公开(公告)号：US20110257412A1

公开(公告)日：2011-10-20

申请号：US13140356

申请日：2009-12-17

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07C29/141 ,  C07F5/06

CPC分类号： C07F5/069 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

摘要： To provide a process for increasing the proportion of an optical isomer of not only a compound having a closed ring but also a compound not having a closed ring when an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule is subjected to a ring closing reaction. A process for increasing the proportion of an optical isomer characterized by subjecting an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule to a ring closing reaction in the presence of a predetermined aluminum complex represented by the general formula: [Al2(L1)n(L2)3-n]m.

摘要翻译： 为了提供不仅具有封闭环的化合物的光学异构体的比例而且当具有甲酰基和双键的化合物的光学异构体混合物能够引起 在相同分子中的羰基 - 烯环闭合反应进行闭环反应。 一种增加光学异构体比例的方法，其特征在于使具有能够在同一分子中引起羰基 - 烯环闭合反应的甲酰基和双键的化合物的旋光异构体混合物在 由通式[Al2（L1）n（L2）3-n] m表示的预定铝络合物的存在。

公开(公告)号：US08580991B2

公开(公告)日：2013-11-12

申请号：US13140356

申请日：2009-12-17

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07D305/00 ,  C07F5/06

CPC分类号： C07F5/069 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

摘要： To provide a process for increasing the proportion of an optical isomer of not only a compound having a closed ring but also a compound not having a closed ring when an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule is subjected to a ring closing reaction. A process for increasing the proportion of an optical isomer characterized by subjecting an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule to a ring closing reaction in the presence of a predetermined aluminum complex represented by the general formula: [Al2(L1)n(L2)3-n]m.

摘要翻译： 为了提供不仅具有封闭环的化合物的光学异构体的比例而且当具有甲酰基和双键的化合物的光学异构体混合物能够引起 在相同分子中的羰基 - 烯环闭合反应进行闭环反应。 一种增加光学异构体比例的方法，其特征在于使具有能够在同一分子中引起羰基 - 烯环闭合反应的甲酰基和双键的化合物的旋光异构体混合物在 由通式[Al2（L1）n（L2）3-n] m表示的预定铝络合物的存在。

公开(公告)号：US08329930B2

公开(公告)日：2012-12-11

申请号：US12991967

申请日：2009-05-25

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07F5/06 ,  C07C35/08

CPC分类号： C07C39/235 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/56 ,  C07C45/67 ,  C07C2601/14 ,  C07F5/069 ,  C07C35/17 ,  C07C47/21

摘要： Provided is a process in which cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, increases the ratio of a particular optical isomer not only in a cyclized compound, but also in an unreacted compound. The process comprises performing, in the presence of a specified aluminum complex represented by the general formula: [Al2(L1)n(L2)3-n]m, cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, to increase the ratio of a particular optical isomer.

摘要翻译： 提供一种方法，其中在分子中使具有允许羰基环环化的甲酰基和双键的化合物作为其光学异构体的混合物存在的化合物的环化增加了特定光学异构体的比例 仅在环化化合物中，而且在未反应的化合物中。 该方法包括在由通式[Al2（L1）n（L2）3-n] m表示的规定的铝络合物的存在下进行，分子中具有甲酰基和双 允许羰基环环化的键，作为其光学异构体的混合物存在的化合物，以增加特定光学异构体的比例。

公开(公告)号：US20110082308A1

公开(公告)日：2011-04-07

申请号：US12991967

申请日：2009-05-25

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07C29/00 ,  C07F5/06

CPC分类号： C07C39/235 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/56 ,  C07C45/67 ,  C07C2601/14 ,  C07F5/069 ,  C07C35/17 ,  C07C47/21

摘要： Provided is a process in which cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, increases the ratio of a particular optical isomer not only in a cyclized compound, but also in an unreacted compound. The process comprises performing, in the presence of a specified aluminum complex represented by the general formula: [Al2(L1)n(L2)3-m]m, cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, to increase the ratio of a particular optical isomer.

