公开(公告)号：US06864006B2

公开(公告)日：2005-03-08

申请号：US10038875

申请日：2002-01-08

申请人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

发明人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

IPC分类号： B01D69/14 ,  B01D71/70 ,  C08G77/04 ,  C08J5/22 ,  H01B1/06 ,  H01B13/00 ,  H01M8/02 ,  H01M8/10

CPC分类号： C08J5/2256 ,  B01D69/141 ,  B01D71/70 ,  C08J2383/10 ,  H01M8/1023 ,  H01M8/1037 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1074 ,  Y02P70/56

摘要： A proton-conducting membrane, excellent in resistance to heat, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature and a method for producing the same. A proton-conducting membrane includes a carbon-containing compound and inorganic acid, characterized by a phase-separated structure containing a carbon-containing phase containing at least 80% by volume of the carbon-containing compound and inorganic phase containing at least 80% by volume of the inorganic acid, the inorganic phase forming the continuous ion-conducting paths. The method for producing the above proton-conducting membrane includes steps of preparing a mixture of a carbon-containing compound (D) having one or more hydrolyzable silyl groups and inorganic acid (C), forming the above mixture into a film, and hydrolyzing/condensing the hydrolyzable silyl group contained in the mixture formed into the film, to form a three-dimensionally crosslinked silicon-oxygen structure (A). The above proton-conducting membrane is incorporated in a fuel cell.

摘要翻译： 具有优异耐热性，耐久性，尺寸稳定性和燃料阻隔特性以及高温下优异的质子传导性的质子传导膜及其制造方法。 质子传导膜包括含碳化合物和无机酸，其特征在于相分离结构，其含有含碳相含有至少80体积％的含碳化合物和无机相的无机相含有至少80％ 无机酸的体积，形成连续离子传导路径的无机相。 制造上述质子传导膜的方法包括以下步骤：制备具有一个或多个可水解甲硅烷基的含碳化合物（D）和无机酸（C）的混合物，将上述混合物形成膜，并水解/ 将形成的混合物中所含的可水解甲硅烷基缩合成膜，形成三维交联的硅 - 氧结构（A）。 上述质子传导膜并入燃料电池中。

公开(公告)号：US06680138B1

公开(公告)日：2004-01-20

申请号：US09662909

申请日：2000-09-15

申请人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

发明人： Itaru Honma ,  Shigeki Nomura ,  Toshiya Sugimoto ,  Osamu Nishikawa

IPC分类号： H01M986

CPC分类号： C08J5/2256 ,  C08J2371/12 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1037 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1051 ,  H01M8/1074 ,  Y02P70/56

摘要： It is an object of the present invention to provide a proton-conducting membrane excellent in resistance to heat and durability and showing excellent proton conductivity at high temperature. It is another object of the present invention to provide a method for producing the same and fuel cell using the same. The present invention provides a proton-conducting membrane, comprising an organic material (A), three-dimensionally crosslinked structure (B) containing a specific metal-oxygen bond, agent (C) for imparting proton conductivity, and water (D), wherein the organic material (A) has a number-average molecular weight of 56 to 30,000, and at least 4 carbon atoms connected in series in the main chain, and the organic material (A) and three-dimensionally crosslinked structure (B) are bound to each other via a covalent bond.

摘要翻译： 本发明的目的是提供耐热性和耐久性优异的质子传导膜，并且在高温下显示优异的质子传导性。 本发明的另一个目的是提供一种其制造方法和使用该方法的燃料电池。本发明提供一种质子传导膜，其包含有机材料（A），三维交联结构（B），其含有 特定的金属 - 氧键，用于赋予质子传导性的试剂（C）和水（D），其中有机材料（A）的数均分子量为56〜30,000，至少4个碳原子串联连接 在主链中，有机材料（A）和三维交联结构（B）通过共价键彼此结合。

