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    Siloxane compounds
    1.
    发明授权
    Siloxane compounds 失效
    硅氧烷化合物

    公开(公告)号：US5196558A

    公开(公告)日：1993-03-23

    申请号：US925147

    申请日：1992-08-06

    申请人： Hiroshi Inomata ,  Yasushi Yamamoto ,  Yasuo Tarumi ,  Kenichi Fukuda

    发明人： Hiroshi Inomata ,  Yasushi Yamamoto ,  Yasuo Tarumi ,  Kenichi Fukuda

    IPC分类号： C07F7/08

    CPC分类号： C07F7/0852 ,  C07F7/0896

    摘要： Novel siloxane compounds are provided which have 1-5 hydrogen atoms each attached to a silicon atom (SiH group) and 1-5 epoxy or alkoxy - containing organic groups each attached to a silicon atom in a molecule. These siloxane compounds are useful tackifiers to conventional resins, have good affinity to fluorinated silicone resins and rubbers so that they impart adhesion to fluorinated silicone resins and rubbers, and contribute to solvent resistance and minimal moisture permeability.

    摘要翻译： 提供了新的硅氧烷化合物，其具有各自连接到硅原子（SiH基团）上的1-5个氢原子和分别连接到硅原子上的1-5个环氧基或含烷氧基的有机基团。 这些硅氧烷化合物是常规树脂的有用的增粘剂，对氟化硅树脂和橡胶具有良好的亲和性，使得它们赋予氟化硅树脂和橡胶粘合性，并且有助于耐溶剂性和最小的透湿性。

    Fluoroorganopolysiloxane and a process for preparing the same
    3.
    发明授权
    Fluoroorganopolysiloxane and a process for preparing the same 失效
    氟代聚氧乙烯醚及其制备方法

    公开(公告)号：US5118775A

    公开(公告)日：1992-06-02

    申请号：US481208

    申请日：1990-02-20

    申请人： Hiroshi Inomata ,  Yasuo Tarumi

    发明人： Hiroshi Inomata ,  Yasuo Tarumi

    IPC分类号： C08G77/06 ,  C08G77/22 ,  C08G77/24

    CPC分类号： C08G77/24

    摘要： A fluoroorganopolysiloxane having the following general unit formula (I): ##STR1## wherein R.sup.1 represents a fluorine-containing organic group represented by the following formula:F--(--C.sub.g F.sub.2g O--).sub.d --C.sub.h F.sub.2h CH.sub.2 --whered represents an integer of from 1 to 5, g represents an integer of from 1 to 3, and h is an integer of 1 or 2,R.sup.2 represents a divalent hydrocarbon group containing no fluorine atom,R.sup.3 represents a hydrocarbon group containing no fluorine atom,a is a number of from 0.001 to 0.34,b is a number of from 1.64 to 2.34,c is a number of from 0 to 0.67, and a+b+c ranges from 1.90 to 2.67,and having a viscosity of not less than 1.times.10.sup.6 at 25.degree. C., and a process for preparing the same. This polymer is useful as a raw material of heat-vulcaization type fluorosilicone rubber.

    摘要翻译： 具有以下通式（I）的氟代有机聚硅氧烷：其中R1表示由下式表示的含氟有机基团：F - （ - CgF2gO-）d-ChF2hCH2-其中d表示 1〜5，g表示1〜3的整数，h为1或2的整数，R 2表示不含氟原子的二价烃基，R 3表示不含氟原子的烃基，a为数 为0.001〜0.34，b为1.64〜2.34的数，c为0〜0.67的数，a + b + c为1.90〜2.67，25℃时的粘度为1×10 6以上 C.及其制备方法。 该聚合物可用作热氧化型氟硅橡胶的原料。

    Method for the preparation of a fluorine-containing organopolysiloxane
    5.
    发明授权
    Method for the preparation of a fluorine-containing organopolysiloxane 失效
    制备含氟有机聚硅氧烷的方法

    公开(公告)号：US5639845A

    公开(公告)日：1997-06-17

    申请号：US551339

    申请日：1995-11-01

    申请人： Hiroshi Inomata ,  Yasushi Yamamoto ,  Yasuo Tarumi ,  Noriyuki Koike ,  Kouichi Ishida

    发明人： Hiroshi Inomata ,  Yasushi Yamamoto ,  Yasuo Tarumi ,  Noriyuki Koike ,  Kouichi Ishida