摘要翻译： 提供一种方法，其中在分子中使具有允许羰基环环化的甲酰基和双键的化合物作为其光学异构体的混合物存在的化合物的环化增加了特定光学异构体的比例 仅在环化化合物中，而且在未反应的化合物中。 该方法包括在由通式[Al2（L1）n（L2）3-m] m表示的规定的铝络合物的存在下进行，分子中具有甲酰基和双 允许羰基环环化的键，作为其光学异构体的混合物存在的化合物，以增加特定光学异构体的比例。

公开(公告)号：US20060094875A1

公开(公告)日：2006-05-04

申请号：US10533303

申请日：2003-10-17

申请人： Hisanori Itoh ,  Yuji Nakayama ,  Yoshimasa Matsushima ,  Yoji Hori

发明人： Hisanori Itoh ,  Yuji Nakayama ,  Yoshimasa Matsushima ,  Yoji Hori

IPC分类号： C07F15/00 ,  H01L51/54 ,  C09K11/06

CPC分类号： C07F15/0093 ,  C07D213/53 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5048 ,  H01L51/5096

摘要： The invention aims at providing platinum complexes useful as materials for light emitting devices and extremely excellent in heat stability, luminous characteristics, and luminous efficiency, and a process for effective preparation thereof. The invention relates to platinum complexes represented by the general formula [1]: wherein any two of A, B and C are each independently an optionally substituted nitrogenous aromatic heterocyclic group and the other is optionally substituted aryl or optionally substituted heteroaryl; and Y is halogeno or an optionally substituted aryl or heteroaryl group which is bonded either directly or through oxygen (—O—) or sulfur (—S—) (with the proviso that when the adjacent two rings are nitrogenous aromatic heterocyclic groups, the cases wherein Y is chloro are excepted, while when the nonadjacent two rings are nitrogenous aromatic heterocyclic groups, the cases wherein Y is not halogeno are excepted).

摘要翻译： 本发明旨在提供可用作发光器件材料的铂络合物，并且热稳定性，发光特性和发光效率极好，以及其制备方法。 本发明涉及由通式[1]表示的铂络合物：其中A，B和C中的任何两个各自独立地为任选取代的含氮芳族杂环基，另一个为任选取代的芳基或任选取代的杂芳基; Y为卤素或任选取代的芳基或杂芳基，其直接或通过氧（-O-）或硫（-S-）键合（条件是当相邻的两个环为含氮芳族杂环基时） 其中Y为氯的除外，而当不相邻的两个环为含氮芳族杂环基时，除了Y不是卤素的情况外）。

公开(公告)号：US08329931B2

公开(公告)日：2012-12-11

申请号：US13115608

申请日：2011-05-25

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07F5/06 ,  C07C35/08

CPC分类号： C07F5/066 ,  B01J31/143 ,  B01J2231/52 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

摘要： A catalyst for obtaining isopulegol of high diastereoselectivity by highly selective cyclization reaction of citronellal is provided. The present invention relates to an organoaluminum compound obtained by reacting at least one organoaluminumoxy compound selected from the group consisting of chain aluminoxanes, cyclic aluminoxanes and bis(dialkylaluminumoxy)alkylboranes, with at least one hydroxy compound selected from the group consisting of diarylphenols, bis(diarylphenol) compounds, biaryldiols, dimethanols and silanols.

摘要翻译： 提供了通过香茅醛的高度选择性环化反应获得高非对映选择性的异ule醇的催化剂。 本发明涉及通过使至少一种选自链铝氧烷，环状铝氧烷和双（二烷基铝氧基）烷基硼烷的有机铝氧化合物与至少一种选自二芳基酚，二（ 二芳基苯酚）化合物，联芳二醇，二甲醇和硅烷醇。

公开(公告)号：US20110319638A1

公开(公告)日：2011-12-29

申请号：US13140213

申请日：2009-12-17

申请人： Hisanori Itoh ,  Yoji Hori

发明人： Hisanori Itoh ,  Yoji Hori

IPC分类号： C07C29/56 ,  C07F5/06

CPC分类号： C07F5/069 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

摘要： To provide a process for increasing the proportion of an optical isomer of not only a compound having a closed ring but also a compound not having a closed ring when an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule is subjected to a ring closing reaction. A process for increasing the proportion of an optical isomer characterized by subjecting an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule to a ring closing reaction in the presence of a predetermined aluminum complex represented by the general formula: [Al1(L1)1(L2)m(Lh)n]k.