公开(公告)号：US06228248B1

公开(公告)日：2001-05-08

申请号：US09291549

申请日：1999-04-14

申请人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

发明人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

IPC分类号： C25D100

CPC分类号： C01B33/12 ,  Y10T428/31598

摘要： A process directed to preparing surfactant-polycrystalline inorganic nanostructured materials having designed microscopic patterns. The process includes forming a polycrystalline inorganic substrate having a flat surface and placing in contact with the flat surface of the substrate a surface having a predetermined microscopic pattern. An acidified aqueous reacting solution is then placed in contact with an edge of the surface having the predetermined microscopic pattern. The solution wicks into the microscopic pattern by capillary action. The reacting solution has an effective amount of a silica source and an effective amount of a surfactant to produce a mesoscopic silica film upon contact of the reacting solution with the flat surface of the polycrystalline inorganic substrate and absorption of the surfactant into the surface. Subsequently an electric field is applied tangentially directed to the surface within the microscopic pattern. The electric field is sufficient to cause electro-osmotic fluid motion and enhanced rates of fossilization by localized Joule heating.

公开(公告)号：US07625673B2

公开(公告)日：2009-12-01

申请号：US10129362

申请日：2001-09-06

申请人： Tetsuichi Kudo ,  Masaru Miyayama ,  Keiji Sakai ,  Yasuo Takeda ,  Itaru Honma ,  Hiroshi Abe

发明人： Tetsuichi Kudo ,  Masaru Miyayama ,  Keiji Sakai ,  Yasuo Takeda ,  Itaru Honma ,  Hiroshi Abe

IPC分类号： H01M4/62

CPC分类号： H01G9/155 ,  H01M4/02 ,  H01M4/366 ,  H01M4/48 ,  H01M4/485 ,  H01M4/624 ,  H01M4/625 ,  H01M10/052 ,  H01M2300/0014 ,  H01M2300/0025 ,  Y02E60/13

摘要： An electrode material for an electrochemical device comprising a composite of a particulate conductive material and a metal oxide is prepared by mixing and dispersing the particulate conductive material with a colloidal solution of an oxide of an element in a range of from Group 3 to Group 12 in the fourth, fifth and sixth periods of the Periodic Table and heating the mixture. This composite has a high capacity even at a high current density and good filling properties, and is useful as an electrode material for an electrochemical device such as a lithium secondary battery or an electrochemical capacitor. When the electrode material comprising this composite is used, an electrode can be produced without any binder, and the electrochemical device having good output characteristics can be constructed.

公开(公告)号：US09583750B2

公开(公告)日：2017-02-28

申请号：US14349444

申请日：2012-06-11

申请人： Yuki Hanyu ,  Itaru Honma

发明人： Yuki Hanyu ,  Itaru Honma

IPC分类号： H01M2/14 ,  H01M2/18 ,  H01M6/18 ,  H01M10/0562 ,  H01M2/16 ,  H01M10/052 ,  H01M4/136 ,  H01M4/58 ,  H01M4/60 ,  H01M4/62 ,  H01M10/056 ,  H01M4/02

CPC分类号： H01M2/16 ,  H01M2/1653 ,  H01M4/136 ,  H01M4/5815 ,  H01M4/602 ,  H01M4/622 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0562 ,  H01M2004/023 ,  H01M2220/30 ,  H01M2300/0045 ,  H01M2300/0065 ,  Y02E60/122 ,  Y02P70/54

摘要： A secondary battery charged and discharged even after dissolution. The active material in the cathode body and/or the anode body is a liquid, or the active material undergoes phase transition into a liquid is provided. The secondary battery (1) includes: a cathode collector (2), a cathode body (3), a solid electrolyte (4), an anode body (5), and an anode collector (6). The cathode body and the anode body are sealed by the solid electrolyte, the cathode collector, and/or the anode collector. The cathode body and the anode body preferably contain an active material that undergoes phase transition from a solid to a liquid, or to a phase containing a liquid, due to charge and discharge. The cathode body or the anode body preferably contains a liquid active material. A polymeric layer may be inserted between the cathode body and/or the anode body and the solid electrolyte.

