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公开(公告)号：US06436592B1
公开(公告)日：2002-08-20
申请号：US09845394
申请日：2001-04-30
IPC分类号： G03C176
CPC分类号： G03C1/7614 , G03C11/08 , G03C2001/7635 , G03C2200/47 , Y10S430/162
摘要： The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat is formed by providing a photographic element having at least one silver halide light-sensitive emulsion layer. A first coating of hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55 to 200 ° C. at a weight percent of 30 to 95, and one or more hydrophilic polymers at a total weight percent of 5 to 70 is applied to form a first layer over the silver halide light-sensitive emulsion layer. A second coating of abrasion resistant particles having an average size of from 0.01 to 1 microns is applied to form a second layer over the first layer. The coatings are dried at temperatures not exceeding the melting point of the particles used in the first coating, or of the glass transition temperature of the abrasion resistant particles used in the second coating, whichever is the lowest. After photoprocessing, the first and second layers can be fused to form a protective overcoat. The photographic element is developed to provide an imaged photographic element.
摘要翻译： 本发明是在其上具有保护性外涂层的成像照相元件。 保护性外涂层通过提供具有至少一种卤化银感光乳剂层的照相元件形成。 平均尺寸为0.01至1微米，熔化温度为55至200℃，重量百分比为30至95的疏水性聚合物颗粒和一种或多种总重量百分比为5的亲水性聚合物的第一涂层 施加到70以形成卤化银感光乳剂层上的第一层。 施加平均尺寸为0.01至1微米的耐磨颗粒的第二涂层以在第一层上形成第二层。 涂层在不超过第一涂层中使用的颗粒的熔点或第二涂层中使用的耐磨性颗粒的玻璃化转变温度的温度下进行干燥，以最低者为准。 在光处理之后，第一层和第二层可以熔合以形成保护性外涂层。 照相元件被显影以提供成像的照相元件。
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公开(公告)号：US06465165B2
公开(公告)日：2002-10-15
申请号：US09312378
申请日：1999-05-14
IPC分类号： G03C176
CPC分类号： G03C11/08 , G03C1/7614 , G03C2001/7621 , G03C2001/7635 , G03C2200/36
摘要： The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat is formed by providing a photographic element having at least one silver halide light-sensitive emulsion layer. A first coating of hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55 to 200° C. at a weight percent of 30 to 95, and gelatin at a weight percent of 5 to 70 is applied to form a first layer over the silver halide light-sensitive emulsion layer. A second coating of abrasion resistant particles having an average size of from 0.01 to 1 microns is applied to form a second layer over the first layer. The photographic element is developed to provide an imaged photographic element. The first and second layers are fused to form a protective overcoat.
摘要翻译： 本发明是在其上具有保护性外涂层的成像照相元件。 保护性外涂层通过提供具有至少一种卤化银感光乳剂层的照相元件形成。 将平均尺寸为0.01至1微米，熔化温度为55至200℃，重量百分比为30至95的疏水聚合物颗粒和重量百分比为5至70的明胶的第一涂层施加到 在卤化银感光乳剂层上形成第一层。 施加平均尺寸为0.01至1微米的耐磨颗粒的第二涂层以在第一层上形成第二层。 照相元件被显影以提供成像的照相元件。 将第一层和第二层熔合以形成保护性外涂层。
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3.发明授权Polymeric scavengers for oxidized developing agents and photographic elements containing the same 失效用于氧化发展代理的聚合物扫描器和包含其的摄影元件
公开(公告)号：US5244763A
公开(公告)日：1993-09-14
申请号：US3038
申请日：1993-01-11
申请人： Ralph B. Nielsen , Lan B. Thai , Hwei-ling Yau
发明人： Ralph B. Nielsen , Lan B. Thai , Hwei-ling Yau
摘要： Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
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公开(公告)号：US5965304A
公开(公告)日：1999-10-12
申请号：US965335
申请日：1997-11-06
CPC分类号： G03C11/08 , G03C1/7614 , Y10S430/162 , Y10S977/887 , Y10T428/24802 , Y10T428/24884
摘要： The present invention is an imaged photographic element which includes a support, at least one silver halide light-sensitive emulsion layer superposed on the support; and a protective overcoat furthest from the support. The protective overcoat is superposed on the silver halide light sensitive layer. The protective overcoat includes a first polymeric particle having a glass transition temperature of greater than or equal to 25.degree. C. and a particle size of from 5 to 500 nm and a second polymeric particle having a glass transition temperature of less than 25.degree. C. and a particle size of from 5 to 500 nm at a weight ratio of the first polymeric particle to the second polymeric particle of from 3:97 to 80:20 and wax particle having a size of from 0.01 .mu.m to 0.5 .mu.m. The protective overcoat is applied from an aqueous coating.
