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公开(公告)号：US20060186376A1
公开(公告)日：2006-08-24
申请号：US11409694
申请日：2006-04-24
申请人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
发明人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
CPC分类号： H01L51/0058 , C07D487/04 , C09B57/004 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1044 , H01L51/0053 , H01L51/006 , H01L51/0072 , H01L2251/308 , Y10S428/917
摘要： The present invention relates to fluorescent diketopyrrolopyrroles (“DPPs”) of the formula A1 and A2 independently from each other stand for characterized in that that at least two adjacent substituents R5 to R11 form an aromatic or aliphatic fused ring system, or at least one substituent R5 to R11 is cycloalkyl, aralkyl, alkenyl, cycloalkenyl, alkynyl, a hydroxyl group, a mercapto group, alkylthio, an aryl thioether group, a heterocyclic group, halogen, haloalkyl, haloalkenyl, haloalkynyl, a cyano group, an aldehyde group, a carbonyl group, a carboxyl group, an ester group, a carbamoyl group, a nitro group, a silyl group, a siloxanyl group, a substituted or unsubstituted vinyl, arylamino or diarylamino group; a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, or for the preparation of polymeric ink particles, toners, dye lasers and electroluminescent devices. The fluorescent diketopyrrolopyrroles (“DPPs”) of the formula I exhibit a high lightfastness, a high heat stability, especially in plastics. A luminescent device comprising a DPP compound of formula I is high in the efficiency of electrical energy utilisation, high in luminance and high in colour purity.
摘要翻译： 本发明涉及式A 1和A 2的荧光二酮吡咯并吡咯（“DPP”）彼此独立，其特征在于，至少两个相邻的取代基R R 11与R 11之间形成芳族或脂肪族稠合环系，或至少一个R 5至R 11的取代基 环烷基，芳烷基，烯基，环烯基，炔基，羟基，巯基，烷硫基，芳基硫醚基，杂环基，卤素，卤代烷基，卤代烯基，卤代炔基，氰基，醛基，羰基 羧基，酯基，氨基甲酰基，硝基，甲硅烷基，硅氧烷基，取代或未取代的乙烯基，芳基氨基或二芳基氨基; 其制备方法及其用于制备油墨，着色剂，涂料着色塑料，非冲击印刷材料，滤色器，化妆品或用于制备聚合物墨颗粒，调色剂，染料激光和电致发光装置的方法。 式I的荧光二酮吡咯并吡咯（“DPP”）具有高的耐光性，高的热稳定性，特别是在塑料中。 包含式I的DPP化合物的发光装置的电能利用效率高，亮度高，色纯度高。
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公开(公告)号：US07749404B2
公开(公告)日：2010-07-06
申请号：US11409694
申请日：2006-04-24
申请人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
发明人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
IPC分类号： H05B33/14 , C09K11/06 , C08K5/3415 , C07D487/04 , C09B57/00
CPC分类号： H01L51/0058 , C07D487/04 , C09B57/004 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1044 , H01L51/0053 , H01L51/006 , H01L51/0072 , H01L2251/308 , Y10S428/917
摘要： The present invention relates to fluorescent diketopyrrolopyrroles (“DPPs”) of the formula A1 and A2 independently from each other stand for characterized in that that at least two adjacent substituents R5 to R11 form an aromatic or aliphatic fused ring system, or at least one substituent R5 to R11 is cycloalkyl, aralkyl, alkenyl, cycloalkenyl, alkynyl, a hydroxyl group, a mercapto group, alkylthio, an aryl thioether group, a heterocyclic group, halogen, haloalkyl, haloalkenyl, haloalkynyl, a cyano group, an aldehyde group, a carbonyl group, a carboxyl group, an ester group, a carbamoyl group, a nitro group, a silyl group, a siloxanyl group, a substituted or unsubstituted vinyl, arylamino or diarylamino group; a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, or for the preparation of polymeric ink particles, toners, dye lasers and electroluminescent devices. The fluorescent diketopyrrolopyrroles (“DPPs”) of the formula I exhibit a high lightfastness, a high heat stability, especially in plastics. A luminescent device comprising a DPP compound of formula I is high in the efficiency of electrical energy utilisation, high in luminance and high in colour purity.
