公开(公告)号：US20150299068A1

公开(公告)日：2015-10-22

申请号：US14646877

申请日：2013-11-18

申请人： IFP ENERGIES NOUVELLES ,  TOTAL RESEARCH & TECHNOLOGY FELUY

发明人： Vincent COUPARD ,  Natacha TOUCHAIS ,  Thomas PLENNEVAUX ,  Emilie KOBEL ,  Stephanie FLEURIER ,  Walter VERMEIREN ,  Delphine MINOUX ,  Philip DE SMEDT ,  Cindy ADAM ,  Nikolai NESTERENKO

IPC分类号： C07C1/24 ,  C07C41/09

CPC分类号： C07C1/24 ,  C07C29/76 ,  C07C41/09 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/85 ,  Y02P30/48 ,  C07C43/06 ,  C07C11/04 ,  C07C31/08

摘要： A process for dehydration of an ethanol feedstock to ethylene by: a) preheating ethanol feedstock by heat exchange with effluent from e), b) pretreating the ethanol feedstock to produce pretreated ethanol feedstock, c) vaporizing a vaporization feedstock containing pretreated ethanol feedstock and at least a portion of the flow of treated water recycled in an exchanger to produce a vaporized feedstock, d) compressing said vaporized feedstock to produce a compressed feedstock, e) dehydrating said compressed feedstock in at least one adiabatic reactor, f) separating the effluent from the last adiabatic reactor of e) into an effluent containing ethylene and an effluent containing water, g) purifying at least a portion of the effluent containing water from 0 and separating at least one flow of treated water and at least one flow of unconverted ethanol, h) recycling at least a portion of the flow of treated water from g) upstream of c).

摘要翻译： 乙醇原料通过以下方法脱乙醇的方法：a）通过与来自e）的流出物热交换来预热乙醇原料，b）预处理乙醇原料以产生经预处理的乙醇原料，c）蒸发含有经预处理的乙醇原料的蒸发原料， 在交换器中再循环的经处理水的至少一部分流动以产生蒸发的原料，d）压缩所述蒸发的原料以产生压缩原料，e）使至少一个绝热反应器中的所述压缩原料脱水，f）将流出物从 将e）的最后绝热反应器装入含有乙烯和含水的流出物的流出物中，g）将至少一部分含有水的流出物从0中纯化并分离至少一个处理水流和至少一个未转化的乙醇流， h）从c）上游再循环处理水流的至少一部分。

公开(公告)号：US20200001266A1

公开(公告)日：2020-01-02

申请号：US16456313

申请日：2019-06-28

申请人： IFP Energies nouvelles

发明人： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC分类号： B01J19/24 ,  B01J8/22 ,  B01J23/755 ,  C07C2/24 ,  B01J8/18 ,  B01F3/04 ,  B01J23/26

摘要： Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear α-olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

公开(公告)号：US20200094213A1

公开(公告)日：2020-03-26

申请号：US16577665

申请日：2019-09-20

申请人： IFP Energies nouvelles

发明人： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC分类号： B01J10/00 ,  B01J23/755 ,  C07C2/08 ,  B01J19/00

摘要： Compartmentalized reactor which makes possible the oligomerization of olefins to give linear olefins and preferably to give linear α-olefins, comprising a reaction chamber and at least one heat exchanger(s). The compartmentalized reactor is also employed in an oligomerization process.

公开(公告)号：US20130090510A1

公开(公告)日：2013-04-11

申请号：US13646002

申请日：2012-10-05

申请人： TOTAL RESEARCH & TECHNOLOGY ,  IFP ENERGIES NOUVELLES

发明人： Vincent COUPARD ,  Natacha TOUCHAIS ,  Stephanie FLEURIER ,  Helena GONZALEZ PENAS ,  Philip DE SMEDT ,  Walter VERMEIREN ,  Cindy ADAM ,  Delphine MINOUX

IPC分类号： C07C1/24

CPC分类号： C07C1/24 ,  C07C2529/40 ,  Y02P30/48 ,  C07C11/04

摘要： A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said dilute hydrated ethanol feedstock in an exchanger, with heat exchange with the effluent that is obtained from a last reactor, with said mixture being introduced into said vaporization stage at a pressure that is lower than the pressure of the effluent that is obtained from the last reactor, the compression of the mixture that is vaporized in a compressor, the introduction of the vaporized and compressed mixture, into at least one adiabatic reactor that contains at least one dehydration catalyst.

