公开(公告)号：US20110003212A1

公开(公告)日：2011-01-06

申请号：US12744722

申请日：2008-11-19

申请人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Sakai Noriyuki ,  Takayuki Fujita

发明人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Sakai Noriyuki ,  Takayuki Fujita

IPC分类号： H01M10/0562 ,  H01M10/38 ,  C01B35/00

CPC分类号： H01M10/0585 ,  H01M4/0471 ,  H01M4/62 ,  H01M4/628 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/38 ,  H01M2300/0071 ,  Y10T29/49115

摘要： A multilayer whole solid-type lithium ion rechargeable battery has hitherto been produced by stacking green sheets of a positive electrode layer, a solid electrolyte layer, and a negative electrode layer, which are formed of respective materials different from each other in coefficient of thermal expansion, and firing the layers at a time. This technique poses problems of delamination and nonlamination attributable to a difference in shrinkage. The problems can be solved by forming green sheets with the addition of a sintering aid to each starting material powder for the positive electrode layer, the solid electrolyte layer, and the negative electrode layer and performing control, by setting the additive rate of the sintering aid and the firing temperature, so that the shrinkages of the respective green sheets are substantially equal to each other. Consequently, unfavorable phenomena such as delamination can be prevented.

摘要翻译： 迄今为止，已经通过将由热膨胀系数不同的各种材料形成的正极层，固体电解质层和负极层的生片堆叠而制成多层整体固体型锂离子可再充电电池 ，并一次点燃层。 这种技术存在由于收缩差异引起的分层和非层压问题。 可以通过向正极层，固体电解质层和负极层的各原料粉末添加烧结助剂来形成生片，并通过设定烧结助剂的添加比例来进行控制来解决问题 和烧成温度，使得各个生片的收缩基本上彼此相等。 因此，可以防止诸如分层的不利现象。

公开(公告)号：US09054391B2

公开(公告)日：2015-06-09

申请号：US13637745

申请日：2011-03-22

申请人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Megumi Fujii ,  Rieko Kato ,  Takayuki Fujita

发明人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Megumi Fujii ,  Rieko Kato ,  Takayuki Fujita

IPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M10/0562 ,  H01M10/0585 ,  H01M4/485 ,  H01M4/505

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49112

摘要： Disclosed is a lithium ion secondary battery that has a simple structure, is easily produced, and wherein short circuits do not arise. The lithium ion secondary battery comprises an active material being contained in a matrix comprising a laminated body that includes a positive current collector and a negative current collector which are laminated on each other via a solid electrolyte layer, the solid electrolyte layer includes an active material in a matrix made of solid electrolyte, and a ratio of the volume of the solid electrolyte and the volume of the active material being 90:10-65:35. Also, the active material may also be contained in a matrix of a conductive substance of the positive current collector and/or the negative current collector.

摘要翻译： 公开了一种锂离子二次电池，其结构简单，容易制造，并且不会产生短路。 锂离子二次电池包含包含在包括通过固体电解质层彼此层叠的正极集电体和负极集电体的层叠体的基体中的活性物质，固体电解质层包含活性物质 由固体电解质制成的基体，固体电解质的体积与活性物质的体积的比为90:10〜65:35。 此外，活性物质也可以包含在正极集电体和/或负极集电体的导电性物质的基体中。

公开(公告)号：US20130017435A1

公开(公告)日：2013-01-17

申请号：US13637772

申请日：2011-03-22

申请人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Rieko Kato ,  Tetsu Takahashi ,  Takayuki Fujita

发明人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Rieko Kato ,  Tetsu Takahashi ,  Takayuki Fujita

IPC分类号： H01M4/505 ,  H01M10/0562 ,  H01M2/20 ,  H01M4/525

CPC分类号： H01M10/0585 ,  H01M4/0471 ,  H01M4/505 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0566

摘要： Provided is a lithium ion secondary battery including a laminated body formed by laminating a first electrode layer and a second electrode layer on each other via an electrolytic region, wherein the first electrode layer and the second electrode layer include the same active material, and the active material is Li2MnxMe1−xO3 (Me=Ni, Cu, V, Co, Fe, Ti, Al, Si, or P, and or 0.5£×1).

