公开(公告)号：US08062460B2

公开(公告)日：2011-11-22

申请号：US12905400

申请日：2010-10-15

申请人： Hiroshi Asano ,  Katsuhiro Horikawa ,  Masachika Takata ,  Masanori Kato

发明人： Hiroshi Asano ,  Katsuhiro Horikawa ,  Masachika Takata ,  Masanori Kato

IPC分类号： B32B37/02 ,  B32B38/04

CPC分类号： H03H3/02 ,  H01L41/083 ,  H01L41/273 ,  H01L41/338 ,  H03H9/178 ,  Y10T29/42 ,  Y10T156/1075 ,  Y10T156/13

摘要： There is provided a laminated piezoelectric ceramic element manufacturing method, wherein, even when the number of internal electrode laminations is increased, the lamination and cutting steps can be simplified, to enhance cutting precision and make cutting cost low. A first laminated body having stripe-like internal electrodes is cut into a plurality of second laminated bodies so as to have a width-direction dimension W corresponding to a width dimension of a laminated piezoelectric ceramic element chip to be ultimately obtained. Two or more second laminated bodies are laminated in the laminating direction to obtain a third laminated body, and the third laminated body is cut in the laminating direction and parallel to the width direction W to obtain a laminated piezoelectric body.

摘要翻译： 提供了一种叠层压电陶瓷元件的制造方法，其中，即使内部电极片的数量增加，也可以简化层压和切割步骤，从而提高切割精度并降低切割成本。 具有条状内部电极的第一层叠体被切割为多个第二层压体，以便具有与最终获得的叠层压电陶瓷元件芯片的宽度尺寸相对应的宽度方向尺寸W. 在层叠方向上层叠两层以上的第二层叠体，得到第三层叠体，在层叠方向上切断第三层叠体，与宽度方向W平行，得到层叠型压电体。

公开(公告)号：US20110024033A1

公开(公告)日：2011-02-03

申请号：US12905400

申请日：2010-10-15

申请人： Hiroshi Asano ,  Katsuhiro Horikawa ,  Masachika Takata ,  Masanori Kato

发明人： Hiroshi Asano ,  Katsuhiro Horikawa ,  Masachika Takata ,  Masanori Kato

IPC分类号： H01L41/22

CPC分类号： H03H3/02 ,  H01L41/083 ,  H01L41/273 ,  H01L41/338 ,  H03H9/178 ,  Y10T29/42 ,  Y10T156/1075 ,  Y10T156/13

摘要： There is provided a laminated piezoelectric ceramic element manufacturing method, wherein, even when the number of internal electrode laminations is increased, the lamination and cutting steps can be simplified, to enhance cutting precision and make cutting cost low. A first laminated body having stripe-like internal electrodes is cut into a plurality of second laminated bodies so as to have a width-direction dimension W corresponding to a width dimension of a laminated piezoelectric ceramic element chip to be ultimately obtained. Two or more second laminated bodies are laminated in the laminating direction to obtain a third laminated body, and the third laminated body is cut in the laminating direction and parallel to the width direction W to obtain a laminated piezoelectric body.

摘要翻译： 提供了一种叠层压电陶瓷元件的制造方法，其中，即使内部电极片的数量增加，也可以简化层压和切割步骤，从而提高切割精度并降低切割成本。 具有条状内部电极的第一层叠体被切割为多个第二层压体，以便具有与最终获得的叠层压电陶瓷元件芯片的宽度尺寸相对应的宽度方向尺寸W. 在层叠方向上层叠两层以上的第二层叠体，得到第三层叠体，在层叠方向上切断第三层叠体，与宽度方向W平行，得到层叠型压电体。

公开(公告)号：US07910016B2

公开(公告)日：2011-03-22

申请号：US12769731

申请日：2010-04-29

申请人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

发明人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

IPC分类号： C04B35/495 ,  H01L41/187 ,  H01L41/24

CPC分类号： H01L41/1873 ,  B32B2311/08 ,  C04B35/495 ,  C04B35/62665 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/656 ,  C04B2237/345 ,  C04B2237/408 ,  H01L41/083