摘要翻译： 本发明涉及式A1和A2彼此独立的荧光二酮吡咯并吡咯（“DPP”），其特征在于至少两个相邻的取代基R 5至R 11形成芳族或脂族稠环体系，或至少一个取代基 R5至R11是环烷基，芳烷基，烯基，环烯基，炔基，羟基，巯基，烷硫基，芳基硫醚基，杂环基，卤素，卤代烷基，卤代烯基，卤代炔基，氰基，醛基， 羰基，羧基，酯基，氨基甲酰基，硝基，甲硅烷基，硅氧烷基，取代或未取代的乙烯基，芳基氨基或二芳基氨基; 其制备方法及其用于制备油墨，着色剂，涂料着色塑料，非冲击印刷材料，滤色器，化妆品或用于制备聚合物墨颗粒，调色剂，染料激光和电致发光装置的方法。 式I的荧光二酮吡咯并吡咯（“DPP”）具有高的耐光性，高的热稳定性，特别是在塑料中。 包含式I的DPP化合物的发光装置的电能利用效率高，亮度高，色纯度高。
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公开(公告)号：US07063806B2
公开(公告)日：2006-06-20
申请号：US10481963
申请日：2002-06-20
申请人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
发明人： Hiroshi Yamamoto , Norihisa Dan , Olof Wallquist
CPC分类号： H01L51/0058 , C07D487/04 , C09B57/004 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1044 , H01L51/0053 , H01L51/006 , H01L51/0072 , H01L2251/308 , Y10S428/917
摘要： The present invention relates to fluorescent diketopyrrolopyrroles (“DPPs”) of the formula characterized in that that at least two adjacent substituents R5 to R11 form an aromatic or aliphatic fused ring system, or at least one substituent R5 to R11 is cycloalkyl, aralkyl, alkenyl, cycloalkenyl, alkynyl, a hydroxyl group, a mercapto group, alkylthio, an aryl thioether group, a heterocyclic group, halogen, haloalkyl, haloalkenyl, haloalkynyl, a cyano group, an aldehyde group, a carbonyl group, a carboxyl group, an ester group, a carbamoyl group, a nitro group, a silyl group, a siloxanyl group, a substituted or unsubstituted vinyl, arylamino or diarylamino group; a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, or for the preparation of polymeric ink particles, toners, dye lasers and electroluminescent devices. The fluorescent diketopyrrolopyrroles (“DPPs”) of the formula I exhibit a high lighffastness, a high heat stability, especially in plastics. A luminescent device comprising a DPP compound of formula I is high in the efficiency of electrical energy utilisation, high in luminance and high in colour purity.
摘要翻译： 本发明涉及下式的荧光二酮吡咯并吡咯（“DPP”），其特征在于至少两个相邻的取代基R 5至R 11形成芳族或脂族稠合环 系统或至少一个取代基R 5至R 11是环烷基，芳烷基，烯基，环烯基，炔基，羟基，巯基，烷硫基，芳基硫醚 基团，杂环基，卤素，卤代烷基，卤代烯基，卤代炔基，氰基，醛基，羰基，羧基，酯基，氨基甲酰基，硝基，甲硅烷基，硅氧烷基， 取代或未取代的乙烯基，芳基氨基或二芳基氨基; 其制备方法及其用于制备油墨，着色剂，涂料着色塑料，非冲击印刷材料，滤色器，化妆品或用于制备聚合物墨颗粒，调色剂，染料激光和电致发光装置的方法。 式I的荧光二酮吡咯并吡咯（“DPP”）表现出高的亮度，高的热稳定性，特别是在塑料中。 包含式I的DPP化合物的发光装置的电能利用效率高，亮度高，色纯度高。
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公开(公告)号：US08221508B2
公开(公告)日：2012-07-17
申请号：US13133234
申请日：2009-12-04
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： A61K8/64 , A61K8/645 , A61K8/65 , A61K2800/4322 , A61Q5/065 , C09B69/10 , C09B69/101 , C09B69/106
摘要： Polymeric dye comprising oligo and polypeptides selected from natural or synthetic aminoacids bearing at least one covalently bounded cationic dye. Very good dyeing results on human hair are obtained with these dyes.
