公开(公告)号：US6166338A

公开(公告)日：2000-12-26

申请号：US214706

申请日：1999-01-11

申请人： Hiroshi Ebato

发明人： Hiroshi Ebato

IPC分类号： G01V9/00 ,  H01B7/10 ,  H01H1/00 ,  H01H3/14 ,  H01H3/16 ,  H01H9/02 ,  H01H13/52 ,  H02G1/06

CPC分类号： H01H3/142 ,  H01B7/104

摘要： A tubular switch which is normally off, instantaneously turned on by external pressure, and has long detection distance. The tubular switch comprises a tubular hose member having insulating property and elasticity, and a plurality of flexible conductive members which are spirally fixed to the internal surface of the hose member so that the surfaces of the conductive members should be partially exposed to the internal space of the hose member at any section of the hose member. The tubular switch has durability, can be installed any place, and can have a long detection range, and, in addition, any faults are easily found, repaired and adjusted, it has a simple structure and flexibility, and it can be manufactured at a low cost.

摘要翻译： PCT No.PCT / JP97 / 02356 Sec。 371日期1999年1月11日 102（e）1999年1月11日PCT PCT 1997年7月8日PCT公布。 出版物WO98 / 01875 日期1998年1月15日一种通常由外部压力瞬时开启的管状开关，并具有较长的检测距离。 管状开关包括具有绝缘性和弹性的管状软管构件，以及多个柔性导电构件，其螺旋地固定到软管构件的内表面，使得导电构件的表面应部分地暴露于软管构件的内部空间 软管构件在软管构件的任何部分处。 管状开关具有耐用性，可以安装在任何地方，并且可以具有较长的检测范围，另外，容易发现，修理和调整任何故障，结构简单，灵活性高，可以在 低成本。

公开(公告)号：US5403897A

公开(公告)日：1995-04-04

申请号：US217719

申请日：1994-03-25

申请人： Hiroshi Ebato ,  Satoshi Oya ,  Yasutoshi Kakizawa ,  Hideyuki Furuta ,  Kosuke Arai

发明人： Hiroshi Ebato ,  Satoshi Oya ,  Yasutoshi Kakizawa ,  Hideyuki Furuta ,  Kosuke Arai

IPC分类号： C08G63/08 ,  C08G63/60 ,  C08G63/78 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04 ,  C08F20/00 ,  B32B27/36

CPC分类号： C08L67/00 ,  C08G63/60 ,  Y10T428/31786

摘要： A process for producing a lactic acid-based copolyester by the ring-opening copolymerization and transesterification of a lactide (A) with an aromatic polyester (B) and/or an aliphatic polyester (C) in the presence of a ring-opening polymerization catalyst (D), and a packaging material comprising the lactic acid-based copolyester obtained by the process are disclosed. According to the present invention, a lactic acid-based degradable copolyester which has a sufficiently high molecular weight and satisfactory toughness and also has suitable rigidity, pliability, and transparency according to applications can be produced. Further, a general-purpose packaging material, e.g., a sheet or film, which comprises the lactic acid-based copolyester produced by the process and is excellent in formability, degradability, and transparency can also be produced.

摘要翻译： 一种通过在开环聚合催化剂存在下通过丙交酯（A）与芳族聚酯（B）和/或脂族聚酯（C）的开环共聚和酯交换反应生产乳酸基共聚酯的方法 （D），以及包含通过该方法得到的乳酸类共聚聚酯的包装材料。 根据本发明，可以制备具有足够高的分子量和令人满意的韧性并且根据应用具有合适的刚性，柔韧性和透明度的乳酸类可降解共聚酯。 此外，还可以制造包含通过该方法制备并且成形性，降解性和透明性优异的乳酸类共聚酯的通用包装材料，例如片材或薄膜。

公开(公告)号：US5889073A

公开(公告)日：1999-03-30

申请号：US959981

申请日：1997-10-29

申请人： Husheng Zhang ,  Takanori Anazawa ,  Hiroshi Ebato

发明人： Husheng Zhang ,  Takanori Anazawa ,  Hiroshi Ebato

IPC分类号： C08J3/28 ,  C08J5/00 ,  D01F8/04 ,  D06M14/26 ,  D06M14/28 ,  D06M14/30 ,  C08F2/46 ,  C08F16/06 ,  C08J9/04

CPC分类号： D06M14/26 ,  C08J3/28 ,  C08J5/00 ,  D01F8/04 ,  D06M14/28 ,  D06M14/30

摘要： Disclosed is a process for producing a material having hydrophilic surface which comprises forming a hydrophobic photopolymerizable composition comprising a hydrophobic compound (a) having two or more polymerizable unsaturated double bonds per molecule and a photopolymerization initiator into a desired form and irradiating the resultant shape (b) with actinic rays while keeping the surface of the shape (b) in contact with a hydrophilic liquid (d) containing a hydrophilic compound (c) having one or more polymerizable unsaturated double bonds under such conditions that a photopolymerization reaction is prevented from occurring in the hydrophilic liquid (d) except at the interface between the liquid (d) and the shape (b), whereby the shape (b) is cured and, at the same time, the hydrophobic compound (a) is copolymerized with the hydrophilic compound (c) at the interface between the shape (b) and the hydrophilic liquid (d) to chemically bond molecules of the hydrophilic compound (c) to the surface of the hydrophobic shape (b). The process is advantageous in that the kind and density of hydrophilic groups can be easily controlled and the structure and properties inherent in the material formed from the photopolymerizable composition are not impaired.