摘要： A main component has a general formula of {(1−x)(K1-a-bNaaLib)m(Nb1-c-dTacSbd)O3−x(M10.5Bi0.5)nM2O3} (wherein M1 is Ca, Sr or Ba, M2 is Ti, Zr or Sn, 0.005≦x≦0.5, 0≦a≦0.9, 0≦b≦0.3, 0≦a+b≦0.9, 0≦c≦0.5, 0≦d≦0.1, 0.9≦m≦1.1, and 0.9≦n≦1.1). At least one specific element selected from the group consisting of In, Sc, Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu is contained at as in sample numbers 46 to 48, 0.1 to 10 mol in total per 100 mols of the main component (preferably, 1.5 to 10 mol). This provides a piezoelectric ceramic composition and a piezoelectric ceramic electronic component that can have a desired high piezoelectric d constant in a consistent and highly efficient manner in both a very low electric field and a high electric field.

摘要翻译： 主要成分为{（1-x）（K1-a-bNaaLib）m（Nb1-c-dTacSbd）O3-x（M10.5Bi0.5）nM2O3}（其中M1为Ca，Sr或Ba ，M2为Ti，Zr或Sn，0.005和nlE; x和nlE; 0.5,0和nlE; a＆nlE; 0.9,0和nlE; b和nlE; 0.3,0和nlE; a + b和nlE; 0.9,0和nlE; c＆nlE; 0.5,0和nlE; d＆nlE; 0.1,0.9＆ ; m＆nlE; 1.1和0.9＆nlE; n＆nlE; 1.1）。 如样品号46〜48,0.1〜10中所含有选自In，Sc，Y，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb和Lu中的至少一种特定元素 相对于主成分（优选为1.5〜10摩尔）优选为100摩尔。 这提供了一种压电陶瓷组合物和压电陶瓷电子部件，其可以在非常低的电场和高电场中以一致和高效的方式具有期望的高压电d常数。

公开(公告)号：US20070001553A1

公开(公告)日：2007-01-04

申请号：US11517484

申请日：2006-09-08

申请人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

发明人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

IPC分类号： H01L41/187

CPC分类号： H01L41/1873 ,  B32B2311/08 ,  C04B35/495 ,  C04B35/62665 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/656 ,  C04B2237/345 ,  C04B2237/408 ,  H01L41/083

摘要： A main component has a general formula of {(1−x)(K1-a-bNaaLib)m(Nb1-c-dTacSbd)O3-x(M10.5Bi0.5)nM2O3} (wherein M1 is Ca, Sr or Ba, M2 is Ti, Zr or Sn, 0.005≦x≦0.5, 0≦a≦0.9, 0≦b≦0.3, 0≦a+b≦0.9, 0≦c≦0.5, 0≦d≦0.1, 0.9≦m≦1.1, and 0.9≦n≦1.1). At least one specific element selected from the group consisting of In, Sc, Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu is contained at as in sample numbers 46 to 48, 0.1 to 10 mol in total per 100 mols of the main component (preferably, 1.5 to 10 mol). This provides a piezoelectric ceramic composition and a piezoelectric ceramic electronic component that can have a desired high piezoelectric d constant in a consistent and highly efficient manner in both a very low electric field and a high electric field.

摘要翻译： 主要组分具有通式{（1-x）（K 1-a b a b a b a b a b b） （Nb 1 -c a）C 3 O 3-x（M 1） 0.5其中M 1为Ca，Sr或Ba，M 2为Ti，Zr或Sn ，0.005 <= x <= 0.5,0 <= a <= 0.9,0 <= b <= 0.3,0 <= a + b <= 0.9,0 <= c <= 0.5,0 <= d <= 0.1 ，0.9 <= m <= 1.1，0.9 <= n <= 1.1）。 如样品号46〜48,0.1〜10中所含有选自In，Sc，Y，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb和Lu中的至少一种特定元素 相对于主成分（优选为1.5〜10摩尔）优选为100摩尔。 这提供了一种压电陶瓷组合物和压电陶瓷电子部件，其可以在非常低的电场和高电场中以一致和高效的方式具有期望的高压电d常数。

公开(公告)号：US20100207494A1

公开(公告)日：2010-08-19

申请号：US12769731

申请日：2010-04-29

申请人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

发明人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

IPC分类号： H01L41/187 ,  H01L41/047

CPC分类号： H01L41/1873 ,  B32B2311/08 ,  C04B35/495 ,  C04B35/62665 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/656 ,  C04B2237/345 ,  C04B2237/408 ,  H01L41/083

