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    Stabilizer composition
    4.
    发明授权
    Stabilizer composition 失效
    稳定剂组成

    公开(公告)号：US06492442B1

    公开(公告)日：2002-12-10

    申请号：US09676985

    申请日：2000-10-02

    申请人： Manfred Appel ,  Hubert Trauth ,  Jürgen Krockenberger ,  Alexander Aumüller

    发明人： Manfred Appel ,  Hubert Trauth ,  Jürgen Krockenberger ,  Alexander Aumüller

    IPC分类号： C08K51575

    CPC分类号： C08K5/10 ,  C08K5/005 ,  C08K5/1345 ,  C08L75/04 ,  C08L35/00

    摘要： Described is a stabilizer composition comprising a 3-arylacrylic ester, a polymeric compound having a molecular weight of at least 2000 which carries, on a polymeric framework, side groups having secondary amine functions, all substituents positioned to the amine nitrogen being other than hydrogen, a chroman derivative, and an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane against light, oxygen and heat.

    摘要翻译： 描述了一种稳定剂组合物，其包含3-芳基丙烯酸酯，分子量至少为2000的聚合化合物，其在聚合物骨架上带有具有仲胺官能团的侧基，位于胺氮以外的所有取代基不同于氢， 苯并二氢吡喃衍生物和有机亚磷酸酯和/或亚膦酸酯。 稳定剂组合物特别适合于稳定热塑性聚氨酯以抵抗光，氧和热。

    Use of isoindolinone derivatives as stabilizers for organic materials
    5.
    发明授权
    Use of isoindolinone derivatives as stabilizers for organic materials 失效
    异吲哚啉酮衍生物作为有机材料的稳定剂的使用

    公开(公告)号：US06210657B1

    公开(公告)日：2001-04-03

    申请号：US09207624

    申请日：1998-12-09

    申请人： Thorsten Habeck ,  Sylke Haremza ,  Hubert Trauth ,  Volker Schehlmann ,  Horst Westenfelder

    发明人： Thorsten Habeck ,  Sylke Haremza ,  Hubert Trauth ,  Volker Schehlmann ,  Horst Westenfelder

    IPC分类号： A61K742

    CPC分类号： A61K31/4035 ,  C08K5/3417 ,  C09D7/48 ,  C09K15/30 ,  Y10S514/844 ,  Y10S514/97 ,  Y10S514/972

    摘要： Isoindolinone derivatives of the formula I, in which the variables have the following meanings: R1 is hydrogen, COOR4, COR4, CONR4R5, CN, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, aryl or heteroaryl, substituted or unsubstituted; R1 and R2 together are C7-C10-bicycloalkyl or C7-C10-bicycloalkenyl; R3 is hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl or heteroaryl, substituted or unsubstituted, substituents which confer solubility in water, selected from the group consisting of carboxylate, sulfonate or ammonium radicals; R4 and R5 independently of one another are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl; aryl or heteroaryl, substituted or unsubstituted; are used as stabilizers for organic materials.

    摘要翻译： 式I的异吲哚啉酮衍生物，其中变量具有以下含义：R1是氢，COOR4，COR4，CONR4R5，CN，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3-C10- 环烯基，芳基或杂芳基，取代或未取代的; R1和R2一起是C7-C10-双环烷基或C7-C10-双环烯基; R3是氢，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20 - 烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基或杂芳基，取代或未取代的赋予水溶性的取代基， 羧酸酯，磺酸酯或铵基; R 4和R 5彼此独立地是氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烯基; 芳基或杂芳基，取代或未取代的;被用作有机材料的稳定剂。

    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives
    8.
    发明授权
    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives 失效
    N-（β-羰基 - 和β-氰基乙烯基）-2,2,6,6-四甲基 - 哌啶衍生物

    公开(公告)号：US5434202A

    公开(公告)日：1995-07-18

    申请号：US244209

    申请日：1994-06-03

    申请人： Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    发明人： Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    IPC分类号： C07D211/46 ,  C07D211/54 ,  C07D211/58 ,  C07D401/04 ,  C07D405/06 ,  C07D409/06 ,  C08K5/3432 ,  C08K5/3435

    CPC分类号： C07D211/58 ,  C07D211/46 ,  C08K5/3435

    摘要： N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.

