公开(公告)号：US20130180886A1

公开(公告)日：2013-07-18

申请号：US13723616

申请日：2012-12-21

申请人： TOTAL RAFFINAGE MARKETING ,  IFP ENERGIES NOUVELLES

发明人： Laurent SIMON ,  Bertrand GUICHARD ,  Gregory LAPISARDI ,  Hugues DULOT ,  Valentina DE GRANDI ,  Delphine MINOUX ,  Jean Pierre DATH

IPC分类号： B01J31/34 ,  C10G47/20

CPC分类号： B01J31/34 ,  B01J27/188 ,  B01J27/19 ,  B01J29/064 ,  B01J29/076 ,  B01J29/166 ,  B01J29/7815 ,  B01J31/0209 ,  B01J31/04 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/42 ,  C10G47/20

摘要： The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm−1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm−1.The invention also concerns the process for preparing the catalyst and its use in hydroconversion.

摘要翻译： 本发明涉及一种含有载体的催化剂，其包括至少一种粘合剂和至少一种沸石，该沸石具有至少一个通道，其开口由含有12个氧原子的环所限定，所述催化剂包含磷，至少一个C 1 -C 4 琥珀酸二烷基酯，乙酸和氢化脱氢功能，其包含来自VIB族的至少一种元素和来自VIII族的至少一种元素，催化剂的拉曼光谱包含990和/或974cm -1处的带，其特征在于至少一个Keggin 杂多阴离子，所述琥珀酸的特征带和乙酸的特征主带在896cm -1。 本发明还涉及制备催化剂的方法及其在加氢转化中的用途。

公开(公告)号：US20130270153A1

公开(公告)日：2013-10-17

申请号：US13859789

申请日：2013-04-10

申请人： ENI S.P.A. ,  IFP ENERGIES NOUVELLES

发明人： Jean-Philippe HERAUD ,  Aline GREZAUD ,  Hugues DULOT ,  Christophe BOUCHY ,  Vincenzo CALEMMA

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  B01J21/12 ,  B01J23/462 ,  B01J23/464 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/0465 ,  C07C1/12 ,  C07C5/02 ,  C07C9/04

摘要： Production of middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds: a) catalytic hydrotreating; b) hydroisomerization/hydrocracking at least a part of liquid and gaseous effluent originating from a); c) gas/liquid separation of the stream from b) into a gaseous fraction comprising predominantly hydrogen, a hydroisomerized/hydrocracked organic liquid fraction and an aqueous fraction; d) fractionation of the organic liquid fraction in c) to obtain at least one fraction of middle distillates; and e) catalytic methanation of CO and CO2 on at least a part of said gaseous fraction in c) before hydrotreating a), and/or on at least a part of the liquid and gaseous effluent originating from a) in which the hydrogen in a) is obtained at least partly from the gaseous fraction separated in c).

摘要翻译： 由费 - 托合成生产含有氧化合物的原料生产中间馏分：a）催化加氢处理; b）加氢异构化/加氢裂化来自a）的至少一部分液体和气态流出物; c）将气流/液体从b）分离成主要包含氢气，加氢异构化/加氢裂化的有机液体馏分和水性馏分的气体馏分; d）有机液体馏分的分馏，c）得到至少一部分中间馏分; 和e）在加氢处理a）之前和/或在至少一部分源自a）的液体和气态流出物中，在c）中的至少一部分所述气态馏分中CO和CO 2的催化甲烷化，其中a） ）至少部分地由在c）中分离的气态馏分获得。

公开(公告)号：US20130105358A1

公开(公告)日：2013-05-02

申请号：US13661183

申请日：2012-10-26

申请人： ENI S.P.A ,  IFP Energies Nouvelles

发明人： Christophe BOUCHY ,  Aline GREZAUD ,  Jean Philippe HERAUD ,  Hugues DULOT ,  Vincenzo CALEMMA

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1081 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08

摘要： The present invention relates to a process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising a limited content of molecules containing at least one oxygen atom in which said feedstock is subjected to at least one hydrocracking/hydroisomerization stage in the presence of a hydrogen stream also containing a limited atomic oxygen content.

摘要翻译： 本发明涉及由费 - 托合成生产的石蜡原料生产中间馏分的方法，包括含有至少一个氧原子的有限含量的分子，其中所述原料经受至少一个加氢裂化/加氢异构化步骤 存在还含有有限原子氧含量的氢气流。

公开(公告)号：US20190119585A1

公开(公告)日：2019-04-25

申请号：US16169341

申请日：2018-10-24

申请人： IFP Energies Nouvelles

发明人： Hugues DULOT ,  Aline GREZAUD ,  Jean-Philippe HERAUD

IPC分类号： C10G65/12 ,  C10G45/38 ,  C10G45/52 ,  C10G45/54

摘要： Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis.The start-up method employs catalytic reaction of Fischer-Tropsch synthesis with a synthesis gas for producing a heavy hydrocarbon fraction and a light hydrocarbon fraction, a reduction (RE) reducing a hydrotreatment catalyst by ensuring contact with a gas comprising hydrogen, bringing the heavy hydrocarbon fraction into contact with the hydrotreatment catalyst (DM). During the step for ensuring contact, the temperature (TEMP) of the catalyst is increased to a temperature of between 260° C. and 360° C. Then, (TR) bringing a mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction into contact with the hydrotreatment catalyst is carried out.