摘要翻译： 本发明是一种成像照相元件，其包括支撑体，叠置在支撑体上的至少一个卤化银感光乳剂层; 和距离支架最远的防护罩。 保护性外涂层叠加在卤化银感光层上。 保护性外涂层包括玻璃化转变温度大于或等于25℃，粒度为5至500nm的第一聚合物颗粒和玻璃化转变温度低于25℃的第二聚合物颗粒。 和第一聚合物颗粒与第二聚合物颗粒的重量比为3:97至80:20的颗粒尺寸为5至500nm，以及尺寸为0.01μm至0.5μm的蜡颗粒。 保护性外涂层由水性涂料施加。
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5.发明授权Silver halide photographic material containing a polymer with a photographically useful group which is rendered non-diffusible by cross-linking 失效含有通过交联使其不扩散的具有摄影有用基团的聚合物的卤化银照相材料
公开(公告)号：US5932404A
公开(公告)日：1999-08-03
申请号：US768691
申请日：1996-12-18
申请人： Tienteh Chen , Hwei-ling Yau , Dorothy T. Java
发明人： Tienteh Chen , Hwei-ling Yau , Dorothy T. Java
CPC分类号： G03C7/3275 , G03C1/053 , G03C7/396 , G03C1/30 , G03C1/8155 , G03C1/83
摘要： The present invention is a silver halide photographic material including at least one layer which contains; a polymer comprising as constituent components thereof a repeating unit having a photographically useful group and at least one repeating unit having an imidazole group; and a compound having at least one functional group which reacts with an imidazole group and at least one other functional group capable of reacting with an imidazole group and a primary amine group, the amount of the compound being sufficient to insure adequate fixation of said polymer.
摘要翻译： 本发明是一种卤化银照相材料，其包括至少一层，其含有： 作为其构成成分的聚合物，具有具有照相用基团的重复单元和至少一个具有咪唑基的重复单元; 和具有至少一个与咪唑基反应的官能团和能与咪唑基和伯胺基反应的至少一个官能团的化合物，该化合物的量足以确保所述聚合物的充分固定。
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6.发明授权Polymeric scavengers for oxidized developing agents and photographic elements containing the same 失效用于氧化发展代理的聚合物扫描器和包含其的摄影元件
公开(公告)号：US5198517A
公开(公告)日：1993-03-30
申请号：US740732
申请日：1991-08-06
申请人： Ralph B. Neilsen , Lan B. Thai , Hwei-ling Yau
发明人： Ralph B. Neilsen , Lan B. Thai , Hwei-ling Yau
摘要： Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
摘要翻译： 用于氧化显影剂和含有还原剂的光敏元件的还原剂，其中还原剂包含具有没食子酸或没食子酸衍生物部分的聚合物。
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7.发明授权Protecting layer for gelatin based photographic products containing 1H-pyrazolo[1,5,-b][1,2,4]triazole-type magenta coupler 失效含有1H-吡唑并[1,5，-b] [1,2,4]三唑型品红色成色剂的基于明胶的照相产品的保护层
公开(公告)号：US6165653A
公开(公告)日：2000-12-26
申请号：US354556
申请日：1999-07-15
申请人： Hwei-ling Yau , Brian Thomas
发明人： Hwei-ling Yau , Brian Thomas
IPC分类号： C08L25/08 , C08L25/14 , C08L33/04 , C09D127/08 , C09D201/00 , G03C1/76 , G03C1/85 , G03C7/24 , G03C7/38 , G03C11/08 , B41J2/01
CPC分类号： G03C11/08 , C08L25/08 , C08L25/14 , C08L33/04 , C09D127/08 , G03C1/7614 , G03C1/85 , G03C7/00 , G03C7/24 , G03C7/38 , G03C7/3835 , G03C2001/7448 , G03C2001/7621 , G03C2001/7635 , G03C2200/08 , G03C2200/10 , G03C2200/36 , G03C2200/51 , Y10S430/162 , C08L2666/04