摘要翻译： 为了提供不仅具有封闭环的化合物的光学异构体的比例而且当具有甲酰基和双键的化合物的光学异构体混合物能够引起 在相同分子中的羰基 - 烯环闭合反应进行闭环反应。 一种增加光学异构体比例的方法，其特征在于使具有能够在同一分子中引起羰基 - 烯环闭合反应的甲酰基和双键的化合物的旋光异构体混合物在 存在由通式[Al1（L1）1（L2）m（Lh）n] k表示的预定铝络合物。

公开(公告)号：US07442797B2

公开(公告)日：2008-10-28

申请号：US10578237

申请日：2004-10-27

申请人： Hisanori Itoh ,  Yuji Nakayama ,  Takeshi Iwata ,  Yoshimasa Matsushima ,  Yoji Hori

发明人： Hisanori Itoh ,  Yuji Nakayama ,  Takeshi Iwata ,  Yoshimasa Matsushima ,  Yoji Hori

IPC分类号： C07F15/00 ,  H01J63/04

CPC分类号： C07D213/74 ,  C07D213/06 ,  C07D213/30 ,  C07D213/53 ,  C07D213/64 ,  C07D277/28 ,  C07D401/14 ,  C07D409/14 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/1096 ,  C09K2211/185 ,  H01L51/0087 ,  H01L51/5016 ,  H05B33/14

摘要： Provision of a novel platinum complex which is useful as a material for a light-emitting device of good light emission characteristic and light emission efficiency, and a novel light-emitting material that may be utilized in various fields.A platinum complex represented by the following general formula (1): (in which two rings of ring A, ring B, ring C, and ring D represent nitrogen-containing heterocyclic rings which may have a substituent and the remaining two rings of them represent aryl rings or hetero aryl rings which may have a substituent, the ring A and the ring B, the ring A and the ring C or/and the ring B and the rind D may form condensed rings. Two of X1, X2, X3, and X4 represent nitrogen atoms coordination bonded to a platinum atom and the remaining two of them represent carbon atoms or nitrogen atoms. Q1, Q2, and Q3 each represents a bond, oxygen atom, sulfur atom or bivalent group, two of Z1, Z2, Z3, and Z4 represent coordination bonds, and the remaining two of them represent covalent bonds, oxygen atoms or sulfur atoms), and a light-emitting device containing the platinum complex.

摘要翻译： 提供可用作发光特性好，发光效率好的发光元件的材料的新颖的铂络合物，以及可用于各种领域的新颖的发光材料。 由以下通式（1）表示的铂络合物（其中环A，环B，环C和环D的两个环表示可以具有取代基的含氮杂环，其余两个环表示 可以具有取代基的芳基环或杂芳基环，环A和环B，环A和环C或/和环B和外皮D可形成稠环，X 1， X 2，X 3，X 3和X 4表示与铂原子配位键合的氮原子，其余两个表示 碳原子或氮原子，Q 1，Q 2，和Q 3各自表示键，氧原子，硫原子或二价基团， Z 1，Z 2，Z 3，Z 4和Z 4中的两个表示配位键，其余两个 它们代表共价键，氧原子或硫原子）和含有铂络合物的发光器件。

公开(公告)号：US20070103060A1

公开(公告)日：2007-05-10

申请号：US10578237

申请日：2004-10-27

申请人： Hisanori Itoh ,  Yuji Nakayama ,  Takeshi Iwata ,  Yoshimasa Matsushima ,  Yoji Hori

发明人： Hisanori Itoh ,  Yuji Nakayama ,  Takeshi Iwata ,  Yoshimasa Matsushima ,  Yoji Hori

