Cathode Material for Lithium Secondary Battery and Manufacturing Method Thereof
    2.
    发明申请
    Cathode Material for Lithium Secondary Battery and Manufacturing Method Thereof 有权
    锂二次电池用阴极材料及其制造方法

    公开(公告)号:US20090121198A1

    公开(公告)日:2009-05-14

    申请号:US11718021

    申请日:2005-10-13

    IPC分类号: H01B1/08

    摘要: Provided is a cathode material for a lithium secondary battery composed of an aggregate of Li-A-O composite oxide particles (wherein A represents one or more metal elements selected from Mn, Fe, Co and Ni), wherein the lithium composite oxide contains 20 to 100 ppm (by mass) of P, and the total content of impurity elements excluding essential components is 2000 ppm or less. Also provided is a manufacturing method of such a cathode material for a lithium secondary battery including the steps of suspending lithium carbonate in water and thereafter introducing a metallic salt solution of one or more metal elements selected from Mn, Fe, Co and Ni in the lithium carbonate suspension, adding a small amount of phosphoric acid so that the P content in the Li-A-O composite oxide particles will be 20 to 100 ppm (by mass), and forming an aggregate of Li-A-O composite oxide particles containing 20 to 100 ppm (by mass) of P by filtering, cleansing, drying and thereafter oxidizing the obtained carbonate. This cathode material for a lithium secondary battery and its manufacturing method realize improved sinterability and battery characteristics.

    摘要翻译: 提供一种由Li-AO复合氧化物粒子(其中A表示一种或多种选自Mn,Fe,Co和Ni的金属元素)的聚集体构成的锂二次电池用阴极材料,其中锂复合氧化物含有20〜100 ppm(质量ppm),除了必要成分以外的杂质成分的总含量为2000ppm以下。 还提供了这种锂二次电池用正极材料的制造方法,其包括以下步骤:将碳酸锂悬浮在水中,然后将选自Mn,Fe,Co和Ni中的一种或多种金属元素的金属盐溶液引入锂 碳酸盐悬浮液,加入少量磷酸,使Li-AO复合氧化物粒子中的P含量为20〜100ppm(质量%),形成含有20〜100ppm的Li-AO复合氧化物粒子的集合体 通过过滤,清洗,干燥,然后氧化所得碳酸盐(质量)P。 该锂二次电池用正极材料及其制造方法实现了烧结性和电池特性的改善。

    Lithium-containing complex oxide and method of producing same
    3.
    发明授权
    Lithium-containing complex oxide and method of producing same 有权
    含锂复合氧化物及其制造方法

    公开(公告)号:US07288242B2

    公开(公告)日:2007-10-30

    申请号:US10510800

    申请日:2003-01-15

    IPC分类号: C01D15/00 C01D15/02

    摘要: A lithium-containing complex oxide exhibits a high performance as a cathode active material of a lithium secondary cell or the like and having a high tap density. A granular lithium-containing complex oxide, such as lithium manganese complex oxide, is made up of “complex oxide grains produced by integrating lithium-rich material grains abnormally grown during a firing reaction with the surfaces of the base grains by sintering.” The number of complex oxide grains is not more than 50 per gram of the complex grains. A metal oxide such as manganese oxide and lithium carbonate not more than 5 μm in average grain size are mixed by means of a mixer which grinds and mixes particles by using a shearing force and heated and fired at a warming rate of not more than 50° C./h., thus producing the lithium-containing complex oxide.

    摘要翻译: 含锂复合氧化物表现出作为锂二次电池等的正极活性物质的高性能,并且具有高振实密度。 颗粒状含锂复合氧化物如锂锰复合氧化物由“通过烧结而使烧结反应期间异常生长的富含锂的材料颗粒与基体颗粒的表面积分的复合氧化物颗粒”组成。 复合氧化物颗粒的数量不超过每克复合颗粒的50个。 平均粒径不超过5μm的氧化锰和碳酸锂的金属氧化物通过使用剪切力研磨和混合颗粒的混合器混合,并以不大于50°的加热速率加热和烧制 C./h,从而制造含锂复合氧化物。

    Method for producing positive plate material for lithium secondary cell
    5.
    发明申请
    Method for producing positive plate material for lithium secondary cell 审中-公开
    锂二次电池正极材料的制造方法

    公开(公告)号:US20050265909A1

    公开(公告)日:2005-12-01

    申请号:US10521370

    申请日:2003-02-25

    摘要: A positive plate material for lithium secondary cells stably exhibiting excellent performance including the cell initial capacity, cycle characteristics, and the safety. The material is produced by dripping an aqueous solution of a salt (e.g., cobalt sulfate) of a doping element (e.g., a transition metal, an alkaline metal, an alkaline-earth metal, B, or Al) into an alkaline solution, a carbonate solution, or a hydrogencarbonate solution in any one of which a compound (e.g., manganese oxide) of a metal (Mn, Co, Ni, or the like) which is the major component of the positive plate material so as to precipitate the compound of the doping element on the major component compound and to cover the major component compound, mixing the major component compound covered with the doping element with a lithium compound (e.g., lithium carbonate), and firing the mixture.