    摘要翻译： PCT No.PCT / EP92 / 02733 Sec。 371日期：1994年6月3日 102（e）日期1994年6月3日PCT提交1992年11月27日PCT公布。 出版物WO93 / 11109 日期：6月10日，1993.N-（β-羰基 - 和β-氰基乙酰基）-2,2,6,6-四甲基哌啶衍生物，其中R1是COOR3，COR4，CONR4R5或CN，R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢，R 3是氢，C 1 -C 8 - 烷基，C 5 -C 8 - 环烷基，C 3 -C 5 - 烯基或苯基，其可以被C1-C4- 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基，R 4和R 5各自为氢，C 1 -C 12烷基，C 5 -C 8环烷基或苯基， - 被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基三取代，n为1-4，各个n的X和A定义 在规范中。

    Heterocyclic amidine derivatives
    9.
    发明授权
    Heterocyclic amidine derivatives 失效
    杂环脒衍生物

    公开(公告)号：US5047539A

    公开(公告)日：1991-09-10

    申请号：US511302

    申请日：1990-04-19

    申请人： Peter Spang ,  Peter Neumann ,  Hubert Trauth

    发明人： Peter Spang ,  Peter Neumann ,  Hubert Trauth

    IPC分类号： C07D209/08 ,  C07D209/86 ,  C07D215/06 ,  C07D215/18 ,  C07D215/20 ,  C07D215/26 ,  C07D219/02 ,  C08K5/3417 ,  C08K5/3437

    CPC分类号： C08K5/3417 ,  C07D209/08 ,  C07D209/86 ,  C07D215/06 ,  C07D215/18 ,  C07D215/20 ,  C07D215/26 ,  C07D219/02 ,  C08K5/3437

    摘要： Heterocyclic amidine derivatives of the general formula I ##STR1## in which the variables R.sup.1 are the same or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl or chlorine,R.sup.2 to R.sup.5 denote hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.3 and R.sup.4 can together form a five-membered or six-membered ring,R.sup.6 denotes hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.7 denotes cyano or --COOR.sup.8, --COR.sup.8, --CONHR.sup.8 or --CONR.sup.8.sub.2, in whichR.sup.8 is a straight-chain or branched-chain C.sub.1 -C.sub.12 -alkyl group which may be interrupted by oxygen atoms, a cyclopentyl or cyclohexyl group or a phenylalkyl group having from 1 to 3 carbon atoms in the alkyl moiety,A is a chemical bond or a methylene group which may additionally carry one or two C.sub.1 -C.sub.4 -alkyl radicals, andm and n are each 1 or 2.The said heterocyclic amidine derivatives I serve as UV stabilizers for organic materials.

    摘要翻译： 其中变量R1相同或不同并表示氢，C1-C4-烷基，C1-C4-烷氧基，羟基或氯的通式I（I）的杂环脒衍生物，R2至R5表示氢或 C 1 -C 4烷基和R 3和R 4可以一起形成五元或六元环，R 6表示氢或C 1 -C 8 - 烷基，R 7表示氰基或-COOR 8，-COR 8，-CONHR 8或-CONR 82，其中 R8是可以被氧原子间隔的直链或支链C 1 -C 12烷基，在烷基部分具有1至3个碳原子的环戊基或环己基或苯基烷基，A是化学键 或可以另外携带一个或两个C 1 -C 4 - 烷基的亚甲基，m和n各自为1或2.所述杂环脒衍生物I用作有机材料的UV稳定剂。

    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials
    10.
    发明授权
    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials 失效
    双酚（3.3.1）壬烷衍生物，用于稳定有机物质

    公开(公告)号：US4943391A

    公开(公告)日：1990-07-24

    申请号：US286295

    申请日：1988-12-10

    申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    IPC分类号： C07D471/08 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3442 ,  C09D7/12 ,  C09K15/18

    CPC分类号： C07D471/08

    摘要： Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.

    摘要翻译： 双环[3.3.1]通式（I）的壬烷衍生物其中n是1至70的整数，R 1是氢，R 2是氢或羟基，或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基，该苯基或萘基各自可被1,2或3个C 1 -C 12烷基，C 1 -C 12烷氧基，氯，溴，氟，三氟甲基或氰基取代 在2或3个取代基的情况下，这些取代基相同或不同，A和B各自独立地为化学键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o分别为 1至20，R 10为氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，苯基或C 2 -C 22 - 氰基烷基，M为式 A不仅通过氮原子而且通过碳原子，并且R 11，R 12，R 13和R 14各自独立地为C 1 -C 4 - 烷基，或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基，R 5是氢，氰基，羟基，R 15是氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时，-MB-R 5为式（VI）的基团，其中R 16为C 1 -C 4 - 烷基，R 17为氢，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基，在塑料方面具有非常好的稳定性，是无色的，与有机聚合物高度相容并且对热分解是稳定的。