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公开(公告)号：US07214744B2
公开(公告)日：2007-05-08
申请号：US11158719
申请日：2005-06-22
Applicant: Xiaoliang Gao , Isam Jaber
Inventor： Xiaoliang Gao , Isam Jaber
CPC classification number: C08F10/00 , C08F4/65912 , C08F4/6592 , C08F110/02 , C08F2420/03 , C08F4/65908
Abstract: A catalyst system comprising (i) a bulky ligand catalyst compound; and (ii) a novel borate activator is active for olefin polymerization. The novel borate contains at least one chelating (divalent) ligand and contains at least one fluorine atom. Preferred borate activators are provided as anilinium or carbonium salts. Highly preferred borate salts contain two perfluorinated alkoxy chelating ligands. The catalyst system may be used to produce polyethylene for “end use” applications such as polyethylene film and molded polyethylene goods.
Abstract translation: 一种催化剂体系，其包含（i）体积大的配体催化剂化合物; 和（ii）新的硼酸盐活化剂对于烯烃聚合是有活性的。 该新型硼酸盐含有至少一种螯合（二价）配位体，并含有至少一个氟原子。 优选的硼酸盐活化剂以苯胺或碳鎓盐的形式提供。 高度优选的硼酸盐含有两个全氟化烷氧基螯合配体。 催化剂体系可用于生产用于“最终用途”应用的聚乙烯，例如聚乙烯薄膜和模塑聚乙烯制品。
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公开(公告)号：US6130300A
公开(公告)日：2000-10-10
申请号：US239079
申请日：1999-01-27
Applicant: Isam Jaber
Inventor： Isam Jaber
IPC: C08F4/642 , C08F4/658 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/52
CPC classification number: C08F10/00 , C08F110/02 , C08F210/16
Abstract: The present invention provides a Ziegler-Natta catalyst useful in solution processes for the polymerization of olefins having a low amount of aluminum and magnesium. The catalysts of the present invention have a molar ratio of magnesium to the first aluminum component from 4.0:1 to 5.5:1 and molar ratio of magnesium to transition metal from 4.0:1 to 5.5:1.
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公开(公告)号：US6084042A
公开(公告)日：2000-07-04
申请号：US106164
申请日：1998-06-29
Applicant: Isam Jaber , Stephen John Brown
Inventor： Isam Jaber , Stephen John Brown
IPC: B01J23/16 , C08F4/685 , C08F10/00 , C08F10/02 , C08F110/06 , C08F210/16 , C08F4/654 , C08F4/68
CPC classification number: C08F10/00 , C08F10/02 , C08F110/06 , C08F210/16
Abstract: The present invention provides a Ziegler-Natta catalyst based on titanium and vanadium useful in solution processes for the polymerization of olefins having a low amount of aluminum and magnesium. The catalysts of the present invention have a molar ratio of magnesium to the first aluminum component from 4.0:1 to 8.0:1 and molar ratio of magnesium to titanium and vanadium from 4.0:1 to 8.0:1. The invention provides a novel catalyst preparation method to substantially increase the polymer molecular weight in the high temperature ethylene polymerization process.
Abstract translation: 本发明提供一种基于钛和钒的齐格勒 - 纳塔催化剂，其用于具有低量铝和镁的烯烃聚合的溶液方法中。 本发明的催化剂的镁与第一铝组分的摩尔比为4.0:1至8.0:1，镁与钛和钒的摩尔比为4.0:1至8.0:1。 本发明提供了一种在高温乙烯聚合方法中大幅度提高聚合物分子量的新型催化剂制备方法。
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公开(公告)号：US20060223960A1
公开(公告)日：2006-10-05
申请号：US11364248
申请日：2006-02-28
Applicant: Isam Jaber , John Swabey , Xiaoliang Gao , Charles Carter , Cliff Baar
Inventor： Isam Jaber , John Swabey , Xiaoliang Gao , Charles Carter , Cliff Baar
IPC: C08F4/44
CPC classification number: C08F10/00 , C08F4/6592 , C08F110/02 , C08F210/16 , C08F4/65912 , C08F4/6028 , C08F2500/12 , C08F210/14
Abstract: A cocatalyst system for olefin polymerization comprises an aluminoxane (especially methylaluminoxane, or “MAO”), an aluminum alkyl and a halogenated phenol. The preferred halogenated phenol is pentafluorophenol. The use of pentafluorophenol permits the substitution of a portion of the MAO cocatalyst (which is expensive) with inexpensive aluminum alkyl. The cocatalyst is most preferably employed in combination with an organometallic catalyst having at lease one pi ligand.
