摘要:
Mixtures curable thermally and with actinic radiation and containing carbamate and/or allophanate groups, comprising (A) at least one of (A1) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (A2) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and additionally allophanate- and/or carbamate-reactive functional groups, which are substantially or entirely free from reactive functional groups which contain at least one bond which can be activated with actinic radiation, and (C) at least one constituent containing on average per molecule at least one reactive functional group having at least one bond which can be activated with actinic radiation; with the proviso that if only (A1) is used, the mixtures further comprise (B) at least one of low molecular mass compounds, oligomers and polymers containing allophanate- and/or carbamate-reactive functional groups.
摘要:
Coating materials including at least one hydroxyl-containing (meth)acrylate (co)polymer, at least one carbamate- and hydroxyl-containing compound and at least one amino resin, where at least 10 equivalent % of the hydroxyl groups present in the (meth)acrylate (co)polymers and/or the carbamate and hydroxyl containing compound are primary hydroxyl groups. The coating materials after curing have a storage modulus E′ in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E′ having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 μm. Also included is a processes for preparing the coating materials and applications therefor.
摘要:
A curable composition comprising (A) constituents containing carbamate groups I: —O—C(O)—NHR (I) in which R=a hydrogen atom or an alkyl, cycloalkyl or aryl group, (B) constituents containing carbamate-reactive groups, the equivalents ratio of carbamate-reactive groups in (B) to carbamate groups in (A) being >0.2, (C) adducts preparable from (c1) polyisocyanates and (c2) compounds II containing isocyanate-reactive functional groups: in which R1 and R2: independently of one another are hydrogen atoms or alkyl radicals; X and Y: oxygen atom, sulfur atom or a radical >N—R6, in which R6=aliphatic radical; R3: is an alkylene radical; R4 and R5: are hydrogen atoms, isocyanate-reactive functional groups or R6; with the proviso that one group R4, R5 or R6 contains an isocyanate-reactive functional group or R4 or R5 is an isocyanate-reactive functional group and the other radicals R4, R5 or R6—where present—contain no isocyanate-reactive groups; the molar ratio of (c1) to (c2) being chosen such that the adducts (C) contain in the molecule isocyanate groups; process for its preparation, and its use.
摘要:
A multicomponent system comprising (I) a component comprising (A) an oligomer and/or polymer containing allophanate groups and/or carbamate groups, (B) an oligomer and/or polymer containing isocyanate-reactive functional groups, (C) a partly or fully alkylated amino resin, and (D) a compound containing groups which can be activated with actinic radiation; and (II) a component comprising (E) a polyisocyanate, with the proviso that the equivalents ratio of isocyanate groups in component (II) to isocyanate-reactive functional groups in component (I) is from 0.2:1 to 1:0.2 and the equivalents ratio of allophanate groups and/or carbamate groups in the oligomer and/or polymer (A) to the N-methylol ether groups or the N-methylol and N-methylol ether groups in the amino resin (C) is from 0.2:1 to 1:0.2; and its use to produce mixtures curable thermally and with actinic radiation.
摘要:
Heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, comprising (A) at least one oligomer and/or polymer selected from the group consisting of oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (B) at least one thixotropic agent selected from the group consisting of urea or urea derivatives preparable by reacting at least one amine and/or water with at least one polyisocyanate, with the proviso that the mixture in question, based on its solids, further comprises at least one silica as thixotropic agent (C), and contains the thixotropic agent (B) in an amount of from 0.1 to 5% by weight if the oligomers and polymers (A) contain no allophanate groups; processes for preparing the mixtures, and their use as coating materials, adhesives and sealing compounds.
摘要:
Novel aqueous dispersion comprising at least one polymer containing on average (i) at least one primary and/or secondary carbamate group, (ii) at least one functional group having at least one bond which may be activated with actinic radiation, and (iii) at least one dispersive ionic functional group; process for preparing it and its use for preparing coating materials, adhesives and sealing compounds which are curable thermally and with actinic radiation, and also novel coating materials, adhesives and sealing compounds consisting of or comprising the novel aqueous dispersion.
摘要:
The invention relates to a coating material that can be cured thermally or by actinic radiation and that contains at least one component (a1) with at least two functional groups (a11) which serve for cross-linking, by actinic radiation, and at least one functional group (a12) that can enter into thermal cross-linking reactions with the hydroxyl and/or thiol groups (a21) in component (a2), at least one branched cyclic and/or acyclic C9-C16 alkane (a2)) that is functionalized with at least two hydroxyl or thiol groups (a21) or with at least one hydroxyl and at least one thiol group, and optionally at least one photo initiator (a3), at least one initiator of the thermal cross-linking reaction (a4), at least one reactive diluent that is cured by actinic radiation and/or thermafly, at least one lacquer additive (a6), at least one thermally curable component (a7) and/or at least one organic solvent (a8). The inventive coating material is used to produce transparent lacquers and multi-layer chromophor and/or effect lacquers.
摘要:
A process for producing a clearcoat and a multi-component composition. The process comprises applying the multi-component composition to a primed substrate, an unprimed substrate, or a coated substrate. The multi-component composition comprises (A) a binder containing on average at least one isocyanate-reactive functional group, (B) an adduct prepared from (b1) a diisocyanate and (b2) a compound of the general formula I containing an isocyanate-reactive group: and (C) at least one cross-linking agent containing on average at least one isocyanate group and at least one functional group which may be activated by actinic reaction.
摘要:
The invention relates to a powder-slurry that can be hardened by actinic radiation or by thermal means, comprising (I) components containing functional groups (A) which render them hardenable by actinic radiation and components containing complementary functional groups (B) which render them thermally hardenable, in a weight ratio of 50:1 to 1:50 and/or comprising (II) components containing the functional groups (A) and (B) which render them thermally hardenable and hardenable by actinic radiation in a molar ratio of 100:1 to 1:100.
摘要:
A mixture and method for preparing a composition curable thermally and with actinic radiation comprising a binder free from carbon-carbon double bonds activatable with actinic radiation, at least one blocked or unblocked polyisocyanate having at least one soft, flexibilizing segment, and at least one unsaturated polyfunctional urethane that is free from isocyanate-reactive functional groups and contains on average per molecule more than four carbon-carbon double bonds activatable with actinic radiation and at least one hardening segment.