Scratch resistant-water resistant overcoat for photographic systems
    3.
    发明授权
    Scratch resistant-water resistant overcoat for photographic systems 失效
    用于摄影系统的防刮水防水外套

    公开(公告)号:US06436592B1

    公开(公告)日:2002-08-20

    申请号:US09845394

    申请日:2001-04-30

    IPC分类号: G03C176

    摘要: The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat is formed by providing a photographic element having at least one silver halide light-sensitive emulsion layer. A first coating of hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55 to 200 ° C. at a weight percent of 30 to 95, and one or more hydrophilic polymers at a total weight percent of 5 to 70 is applied to form a first layer over the silver halide light-sensitive emulsion layer. A second coating of abrasion resistant particles having an average size of from 0.01 to 1 microns is applied to form a second layer over the first layer. The coatings are dried at temperatures not exceeding the melting point of the particles used in the first coating, or of the glass transition temperature of the abrasion resistant particles used in the second coating, whichever is the lowest. After photoprocessing, the first and second layers can be fused to form a protective overcoat. The photographic element is developed to provide an imaged photographic element.

    摘要翻译: 本发明是在其上具有保护性外涂层的成像照相元件。 保护性外涂层通过提供具有至少一种卤化银感光乳剂层的照相元件形成。 平均尺寸为0.01至1微米,熔化温度为55至200℃,重量百分比为30至95的疏水性聚合物颗粒和一种或多种总重量百分比为5的亲水性聚合物的第一涂层 施加到70以形成卤化银感光乳剂层上的第一层。 施加平均尺寸为0.01至1微米的耐磨颗粒的第二涂层以在第一层上形成第二层。 涂层在不超过第一涂层中使用的颗粒的熔点或第二涂层中使用的耐磨性颗粒的玻璃化转变温度的温度下进行干燥,以最低者为准。 在光处理之后,第一层和第二层可以熔合以形成保护性外涂层。 照相元件被显影以提供成像的照相元件。

    Protecting layer for gelatin based AGX photographic products
    4.
    发明授权
    Protecting layer for gelatin based AGX photographic products 失效
    用于基于明胶的AGX摄影产品的保护层

    公开(公告)号:US5965304A

    公开(公告)日:1999-10-12

    申请号:US965335

    申请日:1997-11-06

    摘要: The present invention is an imaged photographic element which includes a support, at least one silver halide light-sensitive emulsion layer superposed on the support; and a protective overcoat furthest from the support. The protective overcoat is superposed on the silver halide light sensitive layer. The protective overcoat includes a first polymeric particle having a glass transition temperature of greater than or equal to 25.degree. C. and a particle size of from 5 to 500 nm and a second polymeric particle having a glass transition temperature of less than 25.degree. C. and a particle size of from 5 to 500 nm at a weight ratio of the first polymeric particle to the second polymeric particle of from 3:97 to 80:20 and wax particle having a size of from 0.01 .mu.m to 0.5 .mu.m. The protective overcoat is applied from an aqueous coating.

    摘要翻译: 本发明是一种成像照相元件,其包括支撑体,叠置在支撑体上的至少一个卤化银感光乳剂层; 和距离支架最远的防护罩。 保护性外涂层叠加在卤化银感光层上。 保护性外涂层包括玻璃化转变温度大于或等于25℃,粒度为5至500nm的第一聚合物颗粒和玻璃化转变温度低于25℃的第二聚合物颗粒。 和第一聚合物颗粒与第二聚合物颗粒的重量比为3:97至80:20的颗粒尺寸为5至500nm,以及尺寸为0.01μm至0.5μm的蜡颗粒。 保护性外涂层由水性涂料施加。

    Scratch resistant-water resistant overcoat for photographic systems
    6.
    发明授权
    Scratch resistant-water resistant overcoat for photographic systems 失效
    用于摄影系统的防刮水防水外套

    公开(公告)号:US06465165B2

    公开(公告)日:2002-10-15

    申请号:US09312378

    申请日:1999-05-14

    IPC分类号: G03C176

    摘要: The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat is formed by providing a photographic element having at least one silver halide light-sensitive emulsion layer. A first coating of hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55 to 200° C. at a weight percent of 30 to 95, and gelatin at a weight percent of 5 to 70 is applied to form a first layer over the silver halide light-sensitive emulsion layer. A second coating of abrasion resistant particles having an average size of from 0.01 to 1 microns is applied to form a second layer over the first layer. The photographic element is developed to provide an imaged photographic element. The first and second layers are fused to form a protective overcoat.

