公开(公告)号：US06716891B1

公开(公告)日：2004-04-06

申请号：US09926532

申请日：2001-11-16

申请人： Uwe Meisenburg ,  Heinz-Peter Rink ,  Karl-Heinz Joost ,  Hubert Baumgart

发明人： Uwe Meisenburg ,  Heinz-Peter Rink ,  Karl-Heinz Joost ,  Hubert Baumgart

IPC分类号： C08F246

CPC分类号： C09D175/16 ,  C09D4/06 ,  Y10T428/31511 ,  Y10T428/31533 ,  Y10T428/31551 ,  Y10T428/31794 ,  Y10T428/31855 ,  C08F290/067 ,  C08F290/061

摘要： The invention relates to a coating material that can be cured thermally or by actinic radiation and that contains at least one component (a1) with at least two functional groups (a11) which serve for cross-linking, by actinic radiation, and at least one functional group (a12) that can enter into thermal cross-linking reactions with the hydroxyl and/or thiol groups (a21) in component (a2), at least one branched cyclic and/or acyclic C9-C16 alkane (a2)) that is functionalized with at least two hydroxyl or thiol groups (a21) or with at least one hydroxyl and at least one thiol group, and optionally at least one photo initiator (a3), at least one initiator of the thermal cross-linking reaction (a4), at least one reactive diluent that is cured by actinic radiation and/or thermafly, at least one lacquer additive (a6), at least one thermally curable component (a7) and/or at least one organic solvent (a8). The inventive coating material is used to produce transparent lacquers and multi-layer chromophor and/or effect lacquers.

摘要翻译： 本发明涉及一种可以热或通过光化辐射固化并且含有至少一种具有至少两个用于通过光化辐射交联的官能团（a11）的组分（a1）的涂料，以及至少一种 可以与组分（a2）中的羟基和/或硫醇基团（a21），至少一种支链环状和/或非环状C 9 -C 16烷烃（a2）进行热交换反应的官能团（a12） 用至少两个羟基或硫醇基团（a21）或至少一个羟基和至少一个硫醇基官能化，和任选地至少一个光引发剂（a3），至少一个热交联反应引发剂（a4） ，至少一种通过光化辐射和/或热解固化的反应性稀释剂，至少一种漆添加剂（a6），至少一种可热固化组分（a7）和/或至少一种有机溶剂（a8）。 本发明的涂料用于生产透明漆和多层发色体和/或效果漆。

公开(公告)号：US06777090B2

公开(公告)日：2004-08-17

申请号：US10130934

申请日：2002-06-19

申请人： Hubert Baumgart ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Paul J. Harris ,  Reinhold Schwalm

发明人： Hubert Baumgart ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Paul J. Harris ,  Reinhold Schwalm

IPC分类号： B32B3126

CPC分类号： C09D201/025 ,  C08G18/3831 ,  C08G18/672 ,  C09J201/025 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31938

摘要： Composition curable thermally and with actinic radiation (dual-cure composition) comprising A) at least one constituent containing on average per molecule at least one primary or secondary carbamate group and at least one bond which can be activated with actinic radiation and preparable by from polyfunctional compounds containing at least two isocyanate-reactive, acid-reactive or epoxide-reactive functional groups and suitable monoisocyanates, monoacids or monoepoxides or from polyisocyanates, polyacids or polyepoxides and suitable compounds which contain an isocyanate-reactive, acid-reactive or epoxide-reactive functional group; and B) at least one constituent containing on average per molecule at least one carbamate-reactive functional group and also, where appropriate, at least one bond which can be activated with actinic radiation; and its use as adhesive, sealing compound and coating material.

摘要翻译： 包含可热固化和与光化辐射（双重固化组合物）组合的组合物，其包含：A）每分子平均含有至少一个伯或仲氨基甲酸酯基团和至少一个可以用光化辐射活化并可由多官能化合物制备的键的至少一种成分 含有至少两种异氰酸酯反应性，酸反应性或环氧化物反应性官能团和合适的单异氰酸酯，单酸或单环氧化物或由多异氰酸酯，多元酸或聚环氧化物和含有异氰酸酯反应性，酸反应性或环氧化物反应性官能团的合适化合物 ; 和B）每分子平均含有至少一个氨基甲酸酯反应性官能团的至少一种组分，并且在适当的情况下还可以使用至少一种可用光化辐射活化的键;以及其用作粘合剂，密封剂和涂料。