摘要： A main component has a general formula of {(1−x)(K1-a-bNaaLib)m(Nb1-c-dTacSbd)O3−x(M10.5Bi0.5)nM2O3} (wherein M1 is Ca, Sr or Ba, M2 is Ti, Zr or Sn, 0.005≦x≦0.5, 0≦a≦0.9, 0≦b≦0.3, 0≦a+b≦0.9, 0≦c≦0.5, 0≦d≦0.1, 0.9≦m≦1.1, and 0.9≦n≦1.1). At least one specific element selected from the group consisting of In, Sc, Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu is contained at as in sample numbers 46 to 48, 0.1 to 10 mol in total per 100 mols of the main component (preferably, 1.5 to 10 mol). This provides a piezoelectric ceramic composition and a piezoelectric ceramic electronic component that can have a desired high piezoelectric d constant in a consistent and highly efficient manner in both a very low electric field and a high electric field.

摘要翻译： 主要成分为{（1-x）（K1-a-bNaaLib）m（Nb1-c-dTacSbd）O3-x（M10.5Bi0.5）nM2O3}（其中M1为Ca，Sr或Ba ，M2为Ti，Zr或Sn，0.005和nlE; x和nlE; 0.5,0和nlE; a＆nlE; 0.9,0和nlE; b和nlE; 0.3,0和nlE; a + b和nlE; 0.9,0和nlE; c＆nlE; 0.5,0和nlE; d＆nlE; 0.1,0.9＆ ; m＆nlE; 1.1和0.9＆nlE; n＆nlE; 1.1）。 如样品号46〜48,0.1〜10中所含有选自In，Sc，Y，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb和Lu中的至少一种特定元素 相对于主成分（优选为1.5〜10摩尔）优选为100摩尔。 这提供了一种压电陶瓷组合物和压电陶瓷电子部件，其可以在非常低的电场和高电场中以一致和高效的方式具有期望的高压电d常数。

公开(公告)号：US20100044568A1

公开(公告)日：2010-02-25

申请号：US12251197

申请日：2008-10-14

申请人： Hideki Ishii ,  Katsuhiro Horikawa ,  Koji Hayashi

发明人： Hideki Ishii ,  Katsuhiro Horikawa ,  Koji Hayashi

IPC分类号： G01J5/02 ,  G01J5/10 ,  C04B35/465

CPC分类号： G01J5/34 ,  C04B35/472 ,  C04B2235/3208 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3279 ,  C04B2235/768 ,  C04B2235/79 ,  C04B2235/81 ,  C04B2235/85 ,  H01L37/025

摘要： A pyroelectric ceramic composition contains a compound represented by (Pb1-xCax)(1+a){(Ni1/3Nb2/3)yTi(1-y)}O3 (wherein x, y, and a satisfy 0.20≦x≦0.27, 0.01≦y≦0.06, and 0.001≦a≦0.02, respectively) as a main component and 0.3 to 2.5 mol of Mn per 100 mol of the main component. The amount of segregates containing Ni, Ti, and Mn is 1.0 vol % or less (including 0 vol %) of a fired sinter. A pyroelectric ceramic composition that has an adequately low insulation resistance and a high Curie temperature while achieving satisfactory pyroelectric properties is realized. Since the composition has a high Curie temperature, a thin, small pyroelectric element that withstands a reflow process can be obtained. Since the composition has a low insulation resistance, an infrared detector incorporating a pyroelectric element composed of the composition does not require a load resistance to be provided in parallel to the pyroelectric element and size reduction is possible.

摘要翻译： 热电陶瓷组合物包含由（Pb1-xCax）（1 + a）{（Ni1 / 3Nb2 / 3）yTi（1-y）} O3表示的化合物（其中x，y和a满足0.20＆nlE; x＆nlE; 0.27 ，0.01＆nlE; y＆nlE; 0.06和0.001＆nlE; a＆nlE; 0.02）和0.3〜2.5mol的Mn / 100mol主成分。 Ni，Ti，Mn的析出物的含量为烧结体的1.0体积％以下（包括0体积％）。 实现了具有足够低绝缘电阻和高居里温度同时实现令人满意的热电性能的热电陶瓷组合物。 由于组成具有高的居里温度，所以可以获得耐受回流处理的薄的小型热电元件。 由于组合物具有低的绝缘电阻，所以并入由该组合物构成的热电元件的红外线检测器不需要与热电元件平行设置负载电阻，并且可以减小尺寸。