摘要翻译： 提供一种锂离子二次电池，其包括通过电解区域层压第一电极层和第二电极层而形成的层叠体，其中，第一电极层和第二电极层包含相同的活性物质，活性物质 材料为Li2MnxMe1-xO3（Me = Ni，Cu，V，Co，Fe，Ti，Al，Si或P，和或0.5£×1）。

公开(公告)号：US20100075219A1

公开(公告)日：2010-03-25

申请号：US12527430

申请日：2007-02-16

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato ,  Hisao Fukumori

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato ,  Hisao Fukumori

IPC分类号： H01M10/05 ,  H01M4/70 ,  H01M4/58 ,  H01M4/50 ,  H01M4/00 ,  H01M4/62 ,  H01M10/04 ,  H01M10/38

CPC分类号： H01M2/14 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/139 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/624 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/38

摘要： In multilayer wholly solid lithium ion secondary batteries, a laminate having a collector layer of material with high conductivity superimposed on an active material layer has been disposed so as to attain a lowering of battery impedance. Consequently, in the fabrication of each of positive electrode layer and negative electrode layer, stacking of three layers consisting of an active material layer, a collector layer and an active material layer has been needed, thereby posing the problem of complex processing and high production cost. In the invention, a positive electrode layer and a negative electrode layer are fabricated from paste consisting of active material mixed with conductive substance in a given mixing ratio, and no collector layer is disposed. This realizes process simplification and manufacturing cost reduction without deterioration of battery performance and has also been effective in enhancing of battery performance, such as improvement to cycle characteristics.

摘要翻译： 在多层全固体锂离子二次电池中，已经布置了具有叠加在活性物质层上的具有高导电性的材料的集电体层的层压体，以便获得电池阻抗的降低。 因此，在正极层和负极层的制造中，需要层叠由活性物质层，集电体层和活性物质层构成的3层，因此存在复杂的加工和高生产成本的问题 。 在本发明中，正极层和负极层由以与给定混合比例的与导电物质混合的活性物质组成的糊料制成，没有设置集电体层。 这实现了过程简化和制造成本的降低，而不会降低电池性能，并且还有效地提高电池性能，例如改善循环特性。

公开(公告)号：US20100216032A1

公开(公告)日：2010-08-26

申请号：US12599941

申请日：2008-05-09

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

IPC分类号： H01M6/18 ,  H01M10/04

CPC分类号： B29C65/02 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/624 ,  H01M10/0525 ,  H01M10/0562 ,  Y02E60/122 ,  Y10T29/49112

摘要： Conventional ion rechargeable batteries having an electrode layer on an electrolyte layer suffer from an impurity layer formed at the interface, degrading performance. Conventional batteries with no such impurity layer have a problem of weak interface bonding. In the present invention, in a baking process step after an electrode layer is laminated on an electrolyte layer, materials for an electrode layer and an electrolyte layer are selected such that an intermediate layer formed of a reaction product contributing to charging and discharging reactions is formed at the interface of the electrode layer and the electrolyte layer. In addition, a paste that an active material is mixed with a conductive material at a predetermined mixing ratio is used to form a positive electrode layer and a negative electrode layer. Reductions in electrode resistance and interface resistance and improvement of charging and discharging cycle characteristics are made possible.

摘要翻译： 在电解质层上具有电极层的常规离子可再充电电池在界面处形成杂质层，降解性能。 没有这种杂质层的常规电池具有界面粘合弱的问题。 在本发明中，在将电极层层压在电解质层上之后的烘烤工序中，选择电极层和电解质层的材料，形成由有助于充放电反应的反应产物形成的中间层 在电极层和电解质层的界面处。 此外，使用活性物质以预定的混合比与导电材料混合的糊料形成正极层和负极层。 降低电极电阻和界面电阻以及充放电循环特性的改善成为可能。