公开(公告)号：US07169877B2

公开(公告)日：2007-01-30

申请号：US10380916

申请日：2001-09-26

申请人： Hubert Baumgart ,  Uwe Meisenburg ,  Heinz-Peter Rink

发明人： Hubert Baumgart ,  Uwe Meisenburg ,  Heinz-Peter Rink

IPC分类号： B05D7/14 ,  B05D1/36 ,  B05D3/02 ,  B05D3/06 ,  C08G18/00

CPC分类号： C09D175/16 ,  C08G18/2875 ,  C08G18/6254 ,  C08G18/807 ,  C08G18/8175 ,  C08G18/62

摘要： A process for producing a clearcoat and a multi-component composition. The process comprises applying the multi-component composition to a primed substrate, an unprimed substrate, or a coated substrate. The multi-component composition comprises (A) a binder containing on average at least one isocyanate-reactive functional group, (B) an adduct prepared from (b1) a diisocyanate and (b2) a compound of the general formula I containing an isocyanate-reactive group: and (C) at least one cross-linking agent containing on average at least one isocyanate group and at least one functional group which may be activated by actinic reaction.

摘要翻译： 一种制备透明涂层和多组分组合物的方法。 该方法包括将多组分组合物施加到底漆衬底，未染色的衬底或涂覆的衬底上。 多组分组合物包含（A）平均含有至少一种异氰酸酯反应性官能团的粘合剂，（B）由（b1）二异氰酸酯制备的加合物和（b2）含有异氰酸酯反应性官能团的通式I化合物， 反应性基团：和（C）至少一种含有至少一个异氰酸酯基团和至少一个可通过光化反应活化的官能团的交联剂。

公开(公告)号：US20060211835A1

公开(公告)日：2006-09-21

申请号：US10543647

申请日：2004-01-28

申请人： Hubert Baumgart ,  Susanne Neumann ,  Karl-Heinz Joost ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Nicole Stegemann

发明人： Hubert Baumgart ,  Susanne Neumann ,  Karl-Heinz Joost ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Nicole Stegemann

IPC分类号： C08F136/00

CPC分类号： C08F212/32 ,  C09D4/00 ,  C08F222/1006

摘要： A composition curable with actinic radiation, containing at least one compound (A) selected from the group consisting of p-menthadienes and olefinically unsaturated monomers, processes for preparing it, and the use thereof.

摘要翻译： 一种可用光化辐射固化的组合物，其含有至少一种选自对甲苯二烯和烯属不饱和单体的化合物（A），其制备方法及其用途。

公开(公告)号：US5914374A

公开(公告)日：1999-06-22

申请号：US803411

申请日：1997-02-20

申请人： Vera Block ,  Harald Borgholte ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Ludwig Moorkamp

发明人： Vera Block ,  Harald Borgholte ,  Uwe Meisenburg ,  Heinz-Peter Rink ,  Ludwig Moorkamp

IPC分类号： C08G18/42 ,  C08G63/20 ,  C09D175/06 ,  C08F20/00 ,  C08L67/00

CPC分类号： C08G18/4205 ,  C09D175/06

摘要： A urethanized polyester is claimed which is suitable as an additive for aqueous coating systems, which is obtainable by, in a first reaction stage (A), subjecting(a) from 10 to 45 mol-% of one or more diols,(b) from 5 to 50 mol-% of one or more polyols having at least 3 OH groups, and(c) from 35 to 47 mol-% of one or more aromatic, aliphatic or cycloaliphatic polycarboxylic acids and/or reactive derivatives thereof to a polycondensation reaction in a manner known per se until the reaction mixture has an acid number of from 1 to 10, and, in a reaction stage (B), reacting the resulting reaction product in a manner known per se with an organic polyisocyanate. The urethanized polyester is outstandingly suitable as an additive for aqueous coating materials in order to improve the rheological stabilization of coating materials.

摘要翻译： 要求保护的氨基甲酸酯化聚酯可用作水性涂料体系的添加剂，其可通过在第一反应阶段（A）中获得，（a）10至45mol％的一种或多种二醇，（b） 5至50摩尔％的一种或多种具有至少3个OH基团的多元醇，和（c）35至47摩尔％的一种或多种芳族，脂族或脂环族多羧酸和/或其反应性衍生物与缩聚物 以本身已知的方式进行反应，直到反应混合物的酸值为1至10，并且在反应阶段（B）中，使所得反应产物以本身已知的方式与有机多异氰酸酯反应。 氨基甲酸酯化聚酯非常适合用作水性涂料的添加剂，以改善涂料的流变稳定性。

