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公开(公告)号:US20160304652A1
公开(公告)日:2016-10-20
申请号:US15103669
申请日:2014-04-16
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert NIESSNER , SangJun AHN , Rudy VERSTRAETEN , Gisbert MICHELS , Florian PATCAS , YoungHwa HWANG , Brian J. BANASZAK , Roland WALKER , Michel PEPERS , Johannes BARTH
IPC: C08F279/04 , C08J5/00 , C08J5/18 , C08L25/12
CPC classification number: C08F279/04 , C08F2500/17 , C08F2800/20 , C08J5/00 , C08J5/18 , C08J2325/12 , C08L25/12 , C08L55/02 , C08L67/00 , C08L69/00 , C08L69/005 , C08L77/02 , C08L77/06 , C08L2201/02 , C08L2201/10 , C08L2203/30 , C08L2205/025 , C08L2205/035 , C08L2207/04 , C08F2/22
Abstract: The invention relates to thermoplastic ABS molding compositions comprising components A) and B): A) from 5 to 80% by weight of a graft polymer A) having bimodal particle size distribution made from, based on A), a1) from 40 to 90% by weight of graft base a1), obtainable by polymerization of, based on a1), a11) from 75.5 to 89.5% by weight of at least one conjugated diene, a12) from 10.5 to 24.5% by weight of at least one vinylaromatic monomer and a2) from 10 to 60% by weight of a graft a2) made from, based on a2), a21) from 65 to 95% by weight of at least one vinylaromatic monomer, a22) from 5 to 35% by weight of acrylonitrile, and a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, B) from 20 to 95% by weight of a thermoplastic polymer B) having a viscosity number VN of from 50 to 120 ml/g, made from, based on B), b1) from 69 to 81% by weight of at least one vinylaromatic monomer, b2) from 19 to 31% by weight of acrylonitrile, and b3) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer. The invention further relates to a process for the preparation of graft copolymer A and to the graft copolymer obtainable by said process.
Abstract translation: 本发明涉及包含组分A)和B)的热塑性ABS模塑组合物:A)5-80重量%的接枝聚合物A),其具有基于A),a1)40至90的双峰粒度分布 a11),通过基于a1),a11)75.5-89.5重量%的至少一种共轭二烯的聚合获得,a12)10.5-24.5重量%的至少一种乙烯基芳族单体 和a2)10至60重量%的基于a2)制备的接枝物a2),a21)65至95重量%的至少一种乙烯基芳族单体,a22)5至35重量%的丙烯腈 ,和a23)0至30重量%的至少一种其它单烯键式不饱和单体,B)20至95重量%的粘度为VN为50至120ml / g的热塑性聚合物B),制成 基于B),b1)69至81重量%的至少一种乙烯基芳族单体,b2)19至31重量%的丙烯腈,和b3)0至30 重量%的至少一种其它单烯属不饱和单体。 本发明还涉及制备接枝共聚物A的方法和可通过所述方法获得的接枝共聚物。
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2.
公开(公告)号:US20180066117A1
公开(公告)日:2018-03-08
申请号:US15560312
申请日:2016-03-23
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Brian J. BANASZAK , Roland WALKER , Libor SEDA , Johannes BARTH , Gisbert MICHELS , Nikolaus NESTLE
CPC classification number: C08J3/24 , C08F2/26 , C08F2/38 , C08F279/04 , C08J2300/22 , C08L25/12 , C08L55/02 , G01R33/46 , C08F220/44 , C08F212/08
Abstract: A process produces a polymer composition (A) containing a styrene copolymer (a) and an impact modifier (b), comprising a copolymer (b1) as graft base and a graft (b2), where the steps of the process are: (1) providing a crosslinked copolymer (b1) made of: (b11) from 70 to 99.99% by weight of a conjugated diene or acrylate, (b12) from 0 to 29% by weight of another comonomer, (b13) from 0 to 10% by weight of crosslinking monomers, and (b14) from 0.01 to 0.7% by weight of a chain-transfer reagent; (2) applying, to the copolymer (b1), at least one graft (b2) comprising: (b21) from 65 to 95% by weight of a vinylaromatic monomer, (b22) from 5 to 35% by weight of acrylonitrile and/or methacrylonitrile, and (b23) from 0 to 30% by weight of monoethylenically unsaturated monomers, thus providing the impact modifier (b); (3) mixing the styrene copolymer (a) and the impact modifier (b), and thus leads to improved mechanical properties of the polymer composition (A).
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