    摘要翻译: 用于锂二次电池的正极板材料稳定地表现出包括电池初始容量,循环特性和安全性的优异性能。 该材料通过将掺杂元素(例如过渡金属,碱金属,碱土金属,B或Al)的盐(例如硫酸钴)的水溶液滴入碱性溶液中而制备, 碳酸盐溶液或其中任何一种的化合物(例如,氧化锰)作为正极板材的主要成分的金属(Mn,Co,Ni等)的碳酸氢盐溶液,以使化合物 的主要组分化合物上的掺杂元素并覆盖主要组分化合物,将被掺杂元素覆盖的主要组分化合物与锂化合物(例如碳酸锂)混合,并焙烧该混合物。

    Cathode material for lithium secondary battery and manufacturing method thereof
    7.
    发明授权
    Cathode material for lithium secondary battery and manufacturing method thereof 有权
    锂二次电池用正极材料及其制造方法

    公开(公告)号:US07799301B2

    公开(公告)日:2010-09-21

    申请号:US11718021

    申请日:2005-10-13

    IPC分类号: C01D1/00

    摘要: Provided is a cathode material for a lithium secondary battery composed of an aggregate of Li-A-O composite oxide particles (wherein A represents one or more metal elements selected from Mn, Fe, Co and Ni), wherein the lithium composite oxide contains 20 to 100 ppm (by mass) of P, and the total content of impurity elements excluding essential components is 2000 ppm or less. Also provided is a manufacturing method of such a cathode material for a lithium secondary battery including the steps of suspending lithium carbonate in water and thereafter introducing a metallic salt solution of one or more metal elements selected from Mn, Fe, Co and Ni in the lithium carbonate suspension, adding a small amount of phosphoric acid so that the P content in the Li-A-O composite oxide particles will be 20 to 100 ppm (by mass), and forming an aggregate of Li-A-O composite oxide particles containing 20 to 100 ppm (by mass) of P by filtering, cleansing, drying and thereafter oxidizing the obtained carbonate. This cathode material for a lithium secondary battery and its manufacturing method realize improved sinterability and battery characteristics.

    摘要翻译: 提供一种由Li-AO复合氧化物粒子(其中A表示一种或多种选自Mn,Fe,Co和Ni的金属元素)的聚集体构成的锂二次电池用阴极材料,其中锂复合氧化物含有20〜100 ppm(质量ppm),除了必要成分以外的杂质成分的总含量为2000ppm以下。 还提供了这种锂二次电池用正极材料的制造方法,其包括以下步骤:将碳酸锂悬浮在水中,然后将选自Mn,Fe,Co和Ni中的一种或多种金属元素的金属盐溶液引入锂 碳酸盐悬浮液,加入少量磷酸,使Li-AO复合氧化物粒子中的P含量为20〜100ppm(质量%),形成含有20〜100ppm的Li-AO复合氧化物粒子的集合体 通过过滤,清洗,干燥,然后氧化所得碳酸盐(质量)P。 该锂二次电池用正极材料及其制造方法实现了烧结性和电池特性的改善。

    Lithium-containing complex oxide and method of producing same
    8.
    发明申请
    Lithium-containing complex oxide and method of producing same 有权
    含锂复合氧化物及其制造方法

    公开(公告)号:US20050152831A1

    公开(公告)日:2005-07-14

    申请号:US10510800

    申请日:2003-01-15

    摘要: Means for stably supplying a lithium-containing complex oxide exhibiting a high performance as a cathode active material of a lithium secondary cell or the like and having a high tap density. Granular lithium-containing complex oxide such as lithium manganese complex oxide comprises “complex oxide grains produced by integrating lithium-rich material grains abnormally grown during a firing reaction with the surfaces of the base grains by sintering.” The number of complex oxide grains is not more than 50 per gram of the complex grains. Metal oxide such as manganese oxide and lithium carbonate not more than 5 μm in average grain size are mixed by means of a mixer which grinds and mixes particles by using shearing force and heating and firing them at a warming rate of not more than 50° C./h., thus producing the lithium-containing complex oxide.

    摘要翻译: 用于稳定地供给表现出高性能的含锂复合氧化物作为锂二次电池等的正极活性物质并具有高振实密度的方法。 颗粒状含锂复合氧化物如锂锰复合氧化物包括“通过将烧结反应期间异常生长的富含锂的材料颗粒与基体颗粒的表面通过烧结而形成的复合氧化物颗粒”。 复合氧化物颗粒的数量不超过每克复合颗粒的50个。 金属氧化物如氧化锰和不超过5μm的平均晶粒尺寸的碳酸锂通过混合器混合,该混合器通过使用剪切力研磨和混合颗粒并加热,并以不高于50℃的升温速率进行烧制 ./h,从而制备含锂复合氧化物。