公开(公告)号：US09236594B2

公开(公告)日：2016-01-12

申请号：US12527430

申请日：2007-02-16

申请人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

发明人： Shoichi Iwaya ,  Hitoshi Masumura ,  Noriyuki Sakai ,  Takayuki Fujita ,  Hiroshi Sasagawa ,  Hiroshi Sato

IPC分类号： H01M10/04 ,  H01M10/38 ,  H01M4/70 ,  H01M4/58 ,  H01M4/50 ,  H01M4/00 ,  H01M2/14

CPC分类号： H01M2/14 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/139 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/624 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/38

摘要： In multilayer wholly solid lithium ion secondary batteries, a laminate having a collector layer of material with high conductivity superimposed on an active material layer has been disposed so as to attain a lowering of battery impedance. Consequently, in the fabrication of each of positive electrode layer and negative electrode layer, stacking of three layers consisting of an active material layer, a collector layer and an active material layer has been needed, thereby posing the problem of complex processing and high production cost. In the invention, a positive electrode layer and a negative electrode layer are fabricated from paste consisting of active material mixed with conductive substance in a given mixing ratio, and no collector layer is disposed. This realizes process simplification and manufacturing cost reduction without deterioration of battery performance and has also been effective in enhancing of battery performance, such as improvement to cycle characteristics.

摘要翻译： 在多层全固体锂离子二次电池中，已经布置了具有叠加在活性物质层上的具有高导电性的材料的集电体层的层压体，以便获得电池阻抗的降低。 因此，在正极层和负极层的制造中，需要层叠由活性物质层，集电体层和活性物质层构成的3层，因此存在复杂的加工和高生产成本的问题 。 在本发明中，正极层和负极层由以与给定混合比例的与导电物质混合的活性物质组成的糊料制成，没有设置集电体层。 这实现了过程简化和制造成本的降低，而不会降低电池性能，并且还有效地提高电池性能，例如改善循环特性。

公开(公告)号：US20130017454A1

公开(公告)日：2013-01-17

申请号：US13637745

申请日：2011-03-22

申请人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Megumi Fuji ,  Rieko Kato ,  Takayuki Fujita

发明人： Hiroshi Sato ,  Hiroshi Sasagawa ,  Megumi Fuji ,  Rieko Kato ,  Takayuki Fujita

IPC分类号： H01M4/64 ,  H01M10/0525 ,  H01M10/0562

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49112

摘要： Disclosed is a lithium ion secondary battery that has a simple structure, is easily produced, and wherein short circuits do not arise. The lithium ion secondary battery comprises an active material being contained in a matrix comprising a laminated body that includes a positive current collector and a negative current collector which are laminated on each other via a solid electrolyte layer, the solid electrolyte layer includes an active material in a matrix made of solid electrolyte, and a ratio of the volume of the solid electrolyte and the volume of the active material being 90:10-65:35. Also, the active material may also be contained in a matrix of a conductive substance of the positive current collector and/or the negative current collector.

摘要翻译： 公开了一种锂离子二次电池，其结构简单，容易制造，并且不会产生短路。 锂离子二次电池包含包含在包括通过固体电解质层彼此层叠的正极集电体和负极集电体的层叠体的基体中的活性物质，固体电解质层包含活性物质 由固体电解质制成的基体，固体电解质的体积与活性物质的体积的比为90:10〜65:35。 此外，活性物质也可以包含在正极集电体和/或负极集电体的导电性物质的基体中。

公开(公告)号：US08883347B2

公开(公告)日：2014-11-11

申请号：US12302250

申请日：2007-02-13

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M4/13 ,  H01M10/04 ,  H01M4/66 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585

CPC分类号： H01M4/0404 ,  H01M4/0414 ,  H01M4/0471 ,  H01M4/485 ,  H01M4/622 ,  H01M4/661 ,  H01M4/666 ,  H01M10/044 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包含层叠材料的全固体二次电池，其中正极单元和负极单元交替地通过离子导电无机材料层层压，正极单元在两个表面上具有正的活性材料层 上述负极单元在负极集电体层的两面具有负极活性物质层，（A）正极集电体层和负极中的至少一个 集电体层包括Ag，Pd，Au和Pt中的任一种的金属，或包含Ag，Pd，Au和Pt中的任一种的合金，或包含选自金属和合金的两种或更多种的混合物，（B）每层 或（C）至少离子传导性无机材料层的离子传导性无机材料的原料为煅烧粉末。