摘要翻译： 二次电池即使溶解后也进行充放电。 阴极体和/或阳极体中的活性物质是液体，或提供活性物质进入液体的相变。 二次电池（1）包括：阴极集电体（2），阴极体（3），固体电解质（4），阳极体（5）和阳极集电体（6）。 阴极体和阳极体由固体电解质，阴极集电体和/或阳极集电体密封。 阴极体和阳极体优选含有由于充放电而从固体到液体或包含液体的相的相变的活性物质。 阴极体或阳极体优选含有液体活性物质。 聚合物层可以插入在阴极体和/或阳极体和固体电解质之间。

公开(公告)号：US20140377621A1

公开(公告)日：2014-12-25

申请号：US14349444

申请日：2012-06-11

申请人： Yuki Hanyu ,  Itaru Honma

发明人： Yuki Hanyu ,  Itaru Honma

IPC分类号： H01M2/16 ,  H01M10/056 ,  H01M10/052

CPC分类号： H01M2/16 ,  H01M2/1653 ,  H01M4/136 ,  H01M4/5815 ,  H01M4/602 ,  H01M4/622 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0562 ,  H01M2004/023 ,  H01M2220/30 ,  H01M2300/0045 ,  H01M2300/0065 ,  Y02E60/122 ,  Y02P70/54

摘要： A secondary battery charged and discharged even after dissolution. The active material in the cathode body and/or the anode body is a liquid, or the active material undergoes phase transition into a liquid is provided. The secondary battery (1) includes: a cathode collector (2), a cathode body (3), a solid electrolyte (4), an anode body (5), and an anode collector (6). The cathode body and the anode body are sealed by the solid electrolyte, the cathode collector, and/or the anode collector. The cathode body and the anode body preferably contain an active material that undergoes phase transition from a solid to a liquid, or to a phase containing a liquid, due to charge and discharge. The cathode body or the anode body preferably contains a liquid active material. A polymeric layer may be inserted between the cathode body and/or the anode body and the solid electrolyte.

摘要翻译： 二次电池即使溶解后也进行充放电。 阴极体和/或阳极体中的活性物质是液体，或提供活性物质进入液体的相变。 二次电池（1）包括：阴极集电体（2），阴极体（3），固体电解质（4），阳极体（5）和阳极集电体（6）。 阴极体和阳极体由固体电解质，阴极集电体和/或阳极集电体密封。 阴极体和阳极体优选含有由于充放电而从固体到液体或包含液体的相的相变的活性物质。 阴极体或阳极体优选含有液体活性物质。 聚合物层可以插入在阴极体和/或阳极体和固体电解质之间。

公开(公告)号：US07179356B2

公开(公告)日：2007-02-20

申请号：US10411641

申请日：2003-04-11

申请人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

发明人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

IPC分类号： B01D57/02

CPC分类号： C01B33/12 ,  Y10T428/31598

摘要： A process directed to preparing surfactant-polycrystalline inorganic nanostructured materials having designed microscopic patterns. The process includes forming a polycrystalline inorganic substrate having a flat surface and placing in contact with the flat surface of the substrate a surface having a predetermined microscopic pattern. An acidified aqueous reacting solution is then placed in contact with an edge of the surface having the predetermined microscopic pattern. The solution wicks into the microscopic pattern by capillary action. The reacting solution has an effective amount of a silica source and an effective amount of a surfactant to produce a mesoscopic silica film upon contact of the reacting solution with the flat surface of the polycrystalline inorganic substrate and absorption of the surfactant into the surface. Subsequently an electric field is applied tangentially directed to the surface within the microscopic pattern. The electric field is sufficient to cause electro-osmotic fluid motion and enhanced rates of fossilization by localized Joule heating.

摘要翻译： 一种制备具有设计微观图案的表面活性剂 - 多晶无机纳米结构材料的方法。 该方法包括形成具有平坦表面的多晶无机基材，并且与基材的平坦表面接触具有预定微观图案的表面。 然后将酸化的水性反应溶液与具有预定微观图案的表面的边缘接触。 溶液通过毛细管作用吸入微观图案。 当反应溶液与多晶无机基材的平坦表面接触并吸收表面活性剂时，反应溶液具有有效量的二氧化硅源和有效量的表面活性剂以产生介观二氧化硅膜。 随后在微观图案中切向地指向表面的电场。 电场足以引起电渗流体运动，并通过局部焦耳加热提高僵化率。

