公开(公告)号：US4264565A

公开(公告)日：1981-04-28

申请号：US121095

申请日：1980-02-13

申请人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

发明人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

IPC分类号： C01B21/068 ,  C04B35/584 ,  C01B21/06

CPC分类号： C04B35/584 ,  C01B21/0685 ,  C01P2004/61 ,  C01P2006/80

摘要： A method for producing powder of .alpha.-silicon nitride which comprises the steps of:adding 0.3 to 2 parts by weight of powder of carbon and 0.005 to 1 paret by weight of at least one silicon compound selected from the group consisting of Si.sub.3 N.sub.4, SiC and silicon oxide nitride series compounds to one part by weight (as converted to SiO.sub.2) to a liquid silane derivative which produces a precipitate and HCl by hydrolysis and further causes SiO.sub.2 to be grown by the baking of said precipitate, or the precipitate produced by hydrolysis of the liquid silane derivatives;hydrolyzing the resultant mixture, if necessary;washing the mixture to separate a solid component, if necessary; andbaking the solid component for reduction and nitrogenization at a temperature of 1300.degree. to 1500.degree. C. in an atmosphere mainly consisting of a nitrogen gas or a gas of a nitrogen compound.

摘要翻译： 一种生产α-氮化硅粉末的方法，包括以下步骤：将0.3至2重量份的碳粉和0.005至1重量份的至少一种选自Si 3 N 4，SiC的硅化合物和 氧化硅氮化物系列化合物与1重量份（转化为SiO 2）相对于通过水解产生沉淀物和HCl的液体硅烷衍生物，并且进一步通过焙烧所述沉淀生成SiO 2或通过水解生成的沉淀 液体硅烷衍生物; 如果需要，水解所得混合物; 如果需要，洗涤混合物以分离固体组分; 在1300〜1500℃的温度下，在氮气或氮化合物气体的气氛中焙烧固体成分。

公开(公告)号：US4615863A

公开(公告)日：1986-10-07

申请号：US768137

申请日：1985-08-22

申请人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

发明人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

IPC分类号： C01B21/072 ,  C04B35/581 ,  B22F1/00

CPC分类号： C04B35/581 ,  C01B21/0726

摘要： A process for producing readily sinterable aluminum nitride powder, which comprises mixing(i) alumina powder and/or powder of a compound capable of forming alumina by heat treatment,(ii) carbon powder and/or powder of a compound capable of forming carbon by heat treatment, and(iii) powder of at least one compound selected from the group consisting of alkaline earth metal oxides, compounds capable of forming said alkaline earth metal oxides by heat treatment, rare earth element oxides and compounds capable of forming said rare earth element oxides by heat treatment,and calcining the resulting mixture in a nitrogen-containing non-oxidative atmosphere, provides an aluminum nitride powder which is readily sinterable without further mixing with a sintering aid.

摘要翻译： 一种制造容易烧结的氮化铝粉末的方法，其包括通过热处理将（i）能够形成氧化铝的化合物的氧化铝粉末和/或粉末混合（ii）通过以下方式混合（i）能够形成碳的化合物的碳粉末和/或粉末 热处理，和（iii）选自碱土金属氧化物，能够通过热处理形成所述碱土金属氧化物的化合物，稀土元素氧化物和能够形成所述稀土元素的化合物中的至少一种化合物的粉末 氧化物，并将所得混合物在含氮非氧化性气氛中煅烧，提供易于烧结的氮化铝粉末，而不用与烧结助剂进一步混合。

公开(公告)号：US4514370A

公开(公告)日：1985-04-30

申请号：US618524

申请日：1984-06-08

申请人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge ,  Kazunari Koide ,  Masaaki Mori ,  Tetsuro Urakawa

发明人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge ,  Kazunari Koide ,  Masaaki Mori ,  Tetsuro Urakawa

IPC分类号： C01B21/068

CPC分类号： C01B21/0685 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2004/62

摘要： Disclosed is a process for preparing silicon nitride powder, which comprises baking a powdery mixture comprising (i) 1 part by weight of silica powder, or a silica-containing substance in terms of silica, (ii) 0.4 to 4 parts by weight of carbon powder, or a substance generating carbon by baking, in terms of carbon and (iii) 0.005 to 1 part by weight of silicon nitride powder synthesized by a silica reduction method, at a temperature of from 1350.degree. to 1550.degree. C. in a non-oxidative atmosphere containing nitrogen.