公开(公告)号：US06280650B1

公开(公告)日：2001-08-28

申请号：US09544850

申请日：2000-04-06

申请人： Tomoyuki Ogawa ,  Katsuhiro Horikawa

发明人： Tomoyuki Ogawa ,  Katsuhiro Horikawa

IPC分类号： C04B35499

CPC分类号： H01L41/187 ,  C04B35/491

摘要： A piezoelectric buzzer formed by using a piezoelectric ceramic having both a higher heat resistance and a higher piezoelectric characteristics than those of a conventional product. The piezoelectric buzzer 10 of the present invention has a metal plate 12. Formed on the metal plate 12 is a piezoelectric ceramic 14. Further, formed on the piezoelectric ceramic 14 is an electrode 16. The piezoelectric composition forming the piezoelectric ceramic is a piezoelectric ceramic composition characterized in that about 0.2 to 2 mol % of the Pb atoms of a lead zirconate titanate (PZT) represented by the composition formula PbA[(TixZr1-x)a(SnyCr1-y)bSbc]O3 has been displaced by La, wherein 0.94≦A≦1.02, 0.46≦x≦0.51, 0.01≦y≦0.5, 0.01≦b≦0.03, 0.01≦c≦0.04,a+b+c=1.

摘要翻译： 一种压电蜂鸣器，其通过使用具有比常规产品更高的耐热性和更高的压电特性的压电陶瓷形成。 本发明的压电蜂鸣器10具有金属板12.在金属板12上形成压电陶瓷14.此外，形成在压电陶瓷14上的是电极16.形成压电陶瓷的压电组合物是压电陶瓷 其特征在于组成式PbA [（TixZr1-x）a（SnyCr1-y）bSbc] O3表示的锆钛酸铅（PZT）的Pb原子的约0.2〜2摩尔％已被La置换，其中 0.94 <= A <= 1.02,0.46 <= x <= 0.51,0.01 <= y <= 0.5,0.01 <= b <= 0.03,0.01 <= c = 0.04，a + b + c = 1。

公开(公告)号：US06208063B1

公开(公告)日：2001-03-27

申请号：US09433517

申请日：1999-11-03

申请人： Katsuhiro Horikawa ,  Akira Ando

发明人： Katsuhiro Horikawa ,  Akira Ando

IPC分类号： H03H925

CPC分类号： H03H9/02574

摘要： A surface acoustic wave device includes a piezoelectric substrate, and an interdigital transducer provided on the piezoelectric substrate, wherein the piezoelectric substrate includes at least two piezoelectric ceramic layers made of a polycrystalline material. The at least two piezoelectric ceramic layers are stacked so that electrical characteristics and mechanical characteristics thereof vary in a direction that is substantially perpendicular a surface of the piezoelectric substrate upon which the at least two ceramic piezoelectric layers are stacked.

摘要翻译： 表面声波装置包括压电基片和设置在压电基片上的叉指换能器，其中压电基片包括由多晶材料制成的至少两个压电陶瓷层。 堆叠至少两个压电陶瓷层，使得其电特性和机械特性在基本上垂直于其上堆积有至少两个陶瓷压电层的压电基板的表面的方向上变化。

公开(公告)号：US07754095B2

公开(公告)日：2010-07-13

申请号：US11517484

申请日：2006-09-08

申请人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

发明人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

IPC分类号： H01L41/24 ,  H01L41/187 ,  C04B35/495

CPC分类号： H01L41/1873 ,  B32B2311/08 ,  C04B35/495 ,  C04B35/62665 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/656 ,  C04B2237/345 ,  C04B2237/408 ,  H01L41/083

摘要： A main component has a general formula of {(1−x)(K1−a−bNaaLib)m(Nb1−c−dTacSbd)O3−x(M10.5Bi0.5)nM2O3} (wherein M1 is Ca, Sr or Ba, M2 is Ti, Zr or Sn, 0.005≦x≦0.5, 0≦a≦0.9, 0≦b≦0.3, 0≦a+b≦0.9, 0≦c≦0.5, 0≦d≦0.1, 0.9≦m≦1.1, and 0.9≦n≦1.1). At least one specific element selected from the group consisting of In, Sc, Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu is contained at as in sample numbers 46 to 48, 0.1 to 10 mol in total per 100 mols of the main component (preferably, 1.5 to 10 mol). This provides a piezoelectric ceramic composition and a piezoelectric ceramic electronic component that can have a desired high piezoelectric d constant in a consistent and highly efficient manner in both a very low electric field and a high electric field.