摘要翻译： 公开了一种具有亲水性表面的材料的制造方法，其包括形成疏水性光聚合性组合物，该组合物包含每分子具有两个以上聚合性不饱和双键的疏水性化合物（a）和光聚合引发剂，并照射所形成的形状（b ），同时保持形状（b）的表面与含有具有一个或多个可聚合不饱和双键的亲水性化合物（c）的亲水性液体（d）接触，所述亲水性化合物（c）在防止光聚合反应发生的条件下 除了液体（d）和形状（b）之间的界面之外的亲水性液体（d），由此形状（b）固化，并且同时疏水性化合物（a）与亲水性化合物 （c）在形状（b）和亲水性液体（d）之间的界面处化学键合亲水性化合物（c）的分子与 疏水形状的表面（b）。 该方法的优点在于可以容易地控制亲水基团的种类和密度，并且不损害由可光聚合组合物形成的材料固有的结构和性质。

公开(公告)号：US5470188A

公开(公告)日：1995-11-28

申请号：US44153

申请日：1993-04-08

申请人： Hiroshi Ebato

发明人： Hiroshi Ebato

IPC分类号： B60P1/44 ,  B60P1/26

CPC分类号： B60P1/4457 ,  B60P1/4414 ,  B60P1/4421

摘要： A lift for loading and unloading a truck. The truck has a loading chamber, a rear body portion and a chassis frame, and the lift has support posts mounted at an end and at each side of the truck at the rear body portion. A connecting member connecting the lower ends of each support post is provided. A drive moves the support posts in an upward and downward direction. A lift table has an opening formed in a portion corresponding to the chassis frame. The lift table is supported by the connecting member and is slidable on the connecting member in a longitudinal direction to the loading chamber thereby traversing the connecting member.

摘要翻译： 用于装卸卡车的电梯。 卡车具有装载室，后主体部分和底盘框架，并且升降机具有安装在卡车的后部主体部分的端部和两侧的支撑柱。 提供连接每个支柱的下端的连接构件。 驱动器使支撑柱向上和向下移动。 升降台具有形成在与底架相对应的部分中的开口。 升降台由连接构件支撑，并且能够在连接构件上沿纵向方向滑动到装载室，从而穿过连接构件。

公开(公告)号：US5616657A

公开(公告)日：1997-04-01

申请号：US503608

申请日：1995-07-18

申请人： Shoji Imamura ,  Hiroshi Ebato

发明人： Shoji Imamura ,  Hiroshi Ebato

IPC分类号： C08G63/60 ,  C08F20/00

CPC分类号： C08G63/60

摘要： A novel process for the preparation of a high molecular lactic copolymer polyester is provided, which includes allowing a lactide (A), a polyester terminated by hydroxyl group at both ends (B1), a polyvalent carboxylic acid having 3 or more functionalities and/or acid anhydride thereof (C) to undergo ring opening copolymerization in the presence of a ring opening polymerization catalyst (D). A novel process is also provided which includes allowing the lactide (A) and the polyester (B1) to undergo ring opening copolymerization in the presence of the catalyst (D) to prepare a polyester, and then reacting the polyester with the component (C). A novel process is further provided which includes reacting the polyester (B1) with the polyvalent carboxylic acid component (C) to obtain a polyester terminated by hydroxyl group at both ends having a weight-average molecular weight of from 10,000 to 300,000 (B2), and then allowing the polyester (B2) and the lactide (A) to undergo ring opening copolymerization in the presence of the catalyst (D). Another novel process is provided which includes allowing a dicarboxylic acid, a diol and the polyvalent carboxylic acid component (C) to undergo dehydration reaction and/or deglycolation reaction to obtain a polyester having a weight-average molecular weight of from 10,000 to 300,000 (B3), and then allowing the polyester (B3) and the lactide (A) to undergo ring opening copolymerization in the presence of the catalyst (D).