摘要翻译： 公开了一种制备氮化硅粉末的方法，其包括将包含（i）1重量份二氧化硅粉末或含二氧化硅的二氧化硅物质的粉末混合物烘烤，（ii）0.4至4重量份的碳 粉末或通过焙烧产生碳的物质，以碳和（iii）0.005〜1重量份的通过二氧化硅还原法合成的氮化硅粉末，在1350〜1550℃的温度下， 含氮的氧化气氛。

公开(公告)号：US4368180A

公开(公告)日：1983-01-11

申请号：US293305

申请日：1981-08-17

申请人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

发明人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

IPC分类号： C01B21/068 ,  C04B35/584

CPC分类号： C04B35/584 ,  C01B21/0685 ,  C01P2004/61 ,  C01P2006/80

摘要： A method for producing powder of a .alpha.-silicon nitride which comprises the steps of adding 0.1 to 2 parts by weight of carbon and 0.005 to 1 part by weight of at least one silicon compound selected from the group consisting of Si.sub.3 N.sub.4, SiC and Si.sub.2 ON.sub.2 to one part by weight, when converted to SiO.sub.2, of a liquid alkylchlorosilane that forms a precipitate and HCl by hydrolysis which precipitate is convertible to SiO.sub.2 at a baking temperature of 1300.degree. to 1550.degree. C., hydrolyzing the resultant mixture, washing the mixture to separate a solid component, and baking the solid component at a temperature of 1300.degree. to 1550.degree. C. in an atmosphere mainly consisting of a nitrogen gas or a gas of a nitrogen compound to effect formation of .alpha.-silicon nitride.

公开(公告)号：US4680278A

公开(公告)日：1987-07-14

申请号：US812012

申请日：1985-12-23

申请人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

发明人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

IPC分类号： C01B21/072 ,  C01B21/082 ,  C04B35/58

CPC分类号： C01B21/0726 ,  C01B21/0826 ,  C01P2004/61

摘要： A process for preparing aluminum nitride powder, which comprises mixing (i) aluminum hydroxide powder, (ii) carbon powder or a substance capable of forming carbon powder by heating and (iii) at least one of additives selected from the group consisting of aluminum nitride powder, silicon nitride powder, silicon carbide powder and powder of substances capable of forming the powder corresponding to these powders, and baking the mixture thus obtained in a non-oxidative atmosphere containing nitrogen. The process is useful for preparing aluminum nitride powder having small particle size and small particle size distribution and also having a uniform shape of particles, at a lower temperature and in a shorter period of time.

摘要翻译： 一种制备氮化铝粉末的方法，其包括将（i）氢氧化铝粉末，（ii）碳粉末或能够通过加热形成碳粉末的物质和（iii）至少一种选自氮化铝 粉末，氮化硅粉末，碳化硅粉末和能够形成与这些粉末相应的粉末的物质的粉末，并在由氮气的非氧化性气氛中焙烧得到的混合物。 该方法在较低的温度和更短的时间内可用于制备具有小粒度和小粒度分布的氮化铝粉末，并且还具有均匀的颗粒形状。

公开(公告)号：US3969125A

公开(公告)日：1976-07-13

申请号：US381672

申请日：1973-07-23

申请人： Katsutoshi Komeya ,  Hiroshi Inoue ,  Akihiko Tsuge

发明人： Katsutoshi Komeya ,  Hiroshi Inoue ,  Akihiko Tsuge

IPC分类号： C04B35/80 ,  C04B35/584 ,  C04B35/593 ,  C04B35/597 ,  C04B35/50

CPC分类号： C04B35/584 ,  C04B35/593 ,  C04B35/597

摘要： We had previously disclosed a heat resistive and reinforced composite material which was prepared by sintering a finely powdered mixture of trisilicon tetranitride and an oxide of yttrium group elements.More improved similar composite material having excellent bending strength can be obtained by sintering a finely powdered mixture of trisilicon tetranitride, yttrium oxide and aluminum oxide. Cerium oxide, lanthanum oxide or scandium oxide can also be used instead of yttrium oxide.

摘要翻译： 我们之前已经公开了一种耐热和增强的复合材料，其通过烧结四氧化三铁三氧化物和钇基元素的氧化物的细粉末混合物制备。

公开(公告)号：US4539298A

公开(公告)日：1985-09-03

申请号：US443955

申请日：1982-11-23

申请人： Katsutoshi Komeya ,  Akihiko Tsuge ,  Hiroshi Inoue ,  Hiroyasu Ohta

发明人： Katsutoshi Komeya ,  Akihiko Tsuge ,  Hiroshi Inoue ,  Hiroyasu Ohta

IPC分类号： C04B35/565 ,  C04B35/581 ,  H01L23/15 ,  H01L23/373 ,  H05K1/03 ,  C04B35/56 ,  C04B35/58

CPC分类号： H01L23/15 ,  C04B35/565 ,  C04B35/581 ,  H01L23/3731 ,  H01L2924/0002 ,  H05K1/0306

摘要： Disclosed is a highly heat-conductive ceramic material which is basically of SiC-AlN system, comprising SiC, AlN and one or more of metal oxide selected from CaO, BaO and SrO, each in a prescribed amount. The SiC may otherwise be one whose particle surface is coated with the AlN.

