻译： PCT No.PCT / JP96 / 02912 Sec。 371日期：1997年6月2日 102（e）日期1997年6月2日PCT提交1996年10月2日PCT公布。 公开号WO97 / 13002 PCT 日期1997年04月10日本发明旨在提供一种氮化方法，其在含硅的铝材料的表面上形成相对较厚的氮化物层，以及用于氮化的辅助剂。 通过使用主要包含与氧接触强度高的金属如锂或硼的铝的氮化辅助剂与硅共存，基本上不形成硅化物，或主要包含Al-Mg-Cu合金的氮化助剂 或Mg-Zn-Cu合金，通过氮气对铝材进行氮化氮化处理。 因此，即使在含硅的铝材料的表面上也可以容易地形成厚的氮化物层，最适合于具有优异的铸造性的表面氮化物铝 - 硅合金。
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3.发明授权
公开(公告)号：US5464463A
公开(公告)日：1995-11-07
申请号：US45697
申请日：1993-04-14
申请人： Hirohisa Miura , Kunihiko Imahashi , Hirohumi Michioka , Yasuhiro Yamada , Jun Kusui , Akiei Tanaka
发明人： Hirohisa Miura , Kunihiko Imahashi , Hirohumi Michioka , Yasuhiro Yamada , Jun Kusui , Akiei Tanaka
CPC分类号： C22C21/00 , C22C21/02 , C22C32/00 , C22C32/0073 , F01L3/02 , Y10T428/12007
摘要： Disclosed are heat resistant aluminum alloy powder and alloy including Ni in an amount of from 5.7 to 20% by weight, Si in an amount of from 6.0 to 25% by weight, at least one of Fe in an amount of from 0.6 to 8.0% by weight and Cu in an amount of from 0.6 to 5.0% by weight, and at least one of B in a form of the simple substance in an amount of from 0.05 to 2.0% by weight (or from 0.05 to 10% by weight for the alloy) and graphite particles (especially for the alloy) in an amount of from 0.1 to 10% by weight. The alloy powder and alloy are not only superb in the tensile strength at room temperature and high temperatures but also superior in the sliding characteristic, they can be further upgraded in the wear resistance and the fretting fatigue resistance by dispersing at least one of nitride particles, boride particles, oxide particles and carbide particles in an amount of from 0.5 to 10% by weight with respect to the whole composite material including the matrix taken as 100% by weight in the matrix, thereby resulting in a heat and wear resistant aluminum alloy-based composite materials. The alloy powder, alloy and composite material are satisfactorily applicable to the component parts of the recent automobile engines which should be light-weight and produce a high output.
摘要翻译： 本发明公开了耐热铝合金粉末和合金，其中含有5.7〜20重量％的Ni，6.0〜25重量％的Si，0.6〜8.0重量％的Fe中的至少1种， ，Cu为0.6〜5.0重量％，B为单体形式的B至少为0.05〜2.0重量％（或0.05〜10重量％ 合金）和石墨颗粒（特别是合金），其量为0.1至10重量％。 合金粉末和合金不仅在室温和高温下的抗拉强度优异，而且在滑动特性方面也是优异的，它们可以通过分散氮化物颗粒中的至少一种来进一步提高耐磨性和耐磨性， 硼化物粒子，氧化物粒子和碳化物粒子相对于包含基质的整个复合材料为基准的100重量％的量为0.5〜10重量％，从而得到耐热耐磨的铝合金 - 基复合材料。 合金粉末，合金和复合材料令人满意地适用于最近汽车发动机的部件，重量轻且产量高。
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公开(公告)号：US5614036A
公开(公告)日：1997-03-25
申请号：US594331
申请日：1996-01-30
申请人： Kunihiko Imahashi , Hirohisa Miura , Yasuhiro Yamada , Hirofumi Michioka , Jun Kusui , Akiei Tanaka
发明人： Kunihiko Imahashi , Hirohisa Miura , Yasuhiro Yamada , Hirofumi Michioka , Jun Kusui , Akiei Tanaka
CPC分类号： C22C21/00 , C22C1/0416 , C22C21/02
摘要： A high heat resisting and high abrasion resisting aluminum alloy and aluminum alloy powder have superior toughness, abrasion resistance, high temperature strength, and creep resistance and are useful to form engine parts for automobiles, airplanes, etc. The high heat resisting and high abrasion resisting aluminum alloy comprises 2 to 15 wt % of Ni, 0.2 to 15 wt % of Si, 0.6 to 8.0 wt % of Fe, one or two of 0.6 to 5.0 wt % of Cu and 0.5 to 3 wt % of Mg, the total amount of Cu and Mg being equal to or less than 6 wt %, one or two of 0.3 to 3 wt % of Zr and 0.3 to 3 wt % of Mo, the total amount of Zr and Mo being equal to or less than 4 wt %, 0.05 to 10 wt % of B, and the balance of Al and unavoidable impurities, and is produced by powder metallurgy.