Abstract translation: 用于烯烃聚合的助催化剂体系包括铝氧烷（特别是甲基铝氧烷或“MAO”），烷基铝和卤代苯酚。 优选的卤代苯酚是五氟苯酚。 五氟苯酚的使用允许用廉价的烷基铝代替一部分MAO助催化剂（这是昂贵的）。 助催化剂最优选与具有至少一个π配体的有机金属催化剂组合使用。
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公开(公告)号：US20060009596A1
公开(公告)日：2006-01-12
申请号：US11158719
申请日：2005-06-22
Applicant: Xiaoliang Gao , Isam Jaber
Inventor： Xiaoliang Gao , Isam Jaber
IPC: C08F4/44
CPC classification number: C08F10/00 , C08F4/65912 , C08F4/6592 , C08F110/02 , C08F2420/03 , C08F4/65908
Abstract: A catalyst system comprising (i) a bulky ligand catalyst compound; and (ii) a novel borate activator is active for olefin polymerization. The novel borate contains at least one chelating (divalent) ligand and contains at least one fluorine atom. Preferred borate activators are provided as anilinium or carbonium salts. Highly preferred borate salts contain two perfluorinated alkoxy chelating ligands. The catalyst system may be used to produce polyethylene for “end use” applications such as polyethylene film and molded polyethylene goods.
Abstract translation: 一种催化剂体系，其包含（i）体积大的配体催化剂化合物; 和（ii）新的硼酸盐活化剂对于烯烃聚合是有活性的。 该新型硼酸盐含有至少一种螯合（二价）配位体，并含有至少一个氟原子。 优选的硼酸盐活化剂以苯胺或碳鎓盐的形式提供。 高度优选的硼酸盐含有两个全氟化烷氧基螯合配体。 催化剂体系可用于生产用于“最终用途”应用的聚乙烯，例如聚乙烯薄膜和模塑聚乙烯制品。
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Patent Agency Ranking
公开(公告)号：US06878658B2
公开(公告)日：2005-04-12
申请号：US10314796
申请日：2002-12-09
Applicant: Isam Jaber
Inventor： Isam Jaber
IPC: C08F4/646 , B01J31/12 , C08F2/06 , C08F4/64 , C08F4/649 , C08F4/656 , C08F10/00 , C08F210/02 , C08F210/16 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC classification number: C08F10/00 , C08F210/16 , C08F4/6567 , C08F4/6576 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F210/14
Abstract: The present invention provides a Ziegler-Natta catalyst useful in solution processes for the polymerization of olefins having a low amount of aluminum and magnesium. The catalysts of the present invention contain an alkyl silanol and have a molar ratio of Si:Ti from 0.25:1 to 4:1. The catalysts are effective for the solution polymerization of olefins at high temperatures.
Abstract translation: 本发明提供了一种齐格勒 - 纳塔催化剂，其用于具有低量铝和镁的烯烃聚合的溶液方法中。 本发明的催化剂含有烷基硅烷醇并且Si:Ti的摩尔比为0.25:1至4:1。 该催化剂对于在高温下烯烃的溶液聚合是有效的。
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公开(公告)号：US06277931B1
公开(公告)日：2001-08-21
申请号：US09386098
申请日：1999-08-30
Applicant: Isam Jaber , Stephen John Brown
Inventor： Isam Jaber , Stephen John Brown
IPC: C08F201
CPC classification number: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/05 , C08F4/685 , C08F4/65904 , C08F2/06 , C08F2/001 , C08F2500/12 , C08F2500/03 , C08F210/14 , C08F2500/04
Abstract: A dual reactor process for the solution and (co)polymerization of ethylene uses two different types of catalysts in the two reactors. A catalyst having a phosphinimine ligand is used in the first reactor. A Ziegler Natta catalyst is used in the second reactor. The process of this invention is comparatively easy to control and may be used to produce polyethylene products having a broad molecular weight distribution. Linear low density produced according to this invention is well suited for the manufacture of molded goods and plastic films.