摘要： An overcoat composition comprising a water insoluble polymer having a Tg equal to or less than 30.degree. C. and comprising 75 to 100 weight percent of the monomer having the following formula: ##STR1## wherein: X is selected from the group consisting of Cl, F or CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, n-C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl, C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, C.sub.2 F.sub.5, n-C.sub.3 F.sub.7, iso-C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5 ; and wherein said overcoat composition being superposed on an imaged light sensitive silver halide emulsion layer on a support, said silver halide emulsion layer containing 1H-pyrazolo[1,5-b][1,2,4]triazole type of magenta coupler. Optionally, the polymer composition may contain a second polymer having a Tg greater than 30.degree. C.
摘要翻译： 一种外涂层组合物，其包含Tg等于或小于30℃的水不溶性聚合物，并且包含75至100重量％的具有下式的单体：其中：X选自Cl，F或CN 并且Y各自独立地选自H，Cl，F，CN，CF 3，CH 3，C 2 H 5，n-C 3 H 7，异-C 3 H 7，n-C 4 H 9，n -C 5 H 11，n-C 6 H 13，OCH 3，OC 2 H 5， 苯基，C 6 F 5，C 6 Cl 5，CH 2 Cl，CH 2 F，C 2 F 5，n -C 3 F 7，异-C 3 F 7，OCF 3，OC 2 F 5，OC 3 F 7，C（CF 3）3，CH 2（CF 3），CH（CF 3）2，COCF 3，COC 2 F 5，COCH 3，COC 2 H 5 ; 并且其中所述外涂层组合物叠加在载体上成像的感光卤化银乳剂层上，所述卤化银乳剂层含有1H-吡唑并[1,5-b] [1,2,4]三唑型品红成色剂。 任选地，聚合物组合物可以含有Tg大于30℃的第二聚合物
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公开(公告)号：US5856051A
公开(公告)日：1999-01-05
申请号：US898985
申请日：1997-07-23
CPC分类号： G03C11/08 , G03C1/7614 , G03C1/74 , Y10S430/162
摘要： The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat formed by the steps of providing a photographic element having at least one silver halide light-sensitive emulsion layer; applying a coating comprising hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55.degree. to 200.degree. C. at a weight percent of 30 to 95, and gelatin at a weight percent of 5 to 70 over the at least one silver halide light-sensitive emulsion layer. The silver halide light sensitive emulsion layer is developed to provide an imaged photographic element. The hydrophobic polymer particles are then fused to form a protective overcoat. In an alternate embodiment the coating further includes water soluble polymer materials at a weight percent of from 5 to 45.
摘要翻译： 本发明是在其上具有保护性外涂层的成像照相元件。 通过提供具有至少一个卤化银感光乳剂层的照相元件的步骤形成的保护外涂层; 施加包含平均尺寸为0.01至1微米，熔化温度为55至200℃，重量百分比为30至95的疏水聚合物颗粒和重量百分比为5至70的明胶的涂层， 至少一种卤化银感光乳剂层。 显影卤化银感光乳剂层以提供成像的照相元件。 然后将疏水性聚合物颗粒熔合以形成保护性外涂层。 在替代实施方案中，该涂层还包括重量百分比为5至45的水溶性聚合物材料。
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