摘要翻译： 公开了一种高度导热的陶瓷材料，其基本上是SiC-AlN体系，其包含SiC，AlN和一种或多种选自CaO，BaO和SrO的金属氧化物，每种均为规定量。 SiC可能是其颗粒表面被AlN涂覆的SiC。

公开(公告)号：US4572844A

公开(公告)日：1986-02-25

申请号：US602447

申请日：1984-04-20

申请人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

发明人： Hiroshi Inoue ,  Akihiko Tsuge ,  Katsutoshi Komeya

IPC分类号： C01B21/072 ,  C04B35/581 ,  C04B41/45 ,  C04B41/81 ,  B05D1/12 ,  C04B35/52 ,  C04B35/56

CPC分类号： C04B41/009 ,  C04B35/581 ,  C04B41/4584 ,  C04B41/81 ,  Y10T428/12181

摘要： There is disclosed a method for preparing a coated powder comprising the steps of adding a carbon powder and an aluminum nitride powder to a methylsilicic acid powder or a precursor of the methylsilicic acid and mixing them and then subjecting the resulting mixed powder to a heat treatment in an atmosphere including an inert gas or a carbon component-containing gas in order to coat the aluminum nitride powder with silicon carbide.This invention provides a chemically stable coated powder and a sintered body obtained by employing the coated powder has a good thermal conductivity.

摘要翻译： 公开了一种制备涂覆粉末的方法，包括以下步骤：向甲基硅酸粉末或甲基硅酸的前体中加入碳粉和氮化铝粉末，并将其混合，然后将所得混合粉末进行热处理 包括惰性气体或含碳成分气体的气氛，以便用碳化硅涂覆氮化铝粉末。 本发明提供了一种化学稳定的涂布粉末，并且通过使用涂覆的粉末获得的烧结体具有良好的导热性。

公开(公告)号：US4511525A

公开(公告)日：1985-04-16

申请号：US443678

申请日：1982-11-22

申请人： Akihiko Tsuge ,  Michiyasu Komatsu ,  Hiroshi Inoue ,  Katsutoshi Komeya

发明人： Akihiko Tsuge ,  Michiyasu Komatsu ,  Hiroshi Inoue ,  Katsutoshi Komeya

IPC分类号： C04B35/584 ,  C04B35/597 ,  C04B35/58

CPC分类号： C04B35/597 ,  C04B35/584

摘要： Disclosed is a process for producing a sintered silicon nitride-base body, which comprises; mixing powder (A) of heat-treated or not heat-treated silicon nitride powder and powder (B) of powder obtained by heat-treating a powdery mixture of silicon nitride powder and a sintering additive in a non-oxidizing atmosphere and then grinding the resulting heat-treated products into powder; and forming the resultant powdery mixture into a desired shape, which is then sintered in a non-oxidizing atmosphere.The process is characterized by heating powder (B), or powder (A) and powder (B), before sintering, thereby producing sintered silicon nitride body of highly improved properties.

摘要翻译： 公开了一种生产氮化硅烧结体的方法，其包括： 将经热处理或未经热处理的氮化硅粉末的粉末（A）和通过在非氧化性气氛中热处理氮化硅粉末和烧结添加剂的粉末混合物得到的粉末（B）混合，然后研磨 将热处理产物变成粉末; 并将所得粉末混合物形成所需形状，然后在非氧化气氛中烧结。 该方法的特征在于在烧结之前加热粉末（B）或粉末（A）和粉末（B），由此制备具有高度改进性能的烧结氮化硅体。

公开(公告)号：US4435513A

公开(公告)日：1984-03-06

申请号：US420842

申请日：1982-09-21

申请人： Katsutoshi Komeya ,  Akihiko Tsuge ,  Hiroshi Inoue

发明人： Katsutoshi Komeya ,  Akihiko Tsuge ,  Hiroshi Inoue

IPC分类号： C04B35/581 ,  C04B35/52 ,  C04B35/58

CPC分类号： C04B35/581

摘要： There is disclosed a sintered body of aluminum nitride comprising a sintered body of powder mixture containing(a) AlN powder: 100 parts by weight,(b) at least one compound selected from CaO, BaO, SrO and a compound capable of being converted into one of these oxides by sintering : 0.05 to 6 parts by weight, and(c) carbon powder or powder of a compound capable of being converted into carbon by sintering : more than 0 to not more than 7 parts by weight.The sintered bodies of aluminum nitride according to this invention have high density and excellent properties such as high thermal conductivity.

摘要翻译： 公开了一种氮化铝烧结体，其包含粉末混合物烧结体，其包含（a）AlN粉末：100重量份，（b）至少一种选自CaO，BaO，SrO的化合物和能够转化为 这些氧化物中的一种通过烧结：0.05〜6重量份，和（c）通过烧结能够转化为碳的化合物的碳粉末或粉末：大于0重量％且不大于7重量份。 根据本发明的氮化铝烧结体具有高密度和优异的性能，例如高导热性。