公开(公告)号：US5876802A

公开(公告)日：1999-03-02

申请号：US836869

申请日：1997-07-03

申请人： Michael Brunnemann ,  Uwe Meisenburg ,  Egbert Nienhaus ,  Heinz-Peter Rink

发明人： Michael Brunnemann ,  Uwe Meisenburg ,  Egbert Nienhaus ,  Heinz-Peter Rink

IPC分类号： B05D7/24 ,  C08G18/62 ,  C08J3/03 ,  C09D133/00 ,  C09D175/04 ,  B05D1/36

CPC分类号： C08G18/6254 ,  C08G18/6229

摘要： The present invention relates to an aqueous two-component polyurethane coating composition comprisingA) a water-dilutable polyacrylate resin (A) having an OH number of from 40 to 200 and an acid number of from 20 to 100 mg of KOH/g, andB) a polyisocyanate component,characterized in that the water-dilutable acrylate resin is obtainable by solution polymerization ofat least one ester of (meth)acrylic acid and a cycloaliphatic C.sub.6 to C.sub.10 alcohol, with the exception of cyclohexyl methacrylate,at least one hydroxyl-containing monomer,if desired, at least one vinyl ester of .alpha.-branched monocarboxylic acids having 5 to 18 carbon atoms per molecule and/or at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of .alpha.-branched monocarboxylic acids having 5 to 18 carbon atoms per molecule,at least one carboxyl-containing monomer and,if desired, further, essentially carboxyl-free monomers,the resulting polyacrylate resin being at least partially neutralized and dispersed in water.

摘要翻译： PCT No.PCT / EP95 / 04234 371日期1997年7月3日 102（e）日期1997年7月3日PCT提交1995年10月28日PCT公布。 WO96 / 14348 PCT出版物 日期：1996年5月17日本发明涉及一种水性双组分聚氨酯涂料组合物，其包含A）水可稀释的聚丙烯酸酯树脂（A），其OH值为40至200，酸值为20至100mg的KOH / g，和B）多异氰酸酯组分，其特征在于，水可稀释丙烯酸酯树脂可通过至少一种（甲基）丙烯酸酯和脂环族C 6至C 10醇的酯的溶液聚合获得，甲基丙烯酸环己酯除外， 至少一个含羟基的单体，如果需要，每分子具有至少一个具有5至18个碳原子的α-支链单羧酸乙烯基酯和/或至少一种丙烯酸和/或甲基丙烯酸与缩水甘油酯的反应产物 每分子具有5至18个碳原子的α-支化单羧酸，至少一种含羧基单体，并且如果需要，进一步基本上不含羧基的单体，所得聚丙烯酸酯树脂为 至少部分中和并分散在水中。

公开(公告)号：US06653394B1

公开(公告)日：2003-11-25

申请号：US09856949

申请日：2001-06-22

申请人： Uwe Meisenburg ,  Heinz-Peter Rink

发明人： Uwe Meisenburg ,  Heinz-Peter Rink

IPC分类号： C08J300

CPC分类号： C08G18/0823 ,  C09D175/06 ,  C08L75/04

摘要： A coating composition consisting of at least three components, comprising a component (I) comprising at least one oligomeric or polymeric resin containing functional groups which react with isocyanate groups, as binder (A), a component (II) comprising at least one polyisocyanate as crosslinking agent (F), and a component (III) which comprises water, wherein component (I), (II) and/or (III) comprise or comprises at least one constituent which is curable with actinic light and/or electron beams.

摘要翻译： 由至少三种组分组成的涂料组合物，其包含至少一种包含与异氰酸酯基团反应的官能团的低聚物或聚合树脂作为粘合剂（A）的组分（I），包含至少一种多异氰酸酯的组分（II） 交联剂（F）和包含水的组分（III），其中组分（I），（II）和/或（III）包含或包含至少一种可用光化学光和/或电子束固化的组分。

公开(公告)号：US20060205837A1

公开(公告)日：2006-09-14

申请号：US10533112

申请日：2003-10-27

申请人： Uwe Meisenburg ,  Heinz-Peter Rink ,  Daniel Couturier ,  Isabelle Couturier-Verlhac

发明人： Uwe Meisenburg ,  Heinz-Peter Rink ,  Daniel Couturier ,  Isabelle Couturier-Verlhac

IPC分类号： C03C25/10

CPC分类号： C09D175/16 ,  C08G18/8116 ,  C08G71/04

摘要： Compounds which can be activated by actinic radiation, contain at least one urethane group, and have the general formula I: X[N(R)—C(O)—O—C(R1R2)—C(R3R4)—Y-Z]n  (I), in which the index and the variables have the following meanings: n is an integer from 1 to 5; X is an at least n-valent, substituted or unsubstituted organic radical; R is a hydrogen atom or a monovalent substituted or unsubstituted organic radical; R1-R4 independently of one another are a hydrogen atom, halogen atom or monovalent, substituted or unsubstituted organic radical, it being possible for at least two radicals to be cyclically linked to one another; Y is a divalent, linking functional group containing at least one oxygen atom; and Z is an organic radical containing at least one group which can be activated by actinic radiation; with the proviso that at least for n=1 the radical R and/or the radical X are/is substituted by at least one substituent of the general formula II: Z—Y—  (II), in which the variables Z and Y are as defined above; processes for preparing them, and their use.