摘要翻译： 包含寡核苷酸和多肽的聚合染料选自具有至少一种共价结合阳离子染料的天然或合成氨基酸。 用这些染料获得人毛发上的非常好的染色结果。
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公开(公告)号：US08118882B2
公开(公告)日：2012-02-21
申请号：US12812782
申请日：2009-01-07
IPC分类号： A61Q5/10 , C07D213/09
CPC分类号： C09B69/101 , C09B1/32 , C09B1/34 , C09B69/106
摘要： Disclosed are cationic oligomeric dye, comprising a low molecular weight polyamine comprising the repeating units (1a) or (1b), wherein at least 90% of the polyamine molecules are selected from tetramines, pentamines and hexamines; and R is the residue of a cationic dye, which is covalently bonded, optionally via a linker, to the nitrogen atoms of the polyamine; or hydrogen; wherein the polyamine repeating units (1a) and (1b) comprise at least one carionic dye residue; and n is a number from 3-12. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译： 公开了阳离子低聚染料，其包含包含重复单元（1a）或（1b）的低分子量多胺，其中至少90％的多胺分子选自四胺，五胺和六胺; 并且R是阳离子染料的残基，其任选地经由接头共价键合到多胺的氮原子上; 或氢; 其中所述多胺重复单元（1a）和（1b）包含至少一个卡莲染料残基; n是3-12的数字。 这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。
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公开(公告)号：US20110110998A1
公开(公告)日：2011-05-12
申请号：US12309091
申请日：2007-07-04
CPC分类号： C08G77/388 , A01N55/00
摘要： Disclosed are oligo- or polysiloxanes, which are characterized by containing at least 3, for example 4-3000, Si atoms in the main chain, and wherein at least one thereof is contained in a moiety of the formula (I) whose open bond of the O atom is linked to another Si atom of the oligo- or polysiloxane main chain, and whose open bond of the Si atom is linked either to another O atom of the oligo- or polysiloxane main chain or to R′1, where R1 and R′1 independently are C1-C10alkyl, R2 and R3 independently are C1-C18alkylene, X is a divalent spacer group selected from O, NR4, N(COR′5), CONR′4, OCONR′4;. Y is selected from OCOR5, NHCOR5, NHR4, COOR5, CONHR4, NR′4R4; R4 is selected from C6-C18 organic residues containing at least one aryl moiety; R′4 is as defined for R4; or is selected from H, C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl; R5 is R7—Z; R′5 is as defined for R5; or is selected from H, C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl; R7 is C1-C20alkylene, which may be interrupted by phenylene, C4-C12cycloalkylene, O, NR′4; or is unsubstituted or substituted phenylene or C4-C12cycloalkylene; Z is halogen or N+R8R8R10; R8, R9 and R10 independently are selected from C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl, unsubstituted or substituted aryl; or 2 of R8, R9 and R10 are linked together to form a quaternized aliphatic, substituted or unsubstituted N-heterocyclic ring of 4-6 carbon atoms such as a piperidine ring; or all of R8, R9 and R10 are linked together to form, together with the nitrogen atom they are bonding to, a substituted or unsubstituted N-heterocyclic ring system of 4-7 carbon atoms. The novel compounds are effective as antimicrobials.
摘要翻译： 公开了低聚或聚硅氧烷，其特征在于在主链中含有至少3个，例如4-3000个Si原子，并且其中至少一个包含在式（I）的部分中，其开环键 O原子与低聚或聚硅氧烷主链的另一个Si原子连接，并且其Si原子的开环键连接到寡聚或聚硅氧烷主链的另一个O原子或R'1，其中R 1和 R 1独立地是C 1 -C 10烷基，R 2和R 3独立地是C 1 -C 18亚烷基，X是选自O，NR 4，N（COR'5），CONR 4，OCONR 4的二价间隔基。 Y选自OCOR5，NHCOR5，NHR4，COOR5，CONHR4，NR'4R4; R4选自含有至少一个芳基部分的C6-C18有机残基; R'4如R4所定义; 或选自H，C 1 -C 20烷基，C 7 -C 20苯基烷基，C 4 -C 12环烷基; R5为R7-Z; R'5如R5所定义; 或选自H，C 1 -C 20烷基，C 7 -C 20苯基烷基，C 4 -C 12环烷基; R 7是C 1 -C 20亚烷基，其可被亚苯基，C 4 -C 12亚环烷基，O，NR'4中间; 或未取代或取代的亚苯基或C 4 -C 12亚环烷基; Z为卤素或N + R8R8R10; R 8，R 9和R 10独立地选自C 1 -C 20烷基，C 7 -C 20苯基烷基，C 4 -C 12环烷基，未取代或取代的芳基; 或2的R 8，R 9和R 10连接在一起形成4-6个碳原子的季铵化的脂族，取代或未取代的N-杂环，例如哌啶环; 或全部R 8，R 9和R 10连接在一起，与它们所键合的氮原子一起形成取代或未取代的4-7个碳原子的N-杂环体系。 新型化合物作为抗微生物剂是有效的。
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公开(公告)号：US20110061180A1
公开(公告)日：2011-03-17
申请号：US12812782
申请日：2009-01-07
IPC分类号： A61K8/81 , A61Q5/10 , C09B46/00 , C07C211/63
CPC分类号： C09B69/101 , C09B1/32 , C09B1/34 , C09B69/106
摘要： Disclosed are cationic oligomeric dye, comprising a low molecular weight polyamine comprising the repeating units (1a) or (1b), wherein at least 90% of the polyamine molecules are selected from tetramines, pentamines and hexamines; and R is the residue of a cationic dye, which is covalently bonded, optionally via a linker, to the nitrogen atoms of the polyamine; or hydrogen; wherein the polyamine repeating units (1a) and (1b) comprise at least one carionic dye residue; and n is a number from 3-12. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译： 公开了阳离子低聚染料，其包含包含重复单元（1a）或（1b）的低分子量多胺，其中至少90％的多胺分子选自四胺，五胺和六胺; 并且R是阳离子染料的残基，其任选地经由接头共价键合到多胺的氮原子上; 或氢; 其中所述多胺重复单元（1a）和（1b）包含至少一个卡莲染料残基; n是3-12的数字。 这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。