    IPC分类号： C08G77/385 ,  C08G77/08

    CPC分类号： C08G77/385

    摘要： A novel and very efficient method is disclosed for the introduction of perfluoroalkyl groups into an organopolysiloxane by utilizing the hydrosilation reaction with an organohydrogenpolysiloxane. Different from the conventional but inefficient hydrosilation reaction using a perfluoroalkyl-substituted ethylene as the olefin compound, the inventive method utilizes a propene-1 3-substituted by a perfluoroalkyl group compound as the olefin compound to react with an organohydrogenpolysiloxane by which a very high efficiency in the hydrosilation reaction can be obtained without side reactions which otherwise greatly decrease the yield of the desired perfluoroalkyl-containing organopolysiloxane product.

    摘要翻译： 公开了一种通过利用有机氢聚硅氧烷的氢硅化反应将全氟烷基引入有机聚硅氧烷的新颖而非常有效的方法。 与使用全氟烷基取代的乙烯作为烯烃化合物的常规但低效的硅氢化反应不同，本发明的方法利用由全氟烷基化合物作为烯烃化合物取代的丙烯-1,3-与有机氢聚硅氧烷反应，通过该有机氢聚硅氧烷具有非常高的效率 在氢化硅烷化反应中可以获得无副反应，否则大大降低了所需的含全氟烷基的有机聚硅氧烷产物的产率。

    Process for preparing a fluoroorganopolysiloxane
    9.
    发明授权
    Process for preparing a fluoroorganopolysiloxane 失效
    制备氟代甘油醚的方法

    公开(公告)号：US5116928A

    公开(公告)日：1992-05-26

    申请号：US481240

    申请日：1990-02-20

    申请人： Hiroshi Inomata ,  Yasuo Tarumi

    发明人： Hiroshi Inomata ,  Yasuo Tarumi

    IPC分类号： C07F7/21 ,  C08G77/06 ,  C08G77/22 ,  C08G77/24

    CPC分类号： C08G77/24 ,  C07F7/21

    摘要： A process for preparing a fluoroorganopolysiloxane having a fluorine-containing organic group represented by the following formula:F--(--C.sub.g F.sub.2g O--).sub.d --C.sub.h F.sub.2h CH.sub.2 --where d represents an integer of from 1 to 5, g represents an integer of from 1 to 3, and h is 1 or 2, comprising the steps of:polymerizing a monomer comprising a fluorine-containing cyclotrisiloxane having the following formula (II): ##STR1## wherein R.sup.1 represents the above fluorine-containing organic group, R.sup.2 is a fluorine-free hydrocarbon group, and R.sup.3 is a fluorine-free divalent hydrocarbon group, in the presence of an acidic catalyst or a basic catalyst, and in the presence of a water at a temperature of not higher than 80.degree. C., andneutralizing the resulting polymerization product. This process can produce the above polymer containing little low molecular weight compounds and having a desired polymerization degree in a good yield.

    Curable compositions and cured gel parts thereof
    10.
    发明授权
    Curable compositions and cured gel parts thereof 有权
    可固化组合物及其固化凝胶部分

    公开(公告)号：US6127504A

    公开(公告)日：2000-10-03

    申请号：US219866

    申请日：1998-12-24

    申请人： Kenichi Fukuda ,  Yasuo Tarumi

    发明人： Kenichi Fukuda ,  Yasuo Tarumi

    IPC分类号： C08K5/02 ,  C08G65/00 ,  C08L83/05 ,  C08G77/08 ,  C08G77/24

    CPC分类号： C08G65/007

    摘要： A linear polyfluoro compound having at least two alkenyl groups as a base component is blended with a linear polyfluoro compound having one alkenyl group and a hydrosilyl-bearing linear polysiloxane having fluoroalkyl substituents in side chains and at ends thereof. With a platinum catalyst added, there is obtained a curable composition having improved storage stability which will quickly cure into satisfactory gel products.

    摘要翻译： 具有至少两个烯基作为基础成分的线性多氟化合物与具有一个烯基的线性多氟化合物和在侧链和末端具有氟代烷基取代基的含支链氢原子的直链聚硅氧烷共混。 通过添加铂催化剂，得到具有改善的储存稳定性的可固化组合物，其将快速固化成满意的凝胶产物。