公开(公告)号：US20100003592A1

公开(公告)日：2010-01-07

申请号：US12449532

申请日：2007-02-13

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Sumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Sumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M6/42

CPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/661 ,  H01M10/052 ,  H01M10/0562 ,  Y02T10/7011 ,  Y10T29/49112 ,  Y10T29/49115

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery comprising a laminated material, wherein the laminated material comprises a plurality of cell units and optionally a collector layer(s) constituting one of or both of an uppermost layer and a lowermost layer of the laminated material, wherein each of the cell units comprises a positive active material layer, an ion-conductive inorganic-material layer and a negative active material layer which are continuously arranged in this order, and is laminated so that the positive active material layer and the negative active material layer of adjacent cell units face each other, wherein (a) the laminated material is a product of co-firing, (b) each of the layer is in a sintered state, or (c) at least the ion-conductive inorganic-material layer is formed from a calcined powder of the ion-conductive inorganic-material.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包括层压材料的全固体二次电池，其中层压材料包括多个单元单元和任选的构成叠层材料的最上层和最下层之一或两者的集电极层，其中 每个电池单元包括依次连续排列的正极活性物质层，离子传导性无机材料层和负极活性物质层，并且层叠，使得正极活性物质层和负极活性物质层 相邻的单元单元彼此面对，其中（a）层压材料是共烧的产物，（b）每个层处于烧结状态，或（c）至少离子传导性无机材料层 由离子传导性无机材料的煅烧粉末形成。

公开(公告)号：US20090202912A1

公开(公告)日：2009-08-13

申请号：US12302250

申请日：2007-02-13

申请人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

发明人： Mamoru Baba ,  Shoichi Iwaya ,  Hitoshi Masumura ,  Hiroshi Sato ,  Hiroshi Sasagawa ,  Noriyuki Sakai ,  Takayuki Fujita

IPC分类号： H01M4/40 ,  H01M4/24 ,  H01M10/00

CPC分类号： H01M4/0404 ,  H01M4/0414 ,  H01M4/0471 ,  H01M4/485 ,  H01M4/622 ,  H01M4/661 ,  H01M4/666 ,  H01M10/044 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108

摘要： This is to provide an all solid state secondary battery which can be produced by an industrially employable method capable of mass-production and has excellent secondary battery characteristics.This is an all solid state secondary battery containing a laminated material in which a positive-electrode unit and a negative-electrode unit are laminated alternately through an ion conductive inorganic-material layer, the positive-electrode unit has positive active material layers on both surfaces of a positive-electrode collector layer, the above-mentioned negative-electrode unit has negative active material layers on both surfaces of a negative-electrode collector layer, (A) at least one of the positive-electrode collector layer and the negative-electrode collector layer comprises a metal of either of Ag, Pd, Au and Pt, or an alloy containing either of Ag, Pd, Au and Pt, or a mixture containing two or more kinds selected from the metals and alloys, (B) each layer is in a sintered state, or (C) at least the starting material for the ion conductive inorganic material of the ion conductive inorganic-material layer is a calcined powder.

摘要翻译： 这是提供一种能够通过工业上可以大规模生产并且具有优异的二次电池特性的方法生产的全固态二次电池。 这是一种包含层叠材料的全固体二次电池，其中正极单元和负极单元交替地通过离子导电无机材料层层压，正极单元在两个表面上具有正的活性材料层 上述负极单元在负极集电体层的两面具有负极活性物质层，（A）正极集电体层和负极中的至少一个 集电体层包括Ag，Pd，Au和Pt中的任一种的金属，或包含Ag，Pd，Au和Pt中的任一种的合金，或包含选自金属和合金的两种或更多种的混合物，（B）每层 或（C）至少离子传导性无机材料层的离子传导性无机材料的原料为煅烧粉末。