IPC分类号： H01J1/62 ,  C07F15/00

CPC分类号： C07D213/74 ,  C07D213/06 ,  C07D213/30 ,  C07D213/53 ,  C07D213/64 ,  C07D277/28 ,  C07D401/14 ,  C07D409/14 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/1096 ,  C09K2211/185 ,  H01L51/0087 ,  H01L51/5016 ,  H05B33/14

摘要： Provision of a novel platinum complex which is useful as a material for a light-emitting device of good light emission characteristic and light emission efficiency, and a novel light-emitting material that may be utilized in various fields. A platinum complex represented by the following general formula (1): (in which two rings of ring A, ring B, ring C, and ring D represent nitrogen-containing heterocyclic rings which may have a substituent and the remaining two rings of them represent aryl rings or hetero aryl rings which may have a substituent, the ring A and the ring B, the ring A and the ring C or/and the ring B and the rind D may form condensed rings. Two of X1, X2, X3, and X4 represent nitrogen atoms coordination bonded to a platinum atom and the remaining two of them represent carbon atoms or nitrogen atoms. Q1, Q2, and Q3 each represents a bond, oxygen atom, sulfur atom or bivalent group, two of Z1, Z2, Z3, and Z4 represent coordination bonds, and the remaining two of them represent covalent bonds, oxygen atoms or sulfur atoms), and a light-emitting device containing the platinum complex.

摘要翻译： 提供可用作发光特性好，发光效率好的发光元件的材料的新颖的铂络合物，以及可用于各种领域的新颖的发光材料。 由以下通式（1）表示的铂络合物（其中环A，环B，环C和环D的两个环表示可以具有取代基的含氮杂环，其余两个环表示 可以具有取代基的芳基环或杂芳基环，环A和环B，环A和环C或/和环B和外皮D可形成稠环，X 1， X 2，X 3，X 3和X 4表示与铂原子配位键合的氮原子，其余两个表示 碳原子或氮原子，Q 1，Q 2，和Q 3各自表示键，氧原子，硫原子或二价基团， Z 1，Z 2，Z 3，Z 4和Z 4中的两个表示配位键，其余两个 它们代表共价键，氧原子或硫原子）和含有铂络合物的发光器件。

公开(公告)号：US09061959B2

公开(公告)日：2015-06-23

申请号：US13990872

申请日：2011-12-01

申请人： Hironori Maeda ,  Hisanori Itoh ,  Shinya Yamada ,  Yoji Hori

发明人： Hironori Maeda ,  Hisanori Itoh ,  Shinya Yamada ,  Yoji Hori

IPC分类号： C07C29/132 ,  C07B53/00 ,  C07C29/17 ,  C07C29/56 ,  B01J31/18 ,  B01J31/26 ,  B01J21/18 ,  B01J23/44

CPC分类号： C07C29/132 ,  B01J21/18 ,  B01J23/44 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/17 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/12 ,  C07C35/17

摘要： An object of the present invention is to provide a method for manufacturing an optically active menthol having fewer steps, which generates less environmentally polluting waste because a catalytic reaction is involved in all of the steps, and is capable of saving a production cost. The present invention relates to a method for manufacturing an optically active menthol, including the following steps: A-1) asymmetrically hydrogenating at least one of geranial and neral to thereby obtain an optically active citronellal, B-1) conducting a ring-closure reaction of the optically active citronellal in the presence of an acid catalyst to thereby obtain an optically active isopulegol, and C-1) hydrogenating the optically active isopulegol to thereby obtain an optically active menthol.

摘要翻译： 本发明的目的是提供一种制造具有较少步骤的光学活性薄荷醇的方法，其由于在所有步骤中都涉及催化反应而产生较少环境污染的废物，并且能够节省生产成本。 本发明涉及一种光学活性薄荷醇的制造方法，其包括以下步骤：A-1）不对称地氢化至少一种香叶酸和盐酸，从而获得光学活性香茅醛B-1，进行闭环反应 的光学活性香茅醛在酸催化剂的存在下反应，从而得到光学活性的异胡列酮，和C-1）氢化光学活性异胡脑酮，从而得到光学活性的薄荷醇。