摘要翻译： 可以通过光化辐射活化的化合物含有至少一个氨基甲酸酯基团，并且具有通式I：<？in-line-formula description =“In-line Formulas”end =“lead”？> X [N（R ）-C（O）-OC（R 1，R 2） - C（R 3 R 4） -YZ] （I），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中索引和变量具有以下含义：n 是从1到5的整数; X是至少n价的取代或未取代的有机基团; R是氢原子或一价取代或未取代的有机基团; R 1〜R 4彼此独立地是氢原子，卤素原子或一价的，取代或未取代的有机基团，至少两个基团可以是周期性的 相互联系 Y是含有至少一个氧原子的二价连接官能团; Z是含有至少一个可被光化辐射活化的基团的有机基团; 条件是至少对于n = 1，基团R和/或基团X被至少一个通式II的取代基取代：<？in-line-formula description =“In-line Formulas”end =“lead”？> ZY-（II），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中变量Z和Y如上所定义; 制备它们的过程及其用途。

公开(公告)号：US06677045B1

公开(公告)日：2004-01-13

申请号：US09485982

申请日：2000-04-04

申请人： Uwe Meisenburg ,  Karl-Heinz Joost ,  Andrea Hesselmaier ,  Heinz-Peter Rink ,  Reinhold Schwaim ,  Erich Beck ,  Rainer Königer

发明人： Uwe Meisenburg ,  Karl-Heinz Joost ,  Andrea Hesselmaier ,  Heinz-Peter Rink ,  Reinhold Schwaim ,  Erich Beck ,  Rainer Königer

IPC分类号： B32B2716

CPC分类号： B05D7/536 ,  B05D3/067 ,  B05D3/068 ,  B05D7/546 ,  C09D167/07 ,  C09D175/16 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31862 ,  Y10T428/31909 ,  Y10T428/31928

摘要： The present invention relates to a multilayer coating comprising at least one basecoat layer and one topcoat layer, the coating being preparable by A. applying a component (I), if desired radiation-curable component, based on polyurethane resins, polyacrylate resins, polyester resins and/or amino resins and also mixtures thereof to a substrate and subjecting it to thermal partial crosslinking or drying at temperatures of less than 100° C., preferably 60-80° C., and B. applying a topcoat to this coating layer, and subsequently carrying out radiation curing.

摘要翻译： 本发明涉及包含至少一个底涂层和一个顶涂层的多层涂层，该涂层可由A制备。 将基于聚氨酯树脂，聚丙烯酸酯树脂，聚酯树脂和/或氨基树脂以及它们的混合物的组分（I）（如果需要的可辐射固化组分）施用到基材上，并使其在小于等于的温度下进行热部分交联或干燥 100℃，优选60-80℃。 在该涂层上涂上面漆，然后进行辐射固化。

公开(公告)号：US07601765B2

公开(公告)日：2009-10-13

申请号：US10532575

申请日：2003-11-05

申请人： Heinz-Peter Rink ,  Susanne Neumann ,  Uwe Meisenburg ,  Karl-Heinz Joost ,  Dietmar Häring ,  Bernhard Hauer

发明人： Heinz-Peter Rink ,  Susanne Neumann ,  Uwe Meisenburg ,  Karl-Heinz Joost ,  Dietmar Häring ,  Bernhard Hauer

IPC分类号： C08F2/46 ,  C08F2/00 ,  C08F2/38 ,  C08F22/10 ,  C08F22/00

CPC分类号： C12P7/625 ,  C08F8/00 ,  C09D133/04 ,  C09D133/14 ,  C12P7/62 ,  Y10S522/912 ,  C08F220/10

摘要： The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.

摘要翻译： 本发明涉及通过制备含羟基官能侧链的聚（甲基）丙烯酸酯并酯交换或酯化含羟基的聚（甲基）丙烯酸酯而制备光化可辐射固化和/或双重固化的聚（甲基）丙烯酸酯的方法。 具有（甲基）丙烯酸酯或（甲基）丙烯酸的官能侧链。 本发明还涉及光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯本身以及使用光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯在制备 分散体或作为包含至少一种光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯的涂料配方和面漆中的组分。