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公开(公告)号：US07828858B2
公开(公告)日：2010-11-09
申请号：US11992929
申请日：2006-09-13
IPC分类号： A61Q5/10 , C07D277/26
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译： 公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。 染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。
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公开(公告)号：US20090229059A1
公开(公告)日：2009-09-17
申请号：US11992878
申请日：2006-09-27
申请人： Christian Cremer , Olof Wallquist
发明人： Christian Cremer , Olof Wallquist
摘要： Disclosed are oxazine disulfide dyes of formula (1) D1-(Z1)r-Y1—S-A, wherein A is hydrogen; or a radical of formula (1a)*—S—Y2-(Z2)r-D2; Y1 and Y2 independently from each other are unsubstituted or substituted, straight-chain or branched, interrupted or uninterrupted C—1—C—10alkylene; C5-C10cycloalkylene; C5-C10arylene; or —C5-C10arylene-(C1-C10alkylene); Z1 and Z2 independently from each other are *—(CH2)p—C(O)—**; *—(CH2CH2—O)S—**; *—(CH2)p—C(O)O—**; *—(CH2)p—OCO—**; *—(CH2)P—N(R1)—**; formula 1(g); —(CH2)p—CON(R1)—**; *—(CH2)p—(R1)NC(O)—**; , 0-; —S—; —S(O)—; —S(O)2—; or a cationic biradical of a substituted or unsubstituted aromatic or heteroaromatic compound of the formula (1a); (1b); (1c); (1d); or (1e); wherein the asterix * indicates the linkage to D1 and/or D2; the asterix ** indicates the linkage to Y1 and/or Y2; W1 is N or a radical of CR5; R1, R2, R3, R4 and R5 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C5-C10aryl; C5-C10aryl-(C1-C10alkyl); or —C1-C10alkyl(C5-C10aryl); D1 and D2 independently from each other ar the residue of an organic dye selected from the radical of formula (1f); R6 and R7 independently from each other are hydrogen; C1-C20alkyl; C1-C20alkoxy; C3-C6cycloalkyl; C5-C10aryl; anellated aromatic groups; carboxylate; or sulfonate groups; R8, R9 and R10, R11 and R12 each independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl, C2-C14alkenyl, C6-C10aryl, C6-C10aryl-C1-C10alkyl or C5-C10alkyl(C5-C10aryl); or R8 and R9 or R10 and R11, together with the linking nitrogen atom form a 5 to 7 membered carbocyclic ring which may contain one or more than one hetero atom; or R8 is linked to C1 together with N+ forming a 5-7 membered carbocyclic ring; or R9 is linked to C2 together with N+ forming a 5-7 membered carbocyclic ring; X is —O—; or —N(R9)—; or —S—; p is a number from 0 to 5; r is 0 or 1; and s is a number from 1 to 5. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
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公开(公告)号：US20090130045A1
公开(公告)日：2009-05-21
申请号：US11921810
申请日：2006-06-14
申请人： Christian Cremer , Olof Wallquist
发明人： Christian Cremer , Olof Wallquist
IPC分类号： A61K8/46 , C07C321/20
摘要： Disclosed are nitro-sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R2, R3, independently from each other are hydrogen; C1-C20alkyl or C1-C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; C3-C6cycloalkyl; —C(O)H; —C(O)—C1-C5alkyl; —C(O)OH; —C(O)O—C1-C5alkyl; halogen; NO2; OH; SH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; or a radical of formula (1a) —NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; or a radical of formula (2); wherein at least one of the radicals R1, R2 or R3 is NO2; Y1 is C1-C10alkylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-(C1-C10alkylene); Z1 is the direct bond; formula (3); or a cationic biradical of a saturated, aromatic or heteroaromatic group; Q1 is —C(O)—; —C(O)O—; —OCO—; —N(R6)—X2—; —CON(R6)—; —(R6)NC(O)—; —O—; —S—; —S(O)—; or —S(O)2—; X1 and X2 independently from each other are the direct bond; C1-C10alkylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-(C1-C10alkylene); and R6, R7 and R8 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C1-C10alkyl(C5-C10aryl); m is 1; or 2; U is hydrogen, if m is 1; or the direct bond, if m is 2; with the proviso that the method does not comprise contacting hair with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
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