摘要翻译： 高耐热，高耐磨的铝合金和铝合金粉末具有优异的韧性，耐磨性，高温强度和抗蠕变性，可用于形成汽车，飞机等的发动机部件。高耐热性和高耐磨性 铝合金包含2〜15重量％的Ni，0.2〜15重量％的Si，0.6〜8.0重量％的Fe，0.6〜5.0重量％的Cu和0.5〜3重量％的Mg中的1个或2个， 的Cu和Mg等于或小于6重量％，0.3至3重量％的Zr和0.3至3重量％的Mo中的一种或两种，Zr和Mo的总量等于或小于4重量％ ，0.05〜10重量％的B，余量的Al和不可避免的杂质，通过粉末冶金制造。
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5.发明授权
公开(公告)号：US5582655A
公开(公告)日：1996-12-10
申请号：US471752
申请日：1995-06-06
申请人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
发明人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
CPC分类号： C23C8/60
摘要： A case nitrided aluminum product is produced by contacting an aluminum product with a nitriding agent at a part of a surface thereof at least, and by nitriding the aluminum product at the surface with an ambient gas at a temperature of a melting point of the aluminum product or less while keeping the aforementioned contact. The nitriding agent includes an aluminum powder, and the ambient gas virtually includes a nitrogen gas. The resulting nitriding layer has a depth of 5 micrometers or more, and it exhibits a case hardness of from 250 to 1,200 mHv. Thus, it is possible to form the deep and hard nitriding layer on the aluminum product with ease under the conditions where it has been said to be too difficult to nitride aluminum products. The case nitrided aluminum product can appropriately make sliding parts which require high wear resistance.
摘要翻译： 一种氮化铝产品是通过至少在一部分表面上使铝制品与氮化剂接触而制造的，并且通过在铝制品的熔点温度下将表面上的铝产品用环境气体氮化 或更少，同时保持上述接触。 氮化剂包括铝粉末，并且环境气体实际上包括氮气。 得到的氮化层的深度为5微米以上，壳状硬度为250〜1200mHv。 因此，在被认为太难以氮化铝制品的条件下，可以容易地在铝制品上形成深层和硬质氮化层。 氮化铝制品可以适当地制造需要高耐磨性的滑动部件。
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公开(公告)号：US5409661A
公开(公告)日：1995-04-25
申请号：US248546
申请日：1994-05-24
申请人： Kunihiko Imahashi , Hirohisa Miura , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
发明人： Kunihiko Imahashi , Hirohisa Miura , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
IPC分类号： C22C1/10 , C22C21/00 , C22C21/02 , C22C29/06 , C22C29/12 , C22C29/14 , C22C29/16 , C22C32/00 , B22F3/00 , C22C21/04
CPC分类号： C22C32/00
摘要： An aluminum alloy consists essentially of 90 to 99.5% by weight of matrix and 0.5 to 10% by weight of a dispersant dispersed within the matrix. The matrix comprises 10 to 25% by weight of Si, 5 to 20% by weight of Ni, 1 to 5% by weight of Cu and the rest of Al and impurity elements. The dispersant is at least one selected from the group consisting of 0.5 to 10% of nitride, boride, carbide and oxide. The aluminum alloy shows excellent tensile strength and wear resistance.
摘要翻译： 铝合金基本上由90至99.5重量％的基质和0.5至10重量％的分散在基体内的分散体组成。 该基体含有10-25重量％的Si，5-20重量％的Ni，1-5重量％的Cu和其余的Al和杂质元素。 分散剂是选自0.5〜10％的氮化物，硼化物，碳化物和氧化物中的至少一种。 铝合金显示出优异的拉伸强度和耐磨性。
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7.发明授权
公开(公告)号：US5374295A
公开(公告)日：1994-12-20
申请号：US26150
申请日：1993-03-03
申请人： Hirohisa Miura , Kunihiko Imahashi , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
发明人： Hirohisa Miura , Kunihiko Imahashi , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
CPC分类号： C22C32/0047 , C22C1/0416 , C22C21/00 , C22C21/02
摘要： Disclosed are heat resistant aluminum alloy powders and alloys including Ni, Si, either at least one of Fe and Zr or at least one of Zr and Ti. For instance, the alloy powders or alloys consist essentially of Ni in an amount of from 5.7 to 20% by weight, Si in an amount of from 0.2 to 25% by weight, at least one of Fe in an amount of from 0.6 to 8.0% by weight and Cu in an amount of from 0.6 to 5.0% by weight, and the balance of Al. The alloy powders or alloys are optimum for a matrix of heat and wear resistant aluminum alloy-based composite materials including at least one of nitride particles and boride particles in an amount of 0. 5 to 10% by weight with respect to the whole composite material taken as 100% by weight. The alloy powders, alloys and composite materials are satisfactory applicable to the component parts of the recent automobile engines which should produce a high output.
