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16 条记录 (耗时 0.029 秒)

    Metal exchanged zeolite catalysts for alcohol amination
    2.
    发明授权
    Metal exchanged zeolite catalysts for alcohol amination 失效
    用于醇胺化的金属交换沸石催化剂

    公开(公告)号：US5917092A

    公开(公告)日：1999-06-29

    申请号：US49540

    申请日：1998-03-27

    申请人： Gamini Ananda Vedage ,  Lenore Ann Emig ,  Hong-Xin Li ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  Lenore Ann Emig ,  Hong-Xin Li ,  John Nelson Armor

    IPC分类号： C07C209/16 ,  C07C211/03 ,  C07C211/06 ,  C07C211/07 ,  C07C209/38

    CPC分类号： C07C209/16

    摘要： A process for the production of predominantly primary and secondary amines and little or no tertiary amines by the reductive amination of aliphatic alcohols using a metal exchanged crystalline aluminosilicate catalyst. The catalyst has a silica/alumina ratio ranging from about 10:1 to 40:1, contains about 1 to 10% by weight of cobalt or nickel and about 0.05 to 5% by weight of at least one other metal. High conversion rates are achieved at moderate temperatures and pressures.

    摘要翻译： 通过使用金属交换的结晶硅铝酸盐催化剂对脂族醇进行还原胺化，主要生产伯胺和仲胺以及很少或不含叔胺的方法。 催化剂的二氧化硅/氧化铝比例为约10:1至40:1，含约1至10重量％的钴或镍和约0.05至5重量％的至少一种其它金属。 在适度的温度和压力下实现高转化率。

    Process for the production of triethylenediamine
    4.
    发明授权
    Process for the production of triethylenediamine 失效
    三亚乙基二胺生产工艺

    公开(公告)号：US5756741A

    公开(公告)日：1998-05-26

    申请号：US751142

    申请日：1996-11-15

    申请人： John Nelson Armor ,  Jose Guadalupe Santiesteban ,  Hong-Xin Li

    发明人： John Nelson Armor ,  Jose Guadalupe Santiesteban ,  Hong-Xin Li

    IPC分类号： B01J29/40 ,  C07B61/00 ,  C07C209/60 ,  C07C209/62 ,  C07C211/09 ,  C07D487/08

    CPC分类号： C07D487/08

    摘要： A process for preparing triethylenediamine by passing an amine compound over a catalyst at elevated temperature to afford a reaction product containing triethylenediamine and piperazine, the amine compound having, in the molecule, a moiety represented by the following general formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and X is oxygen or nitrogen characterized by adding an ethylating compound containing at least one nitrogen and/or oxygen atom to the reaction product and contacting the reaction product, under conditions sufficient to produce triethylenediamine from the ethylating compound and piperazine, with a condensation/cyclization shape-selective zeolite catalyst demonstrating a triethylenediamine/piperazine weight ratio uptake value of at least 6:1.

    摘要翻译： 一种通过使胺化合物在升高的温度下通过催化剂制备三亚乙基二胺的方法，得到含有三亚乙基二胺和哌嗪的反应产物，所述胺化合物在分子中具有由以下通式表示的部分，其中R1，R2 R 3和R 4独立地是氢原子或具有1至4个碳原子的烷基，X是氧或氮，其特征在于向反应产物中加入含有至少一个氮原子和/或氧原子的乙基化合物，并使反应产物 在足以从乙基化合物和哌嗪产生三亚乙基二胺的条件下，使用缩合/环化形状选择性沸石催化剂，证明三亚乙基二胺/哌嗪的重量比吸收值至少为6:1。

    Selective reductive amination of nitriles
    8.
    发明授权
    Selective reductive amination of nitriles 失效
    腈的选择性还原胺化

    公开(公告)号：US06248925B1

    公开(公告)日：2001-06-19

    申请号：US09425678

    申请日：1999-10-22

    申请人： Michael Edward Ford ,  John Nelson Armor

    发明人： Michael Edward Ford ,  John Nelson Armor

    IPC分类号： C07C20948

    CPC分类号： C07C209/48 ,  C07C211/08

    摘要： This invention pertains to an improvement in a process for the formation of secondary or tertiary amines by the catalytic reductive amination of a nitrile with a primary or secondary amine and, particularly to the reductive amination of C8-20 nitrites with a secondary amine. The catalyst employed in the improved reductive amination process is one which has been promoted with a lithium salt or base, e.g., lithium chloride or lithium hydroxide.

    摘要翻译： 本发明涉及通过腈与伯胺或仲胺的催化还原胺化形成仲胺或叔胺的方法的改进，特别是涉及用仲胺还原胺化C8-20亚硝酸酯。 用于改进的还原胺化方法中的催化剂是用锂盐或碱如氯化锂或氢氧化锂促进的。

    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts
    9.
    发明授权
    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts 失效
    芳香胺的氢化生成它们的环氢化对应物

    公开(公告)号：US06140540A

    公开(公告)日：2000-10-31

    申请号：US43646

    申请日：1993-04-06

    申请人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    IPC分类号： B01J23/89 ,  C07C209/72 ,  C07C209/00

    CPC分类号： B01J23/8913 ,  C07C209/72

    摘要： This invention relates to an improved hydrogenation and isomerization process wherein aromatic amines are hydrogenated to their ring hydrogenated counterparts and substantially isomerized to their thermodynamic form. These aromatic amines are presented by the formulas: ##STR1## wherein R is hydrogen or C.sub.1-6 alkyl, R1 and R2 are hydrogen or C.sub.1-6 aliphatic, A is C.sub.1-4 or NH; n is 0-2, x is 1-3 and y is 0 to 2 except the sum of the y groups must be at least 1.

    摘要翻译： 本发明涉及改进的氢化和异构化方法，其中芳族胺被氢化成它们的环氢化对应物并基本上异构化成它们的热力学形式。 这些芳族胺由下式表示：其中R是氢或C 1-6烷基，R 1和R 2是氢或C 1-6脂族基，A是C 1-4或NH; n为0-2，x为1-3且y为0至2，除了y基团之和必须至少为1。

    Selective reductive amination of nitriles
    10.
    发明授权
    Selective reductive amination of nitriles 失效
    腈的选择性还原胺化

    公开(公告)号：US06399830B1

    公开(公告)日：2002-06-04

    申请号：US09735587

    申请日：2000-12-13

    申请人： John Nelson Armor ,  Michael Edward Ford ,  William Eamon Carroll

    发明人： John Nelson Armor ,  Michael Edward Ford ,  William Eamon Carroll

    IPC分类号： C07C20948

    CPC分类号： C07C209/48 ,  C07C211/09

    摘要： This invention pertains to an improvement in a process for the formation of secondary or tertiary amines by the catalytic reductive amination of a nitrile with a primary amine. The catalyst employed in the improved reductive amination process is one that has been promoted with an acidic promoter preferably a solid phase acidic promoter.

    摘要翻译： 本发明涉及通过腈与伯胺的催化还原胺化形成仲胺或叔胺的方法的改进。 用于改进的还原胺化方法中的催化剂是用酸性促进剂优选固相酸性促进剂促进的。