公开(公告)号：US20130324775A1

公开(公告)日：2013-12-05

申请号：US13900658

申请日：2013-05-23

申请人： IFP Energies nouvelles

发明人： Alain QUIGNARD ,  Olivier THINON ,  Hugues DULOT ,  Raphael HUYGHE

IPC分类号： C10G3/00

CPC分类号： C10G3/50 ,  C10G3/42 ,  C10G69/10 ,  C10G2300/1011 ,  C10G2400/30 ,  Y02P30/20

摘要： A process for preparing aromatic compounds from a liquid biofuel feedstock by introducing the feedstock into a hydroreforming stage in the presence of hydrogen and a hydroreforming catalyst that contains a transition metal of a group 3 to 12 element and an activated carbon, silicon carbide, silica, transition alumina, alumina-silica, zirconium oxide, cerium oxide, titanium oxide, or an aluminate of a transition metal substrate, to obtain a liquid effluent that contains an aqueous phase and an organic phase, a stage for hydrotreatment of the organic phase, a hydrocracking stage, recycling a fraction that boils higher than 160° C. in said hydrocracking stage, a separation into a fraction containing naphtha and a fraction that boils higher than 160° C., a stage for catalytic reforming of the fraction containing naphtha to obtain hydrogen and a reformate that contains aromatic compounds and a stage for separation of the aromatic compounds of the reformate.

摘要翻译： 通过在氢气存在下将原料引入加氢成形阶段和含有3-12元素的过渡金属和活性炭，碳化硅，二氧化硅的氢气制备催化剂，从液体生物燃料原料制备芳族化合物的方法， 过渡氧化铝，氧化铝 - 二氧化硅，氧化锆，氧化铈，氧化钛或过渡金属基材的铝酸盐，以获得含有水相和有机相的液体流出物，有机相的加氢处理阶段 加氢裂化阶段，在所述加氢裂化阶段回收沸点高于160℃的馏分，分离成含有石脑油和沸点高于160℃的馏分，用于含有石脑油馏分的催化重整阶段以获得 氢和含有芳族化合物的重整产物和用于分离重整产物芳族化合物的步骤。

公开(公告)号：US20130270154A1

公开(公告)日：2013-10-17

申请号：US13860850

申请日：2013-04-11

申请人： ENI S.P.A. ,  IFP ENERGIES NOUVELLES

发明人： Aline GREZAUD ,  Jean Philippe HERAUD ,  Hugues DULOT ,  Christophe BOUCHY ,  Vincenzo CALEMMA

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/0495 ,  C07C1/12 ,  Y02P20/52 ,  C07C9/04

摘要： A method for producing middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds, including: a) a step of bringing the feedstock into contact with a hydrotreating catalyst allowing the methanation of the CO and CO2 contained in the feedstock or originating from the decomposition of the oxygenated compounds present in the feedstock, b) a step of hydroisomerization/hydrocracking of at least a part of the liquid and gaseous effluent originating from step a), in the presence of a hydroisomerization/hydrocracking catalyst, c) a step of gas/liquid separation of the effluent originating from step b) into a gaseous fraction comprising predominantly hydrogen and a hydroisomerized/hydrocracked liquid fraction, d) a step of fractionation of the liquid fraction separated in step c) to obtain at least one fraction of middle distillate, in which the hydrogen in step a) is obtained from the gaseous fraction separated in step c).

摘要翻译： 由费 - 托合成生产并含有氧化化合物的原料生产中间馏分的方法，包括：a）使原料与加氢处理催化剂接触的步骤，允许原料中所含的CO和CO 2的甲烷化或起始 来自原料中存在的含氧化合物的分解，b）在加氢异构化/加氢裂化催化剂存在下，来自步骤a）的至少一部分液体和气态流出物的加氢异构化/加氢裂化步骤，c） 将来自步骤b）的流出物气/液分离成主要包含氢气和加氢异构化/加氢裂化的液体馏分的气体馏分的步骤，d）在步骤c）中分离的液体馏分的分级步骤，以获得至少一个馏分 的中间馏分，其中步骤a）中的氢气是从步骤c）中分离的气体馏分得到的。

公开(公告)号：US20130211161A1

公开(公告)日：2013-08-15

申请号：US13767072

申请日：2013-02-14

申请人： IFP ENERGIES NOUVELLES

发明人： Frédéric FEUGNET ,  Francois HUGUES ,  Natacha TOUCHAIS ,  Hugues DULOT ,  Annick PUCCI

IPC分类号： C10G69/12

CPC分类号： C10G69/126 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

摘要： The present invention describes a process for converting a heavy feed which is flexible for the production of propylene, gasoline and middle distillate.The process uses a catalytic cracking unit and a unit for the oligomerization of C4 to C9 olefins. The process of the invention includes selective hydrogenation of the unrefined gasoline cut obtained from the catalytic cracking unit and separation between a light gasoline cut and a heavy gasoline cut, the light gasoline being directed to the oligomerization unit.

摘要翻译： 本发明描述了用于转化可用于生产丙烯，汽油和中间馏分的柔性的重料的方法。 该方法使用催化裂化装置和C4至C9烯烃低聚单元。 本发明的方法包括从催化裂化装置获得的未精制汽油馏分的选择氢化和轻汽油馏分与重汽油馏分之间的分离，轻汽油被引导至低聚单元。