摘要翻译： 提供了一种制备高分子量乳酸共聚物聚酯的新方法，其包括使丙交酯（A），两端用羟基封端的聚酯（B1），具有3个或更多个官能团的多元羧酸和/或 其酸酐（C）在开环聚合催化剂（D）的存在下进行开环共聚。 还提供了一种新颖的方法，其包括使丙交酯（A）和聚酯（B1）在催化剂（D）的存在下进行开环共聚以制备聚酯，然后使聚酯与组分（C）反应， 。 进一步提供一种新的方法，其包括使聚酯（B1）与多元羧酸组分（C）反应，得到重均分子量为10,000至300,000（B2）的两端用羟基封端的聚酯， 然后在催化剂（D）的存在下使聚酯（B2）和丙交酯（A）进行开环共聚。 提供另一种新方法，其包括使二羧酸，二醇和多价羧酸组分（C）进行脱水反应和/或脱醇反应，得到重均分子量为10,000至300,000（B3 ），然后在催化剂（D）的存在下使聚酯（B3）和丙交酯（A）进行开环共聚。

公开(公告)号：US5605981A

公开(公告)日：1997-02-25

申请号：US672917

申请日：1996-06-28

申请人： Shoji Imamura ,  Hiroshi Ebato

发明人： Shoji Imamura ,  Hiroshi Ebato

IPC分类号： C08G63/60 ,  C08F20/00

CPC分类号： C08G63/60

摘要： The present invention provides a process for the preparation of a decomposable lactic copolymer polyester which exhibits a sufficiently high molecular weight, heat resistance and thermal stability and further exhibits a rigidity, flexibility and transparency depending on the purpose. The process for the preparation of a high molecular lactic copolymer polyester includes reacting a polyester terminated by hydroxyl group at both ends (B1) with a polyvalent isocyanate (E) having 2 or more functionalities to obtain a polyester (B4) having a weight-average molecular weight of from 10,000 to 300,000, and then allowing said polyester (B4) and lactide (A) to undergo ring opening copolymerization in the presence of a ring opening polymerization catalyst (D). A process is also provided which includes allowing a lactide (A) and a polyester terminated by hydroxyl group at both ends (B1) to undergo ring opening copolymerization in the presence of a ring opening polymerization catalyst (D) to prepare a polyester having a weight-average molecular weight of from 10,000 to 300,000, and then reacting said polyester with a polyvalent isocyanate having 3 or more functionalities.

摘要翻译： 本发明提供了一种制备可分解乳酸共聚物聚酯的方法，其具有足够高的分子量，耐热性和热稳定性，并且根据目的还显示出刚性，柔韧性和透明度。 制备高分子量乳液共聚物聚酯的方法包括使两末端具有羟基的聚酯（B1）与具有2个或更多个官能团的多价异氰酸酯（E）反应，得到重均分子量的聚酯（B4） 分子量为10,000〜300,000，然后在开环聚合催化剂（D）的存在下使所述聚酯（B4）和丙交酯（A）进行开环共聚。 还提供了一种方法，其包括在开环聚合催化剂（D）的存在下使丙交酯（A）和由两端被羟基封端的聚酯（B1）进行开环共聚以制备具有重量的聚酯 - 平均分子量为10,000至300,000，然后使所述聚酯与具有3个或更多个官能团的多价异氰酸酯反应。

公开(公告)号：US5525671A

公开(公告)日：1996-06-11

申请号：US364097

申请日：1994-12-27

申请人： Hiroshi Ebato ,  Shoji Imamura

发明人： Hiroshi Ebato ,  Shoji Imamura

IPC分类号： C08G63/00 ,  C08G63/08 ,  C08G63/664 ,  C08G63/78 ,  C08G63/91

CPC分类号： C08G63/00 ,  C08G63/08 ,  C08G63/664 ,  C08G63/78

摘要： A process for continuously producing a linear lactide copolymer having a weight-average molecular weight of from 20,000 to 400,000 using a continuous reaction apparatus composed of three or more stirred flow reactors connected in series, which process comprises the steps of continuously feeding from 50 to 98 parts by weight of a lactide and from 2 to 50 parts by weight of a polymer having a hydroxyl group in a molten state or as dissolved in a solvent to the first reactor of said continuous reaction apparatus, and transferring the reaction mixture from said first reactor to the following reactors successively while maintaining the reaction pressure and the reaction temperature in every reactor in the range of from 1 to 5 atm. and of from 140.degree. to 210.degree. C., respectively, to conduct ring opening copolymerization. According to the process of the present invention, the production problems associated with conventional continuous production methods for lactide copolymers, i.e., high viscosity of the reaction system, thermal decomposition of the polymer produced, and coloration of the polymer produced can be eliminated, and a degradable lactide copolymer endowed with broader range properties than conventional lactide copolymers and therefore useful in wider fields can be obtained continuously and efficiently.

摘要翻译： 一种使用连续反应装置连续制造重均分子量为20,000〜400,000的直链丙交酯共聚物的方法，该连续反应装置由串联连接的三个或更多个搅拌流动反应器组成，该方法包括以下步骤：从50至98 重量份的丙交酯和2至50重量份的具有熔融状态的羟基或溶解在所述连续反应装置的第一反应器中的溶剂的聚合物，并将反应混合物从所述第一反应器 将反应压力和每个反应器中的反应温度保持在1〜5atm的范围内，连续进行下列反应器。 分别为140〜210℃，进行开环共聚。 根据本发明的方法，可以消除与常规的丙交酯共聚物的连续制备方法相关的生产问题，即反应体系的高粘度，所生产的聚合物的热分解和所生产聚合物的着色， 可降解丙交酯共聚物具有比常规丙交酯共聚物更宽的范围性质，因此可以连续有效地获得更广泛的领域。