公开(公告)号：US06547940B2

公开(公告)日：2003-04-15

申请号：US09850364

申请日：2001-05-07

申请人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

发明人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

IPC分类号： B01D5702

CPC分类号： C01B33/12 ,  Y10T428/31598

摘要： A process directed to preparing surfactant-polycrystalline inorganic nanostructured materials having designed microscopic patterns. The process includes forming a polycrystalline inorganic substrate having a flat surface and placing in contact with the flat surface of the substrate a surface having a predetermined microscopic pattern. An acidified aqueous reacting solution is then placed in contact with an edge of the surface having the predetermined microscopic pattern. The solution wicks into the microscopic pattern by capillary action. The reacting solution has an effective amount of a silica source and an effective amount of a surfactant to produce a mesoscopic silica film upon contact of the reacting solution with the flat surface of the polycrystalline inorganic substrate and absorption of the surfactant into the surface. Subsequently an electric field is applied tangentially directed to the surface within the microscopic pattern. The electric field is sufficient to cause electro-osmotic fluid motion and enhanced rates of fossilization by localized Joule heating.

摘要翻译： 一种制备具有设计微观图案的表面活性剂 - 多晶无机纳米结构材料的方法。 该方法包括形成具有平坦表面的多晶无机基材，并且与基材的平坦表面接触具有预定微观图案的表面。 然后将酸化的水性反应溶液与具有预定微观图案的表面的边缘接触。 溶液通过毛细管作用吸入微观图案。 当反应溶液与多晶无机基材的平坦表面接触并吸收表面活性剂时，反应溶液具有有效量的二氧化硅源和有效量的表面活性剂以产生介观二氧化硅膜。 随后在微观图案中切向地指向表面的电场。 电场足以引起电渗流体运动，并通过局部焦耳加热提高僵化率。

公开(公告)号：US06255241B1

公开(公告)日：2001-07-03

申请号：US09405595

申请日：1999-09-27

申请人： Kun-ichi Miyazawa ,  Itaru Honma ,  Junya Yano ,  Kunio Ito ,  Toru Kuzumaki

发明人： Kun-ichi Miyazawa ,  Itaru Honma ,  Junya Yano ,  Kunio Ito ,  Toru Kuzumaki

IPC分类号： C04B3552

CPC分类号： B82Y30/00 ,  C01G25/00 ,  C04B35/488 ,  Y10S977/842

摘要： A fullerene-dispersed ceramic is produced by an improved method in which C60 or like fullerene, and C16TMA or like surfactant, are dissolved in a solution of metallic compound, such as zirconyl nitrate, to form a colloidal solution. A gel is formed from the colloidal solution by changing its hydrogen ion concentration. The gel is dried and subjected to heat treatment, to eliminate remaining solvent and surfactant, and thereby stably obtain the desired fullerene-dispersed ceramic powder in which the fullerene is uniformly dispersed and which is essentially free from carbon other than fullerene.

摘要翻译： 富勒烯分散陶瓷通过将C60或类似富勒烯和C16TMA等表面活性剂溶解在金属化合物如硝酸氧锆的溶液中以形成胶体溶液的改进方法制备。 通过改变其氢离子浓度，由胶体溶液形成凝胶。 将凝胶干燥并进行热处理，以除去剩余的溶剂和表面活性剂，从而稳定地获得所需的富勒烯分散陶瓷粉末，其中富勒烯均匀分散且基本上不含富勒烯以外的碳。

公开(公告)号：US6004444A

公开(公告)日：1999-12-21

申请号：US964876

申请日：1997-11-05

申请人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

发明人： Ilhan A. Aksay ,  Mathias Trau ,  Srinivas Manne ,  Itaru Honma ,  George Whitesides

IPC分类号： C01B33/12 ,  B01D57/02

CPC分类号： B82Y30/00 ,  C01B33/12 ,  Y10T428/31598

摘要： A process directed to preparing surfactant-polycrystalline inorganic nanostructured materials having designed microscopic patterns. The process includes forming a polycrystalline inorganic substrate having a flat surface and placing in contact with the flat surface of the substrate a surface having a predetermined microscopic pattern. An acidified aqueous reacting solution is then placed in contact with an edge of the surface having the predetermined microscopic pattern. The solution wicks into the microscopic pattern by capillary action. The reacting solution has an effective amount of a silica source and an effective amount of a surfactant to produce a mesoscopic silica film upon contact of the reacting solution with the flat surface of the polycrystalline inorganic substrate and absorption of the surfactant into the surface. Subsequently an electric field is applied tangentially directed to the surface within the microscopic pattern. The electric field is sufficient to cause electro-osmotic fluid motion and enhanced rates of fossilization by localized Joule heating.