Abstract translation: 用于乙烯溶液和（共）聚合的双反应器方法在两个反应器中使用两种不同类型的催化剂。 在第一反应器中使用具有膦亚胺配体的催化剂。 在第二反应器中使用齐格勒纳塔催化剂。 本发明的方法比较容易控制，并可用于生产具有宽分子量分布的聚乙烯产品。 根据本发明生产的线性低密度非常适合于制造模制品和塑料薄膜。
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公开(公告)号：US20120271087A1
公开(公告)日：2012-10-25
申请号：US13431442
申请日：2012-03-27
Applicant: Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber , Ian Ronald Jobe , Oleksiy Golovchenko
Inventor： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber , Ian Ronald Jobe , Oleksiy Golovchenko
IPC: C07C2/30
CPC classification number: C07C2/36 , C07C2531/12 , C07C2531/24 , C07C11/107
Abstract: The oligomerization of ethylene using a chromium catalyst and an aluminoxane activator is well known. The undesired formation of polyethylene as a by-product is also known to occur during prior oligomerization processes. We have discovered that the use of an aluminoxane that is prepared by non-hydrolytic means provides a highly productive activator (co-catalyst) for ethylene oligomerization and mitigates the undesired formation of by-product polyethylene.
Abstract translation: 使用铬催化剂和铝氧烷活化剂的乙烯的低聚是公知的。 作为副产物的聚乙烯的不期望的形成也已知在先前的低聚反应过程中发生。 我们已经发现，使用由非水解方法制备的铝氧烷提供了用于乙烯低聚的高效活性剂（助催化剂），并减轻了副产物聚乙烯的不期望的形成。
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公开(公告)号：US20120142989A1
公开(公告)日：2012-06-07
申请号：US13293889
申请日：2011-11-10
Applicant: Isam Jaber , Ian Ronald Jobe , P. Scott Chisholm , Andrzej Krzywicki , Charles Ashton Garret Carter , Vernon Lindsay Strom , Kamal l Elias Serhal , Eric Clavelle , Stephen John Brown , Yves Lacombe , Anita Sylvia Magis , Mackenzie Alexander Harris , Russell Kirk Archer , Keith Wayne Besenski , Michel Berghmans , Oleksiy Golovchenko , Dale Alexander Sieben
Inventor： Isam Jaber , Ian Ronald Jobe , P. Scott Chisholm , Andrzej Krzywicki , Charles Ashton Garret Carter , Vernon Lindsay Strom , Kamal l Elias Serhal , Eric Clavelle , Stephen John Brown , Yves Lacombe , Anita Sylvia Magis , Mackenzie Alexander Harris , Russell Kirk Archer , Keith Wayne Besenski , Michel Berghmans , Oleksiy Golovchenko , Dale Alexander Sieben
IPC: C07C2/02
CPC classification number: C07C2/36 , C07C2523/26 , C07C2531/14 , C07C2531/24 , Y02P20/52 , C07C11/107 , C07C11/02
Abstract: The oligomerization of ethylene using a chromium catalyst having a heteroatomic ligand may be used to provide oligomerization products that are selective towards hexene and/or octene. However, such processes also typically produce some polymer as an undesirable by product. The present invention is directed towards improvements in the selective oligomerization of ethylene.
Abstract translation: 可以使用具有杂原子配位体的铬催化剂使乙烯低聚来提供对己烯和/或辛烯有选择性的低聚产物。 然而，这些方法也通常产生一些聚合物作为不期望的产物。 本发明涉及改进乙烯的选择性低聚。
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公开(公告)号：US20120101321A1
公开(公告)日：2012-04-26
申请号：US13200287
申请日：2011-09-22
Applicant: Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber
Inventor： Stephen John Brown , Charles Ashton Garret Carter , P. Scott Chisholm , Isam Jaber
IPC: C07C2/36
CPC classification number: C07C2/36 , B01J31/143 , B01J31/24 , B01J2231/20 , B01J2531/0238 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07C11/02
Abstract: The oligomerization of ethylene using a chromium catalyst having a bridged diphosphine ligand can produce a selective product distribution (to predominantly hexene or predominantly octene/hexene) when activated with an aluminoxane. The oligomerization reaction also produces polymer by product—particularly when the aluminoxane is provided in a non-aromatic solvent. The present invention mitigates this problem.
Abstract translation: 当用铝氧烷活化时，使用具有桥连二膦配体的铬催化剂的乙烯的低聚可以产生选择性产物分布（主要是己烯或主要是辛烯/己烯）。 低聚反应还通过产物产生聚合物，特别是当在非芳族溶剂中提供铝氧烷时。 本发明减轻了这个问题。
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