摘要翻译： 一种将乙醇原料脱水成乙烯的方法，包括在交换器中蒸发所述稀水合乙醇原料，与最后一个反应器获得的流出物进行热交换，所述混合物在压力下被引入所述蒸发阶段 低于从最后一个反应器获得的流出物的压力，在压缩机中蒸发的混合物的压缩，将蒸发和压缩的混合物引入到至少一个绝热反应器中，该绝热反应器含有至少一个脱水 催化剂。

公开(公告)号：US20210107846A1

公开(公告)日：2021-04-15

申请号：US17256786

申请日：2019-06-21

申请人： IFP Energies Nouvelles

发明人： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC分类号： C07C2/32 ,  B01J19/00 ,  B01J19/24

摘要： The invention relates to a process for the oligomerization of ethylene, carried out at a pressure of between 0.1 and 10.0 MPa, at a temperature of between 30 and 200° C., in a cascade of N gas/liquid reactors in series, N being at least equal to 2, comprising a step of introducing a catalytic oligomerization system into at least the first reactor of the cascade, a step of bringing said catalytic system and an optional solvent into contact with ethylene by introducing said ethylene into the lower part of the reaction chamber of at least the first reactor of the cascade, for each reactor n, a step of withdrawing a liquid fraction in the lower part of the reaction chamber of the reactor n, the liquid fraction being separated into two streams: a first stream corresponding to a first, “main”, part of the liquid fraction, which is conveyed to a heat exchanger for cooling; a second stream corresponding to the second part of the liquid fraction which constitutes the liquid feedstock of the following reactor n+1 in the cascade, a step of introducing said second part of the liquid phase withdrawn from the reactor n towards the reaction chamber of the following reactor n+1 in the direction of flow, a step of cooling said first part of the liquid fraction withdrawn from the reactor n in step c) by passing said first part of the liquid fraction into a heat exchanger in order to obtain a cooled liquid fraction, a step of introducing said liquid fraction cooled in step e) at the top of the reaction chamber of said reactor n, the steps a) to f) being carried out, unless indicated otherwise, for each reactor n of the cascade, n being between 1 and N. The invention also relates to a device of N stirred gas/liquid reactors in a cascade, enabling the oligomerization process to be carried out.

公开(公告)号：US20130211161A1

公开(公告)日：2013-08-15

申请号：US13767072

申请日：2013-02-14

申请人： IFP ENERGIES NOUVELLES

发明人： Frédéric FEUGNET ,  Francois HUGUES ,  Natacha TOUCHAIS ,  Hugues DULOT ,  Annick PUCCI

IPC分类号： C10G69/12

CPC分类号： C10G69/126 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

摘要： The present invention describes a process for converting a heavy feed which is flexible for the production of propylene, gasoline and middle distillate.The process uses a catalytic cracking unit and a unit for the oligomerization of C4 to C9 olefins. The process of the invention includes selective hydrogenation of the unrefined gasoline cut obtained from the catalytic cracking unit and separation between a light gasoline cut and a heavy gasoline cut, the light gasoline being directed to the oligomerization unit.

摘要翻译： 本发明描述了用于转化可用于生产丙烯，汽油和中间馏分的柔性的重料的方法。 该方法使用催化裂化装置和C4至C9烯烃低聚单元。 本发明的方法包括从催化裂化装置获得的未精制汽油馏分的选择氢化和轻汽油馏分与重汽油馏分之间的分离，轻汽油被引导至低聚单元。