摘要翻译： 主要成分为{（1-x）（K1-a-bNaaLib）m（Nb1-c-dTacSbd）O3-x（M10.5Bi0.5）nM2O3}（其中M1为Ca，Sr或Ba ，M2为Ti，Zr或Sn，0.005和nlE; x和nlE; 0.5,0和nlE; a＆nlE; 0.9,0和nlE; b和nlE; 0.3,0和nlE; a + b和nlE; 0.9,0和nlE; c＆nlE; 0.5,0和nlE; d＆nlE; 0.1,0.9＆ ; m＆nlE; 1.1和0.9＆nlE; n＆nlE; 1.1）。 如样品号46〜48,0.1〜10中所含有选自In，Sc，Y，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb和Lu中的至少一种特定元素 相对于主成分（优选为1.5〜10摩尔）优选为100摩尔。 这提供了一种压电陶瓷组合物和压电陶瓷电子部件，其可以在非常低的电场和高电场中以一致和高效的方式具有期望的高压电d常数。

公开(公告)号：US07691286B2

公开(公告)日：2010-04-06

申请号：US11852678

申请日：2007-09-10

申请人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

发明人： Shinichiro Kawada ,  Ryoko Katayama ,  Katsuhiro Horikawa

IPC分类号： C04B35/495 ,  H01L41/24 ,  H01L41/187

CPC分类号： H01L41/273 ,  C04B35/495 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3234 ,  C04B2235/3236 ,  C04B2235/3244 ,  C04B2235/3248 ,  C04B2235/3249 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/5409 ,  C04B2235/5445 ,  C04B2235/768 ,  C04B2235/79 ,  C04B2235/80 ,  H01L41/083 ,  H01L41/1873 ,  H01L41/43

摘要： A piezoelectric ceramic composition includes a primary component represented by the formula (1-x)(K1-a-bNaaLib)m(Nb1-c-dTacSbd)O3-xM1nM2O3, and 0.1 to 10 moles (preferably 1.5 to 10 moles) of at least one specific element selected from the group consisting of In, Sc, Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Lu with respect to 100 moles of the primary component, wherein M1 is Ca, Sr, or Ba M2 is Ti, Zr, or Sn; and x, a, b, c, d, m, and n satisfy 0.005≦x≦0.1, 0≦a≦0.9, 0≦b≦0.3, 0≦a+b≦0.9, 0≦c≦0.5, 0≦d≦0.1, 0.9≦m≦1.1, and 0.9≦n≦1.1. Preferably, Mn, Ni, Fe, Zn, Cu, or Mg is further added. As a result, at both a very low and a high electric field, a high piezoelectric d constant can be stably obtained with a high efficiency.

摘要翻译： 压电陶瓷组合物包括由式（1-x）（K1-a-bNaaLib）m（Nb1-c-dTacSbd）O3-xM1nM2O3表示的主要组分和0.1至10摩尔（优选1.5至10摩尔） 相对于100摩尔主要成分，选自In，Sc，Y，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb和Lu中的至少一种特定元素，其中M1为Ca ，Sr或Ba M2是Ti，Zr或Sn; 并且x，a，b，c，d，m和n满足0.005＆nlE; x＆nlE; 0.1,0和nlE; a＆nlE; 0.9,0和nlE; b＆nlE; 0.3,0和nlE; a + b＆nlE; 0.9,0和nlE; c＆nlE; 0.5,0＆ ; d＆nlE; 0.1,0.9＆nlE; m＆nlE; 1.1和0.9＆amp; nlE; n＆nlE; 1.1。 优选进一步添加Mn，Ni，Fe，Zn，Cu或Mg。 结果，在非常低的电场和高电场下，可以高效率地稳定地获得高的压电d常数。