    摘要翻译: 本发明是在其上具有保护性外涂层的成像照相元件。 保护性外涂层通过提供具有至少一种卤化银感光乳剂层的照相元件形成。 将平均尺寸为0.01至1微米,熔化温度为55至200℃,重量百分比为30至95的疏水聚合物颗粒和重量百分比为5至70的明胶的第一涂层施加到 在卤化银感光乳剂层上形成第一层。 施加平均尺寸为0.01至1微米的耐磨颗粒的第二涂层以在第一层上形成第二层。 照相元件被显影以提供成像的照相元件。 将第一层和第二层熔合以形成保护性外涂层。

    Protecting layer for gelatin based photographic products containing
1H-pyrazolo[1,5,-b][1,2,4]triazole-type magenta coupler
    7.
    发明授权
    Protecting layer for gelatin based photographic products containing 1H-pyrazolo[1,5,-b][1,2,4]triazole-type magenta coupler 失效
    含有1H-吡唑并[1,5,-b] [1,2,4]三唑型品红色成色剂的基于明胶的照相产品的保护层

    公开(公告)号:US6165653A

    公开(公告)日:2000-12-26

    申请号:US354556

    申请日:1999-07-15

    摘要: An overcoat composition comprising a water insoluble polymer having a Tg equal to or less than 30.degree. C. and comprising 75 to 100 weight percent of the monomer having the following formula: ##STR1## wherein: X is selected from the group consisting of Cl, F or CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, n-C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl, C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, C.sub.2 F.sub.5, n-C.sub.3 F.sub.7, iso-C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5 ; and wherein said overcoat composition being superposed on an imaged light sensitive silver halide emulsion layer on a support, said silver halide emulsion layer containing 1H-pyrazolo[1,5-b][1,2,4]triazole type of magenta coupler. Optionally, the polymer composition may contain a second polymer having a Tg greater than 30.degree. C.

    摘要翻译: 一种外涂层组合物,其包含Tg等于或小于30℃的水不溶性聚合物,并且包含75至100重量%的具有下式的单体:其中:X选自Cl,F或CN 并且Y各自独立地选自H,Cl,F,CN,CF 3,CH 3,C 2 H 5,n-C 3 H 7,异-C 3 H 7,n-C 4 H 9,n -C 5 H 11,n-C 6 H 13,OCH 3,OC 2 H 5, 苯基,C 6 F 5,C 6 Cl 5,CH 2 Cl,CH 2 F,C 2 F 5,n -C 3 F 7,异-C 3 F 7,OCF 3,OC 2 F 5,OC 3 F 7,C(CF 3)3,CH 2(CF 3),CH(CF 3)2,COCF 3,COC 2 F 5,COCH 3,COC 2 H 5 ; 并且其中所述外涂层组合物叠加在载体上成像的感光卤化银乳剂层上,所述卤化银乳剂层含有1H-吡唑并[1,5-b] [1,2,4]三唑型品红成色剂。 任选地,聚合物组合物可以含有Tg大于30℃的第二聚合物

    Water-resistant protective overcoat for AgX photographic system
    8.
    发明授权
    Water-resistant protective overcoat for AgX photographic system 失效
    AgX摄影系统防水保护罩

    公开(公告)号:US5856051A

    公开(公告)日:1999-01-05

    申请号:US898985

    申请日:1997-07-23

    IPC分类号: G03C1/74 G03C1/76 G03C11/08

    摘要: The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat formed by the steps of providing a photographic element having at least one silver halide light-sensitive emulsion layer; applying a coating comprising hydrophobic polymer particles having an average size of 0.01 to 1 microns, a melting temperature of from 55.degree. to 200.degree. C. at a weight percent of 30 to 95, and gelatin at a weight percent of 5 to 70 over the at least one silver halide light-sensitive emulsion layer. The silver halide light sensitive emulsion layer is developed to provide an imaged photographic element. The hydrophobic polymer particles are then fused to form a protective overcoat. In an alternate embodiment the coating further includes water soluble polymer materials at a weight percent of from 5 to 45.

    摘要翻译: 本发明是在其上具有保护性外涂层的成像照相元件。 通过提供具有至少一个卤化银感光乳剂层的照相元件的步骤形成的保护外涂层; 施加包含平均尺寸为0.01至1微米,熔化温度为55至200℃,重量百分比为30至95的疏水聚合物颗粒和重量百分比为5至70的明胶的涂层, 至少一种卤化银感光乳剂层。 显影卤化银感光乳剂层以提供成像的照相元件。 然后将疏水性聚合物颗粒熔合以形成保护性外涂层。 在替代实施方案中,该涂层还包括重量百分比为5至45的水溶性聚合物材料。