摘要翻译： 公开了耐热铝合金粉末和包括Ni，Si的至少一种Fe，Zr或Zr和Ti中的至少一种的合金。 例如，合金粉末或合金基本上由以重量计为5.7〜20％的Ni，0.2〜25重量％的Si，0.6〜8.0的Fe中的至少1种 重量％，Cu为0.6〜5.0质量％，余量为Al。 合金粉末或合金对于耐热和耐磨铝合金基复合材料的基体是最佳的，其包括相对于整个复合材料为0.5至10重量％的氮化物颗粒和硼化物颗粒中的至少一种 以100重量％计。 合金粉末，合金和复合材料对于应该产生高产量的最近汽车发动机的部件是令人满意的。
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公开(公告)号：US5478418A
公开(公告)日：1995-12-26
申请号：US234578
申请日：1994-04-28
申请人： Hirohisa Miura , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
发明人： Hirohisa Miura , Yasuhiro Yamada , Hirohumi Michioka , Jun Kusui , Akiei Tanaka
CPC分类号： F01L1/14 , C22C1/0416 , F01L2101/00 , F05C2201/021
摘要： An aluminum alloy powder for sliding members includes Fe in an amount of from 0.5 to 5.0% by weight, Cu in an amount of from 0.6 to 5.0% by weight, B in an amount of from 0.1 to 2.0% by weight and the balance of Al. An aluminum alloy includes a matrix made from the aluminum alloy powder and at least one member dispersed, with respect to whole of the matrix taken 100% by weight, in the matrix, and selected from the group consisting of B in an amount of from 0.1 to 5.0% by weight, boride in an amount of from 1.0 to 15% by weight and iron compound in an amount of from 1.0 to 15% by weight, and thereby it exhibits the tensile strength of 400 MPa or more. The aluminum alloy powder and the aluminum alloy are suitable for making sliding members like valve lifters for automobiles.
摘要翻译： 用于滑动构件的铝合金粉末包括0.5至5.0重量％的Fe，0.6至5.0重量％的Cu，0.1至2.0重量％的B，余量为 Al。 一种铝合金包括由铝合金粉末制成的基体和至少一个成分相对于基体中100重量％的整个基体分散，并且选自由0.1组成的组 至5.0重量％，硼化物为1.0至15重量％，铁化合物为1.0至15重量％，因此其拉伸强度为400MPa以上。 铝合金粉末和铝合金适用于制造汽车用气门挺杆等滑动构件。
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公开(公告)号：US5888269A
公开(公告)日：1999-03-30
申请号：US819212
申请日：1997-03-17
申请人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
发明人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
CPC分类号： C23C12/02
摘要： A case nitrided aluminum product is produced by contacting an aluminum product with a nitriding agent at a part of a surface thereof at least, and by nitriding the aluminum product at the surface with an ambient gas at a temperature of a melting point of the aluminum product or less while keeping the aforementioned contact. The nitriding agent includes an aluminum powder, and the ambient gas virtually includes a nitrogen gas. The resulting nitriding layer has a depth of 5 micrometers or more, and it exhibits a case hardness of from 250 to 1,200 mHv. Thus, it is possible to form the deep and hard nitriding layer on the aluminum product with ease under the conditions where it has been said to be too difficult to nitride aluminum products. The case nitrided aluminum product can appropriately make sliding parts which require high wear resistance.
摘要翻译： 一种氮化铝产品是通过至少在一部分表面上使铝制品与氮化剂接触而制造的，并且通过在铝制品的熔点温度下将表面上的铝产品用环境气体氮化 或更少，同时保持上述接触。 氮化剂包括铝粉末，并且环境气体实际上包括氮气。 得到的氮化层的深度为5微米以上，壳状硬度为250〜1200mHv。 因此，在被认为太难以氮化铝制品的条件下，可以容易地在铝制品上形成深层和硬质氮化层。 氮化铝制品可以适当地制造需要高耐磨性的滑动部件。
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10.发明授权
公开(公告)号：US5514225A
公开(公告)日：1996-05-07
申请号：US317525
申请日：1994-10-04
申请人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
发明人： Yasuhiro Yamada , Hirohisa Miura , Mamoru Okamoto , Takashi Matsufuji , Taro Tatsumi , Kazuo Fujii
CPC分类号： C23C8/60
摘要： A case nitrided aluminum product is produced by contacting an aluminum product with a nitriding agent at a part of a surface thereof at least, and by nitriding the aluminum product at the surface with an ambient gas at a temperature of a melting point of the aluminum product or less while keeping the aforementioned contact. The nitriding agent includes an aluminum powder, and the ambient gas virtually includes a nitrogen gas. The resulting nitriding layer has a depth of 5 micrometers or more, and it exhibits a case hardness of from 250 to 1,200 mHv. Thus, it is possible to form the deep and hard nitriding layer on the aluminum product with ease under the conditions where it has been said to be too difficult to nitride aluminum products. The case nitrided aluminum product can appropriately make sliding parts which require high wear resistance.
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