-
公开(公告)号：US20220241754A1
公开(公告)日：2022-08-04
申请号：US17597101
申请日：2020-07-01
Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
Inventor： Masaaki KITANO , Hideo HOSONO , Toshiharu YOKOYAMA , Kayato OOYA , Kiya OGASAWARA , Ryu TAKASHIMA
Abstract: The invention provides a method of producing a metal oxyhydride, capable of synthesizing the metal oxyhydride under reaction conditions close to atmospheric pressure, and excellent in productivity and cost. The method of producing a metal oxyhydride of the present invention includes reacting an oxide with a metal hydride in a hydrogen atmosphere. A non-oxygen element constituting the oxide comprises only one kind of non-oxygen element. A pressure condition of the reaction is 0.1 to 0.9 MPa, and a temperature of the reaction is 500 to 1000° C.
-
2.发明申请公开(公告)号：US20180257061A1
公开(公告)日：2018-09-13
申请号：US15760072
申请日：2016-09-15
Inventor： Hideo HOSONO , Toshiharu YOKOYAMA , Masaaki KITANO , Hiroshi MIZOGUCHI , Takaya OGAWA
CPC classification number: B01J23/63 , B01J35/023 , B01J37/0081 , C01C1/0411 , C22C5/04 , Y02P20/52
Abstract: The invention provides a Laves phase intermetallic compound having a composition represented by general formula ARu2 (A is Y, Sc, or at least one element selected from lanthanoid elements excluding Ce), the crystallite size thereof being 1 nm to 100 nm; a catalyst including the intermetallic compound as an active ingredient; and a method for producing ammonia using the same.
-
公开(公告)号：US20210025063A1
公开(公告)日：2021-01-28
申请号：US17040853
申请日：2019-03-28
Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
Inventor： Hideo HOSONO , Toshiharu YOKOYAMA , Yoshitake TODA , Shintaro ISHIYAMA , Masami TAGUCHI , Hiroki TAKAHASHI
Abstract: An electrolytic cell capable of simply electrolyzing carbon dioxide into carbon monoxide and oxygen with low activation energy, and an electrolytic device. The carbon dioxide electrolytic cell includes a cathode, an anode, and a solid electrolyte having oxide ion conductivity. The cathode is the following (A) or (B); (A) a metal and a first mayenite-type compound are included therein or (B) a metal and a second mayenite-type compound are included therein, said second mayenite type compound including a mayenite type compound having electron conductivity.
-
4.发明申请公开(公告)号：US20180304237A1
公开(公告)日：2018-10-25
申请号：US16065381
申请日：2016-12-22
Inventor： Hideo HOSONO , Masaaki KITANO , Tomofumi TADA , Toshiharu YOKOYAMA , Yoshitake TODA , Yangfan LU , Jiang LI
CPC classification number: B01J23/462 , B01J23/10 , B01J23/14 , B01J23/624 , B01J23/63 , B01J35/0006 , B01J35/002 , B01J35/0073 , B01J35/1009 , B01J37/0207 , B01J37/0209 , B01J37/0225 , B01J37/086 , C01C1/04 , C01C1/0411 , Y02P20/52
Abstract: An electride, which is more stable and can be more easily obtained, is provided or is made available, and as a result, a catalyst particularly useful for chemical synthesis, in which the electride is particularly used, is provided.A transition metal-supported intermetallic compound having a transition metal supported on an intermetallic compound represented by the following formula (1): A5X3 (1) wherein A represents a rare earth element, and X represents Si or Ge.
-
5.发明申请公开(公告)号：US20170355607A1
公开(公告)日：2017-12-14
申请号：US15532877
申请日：2015-12-04
Inventor： Hideo HOSONO , Michikazu HARA , Masaaki KITANO , Toshiharu YOKOYAMA , Yasunori INOUE
CPC classification number: C01C1/0411 , B01J21/18 , B01J23/462 , B01J23/58 , B01J23/63 , B01J23/648 , B01J27/24 , B01J35/0046 , B01J35/006 , B01J35/0066 , B01J35/1014 , B01J35/1019 , B01J37/0072 , B01J37/0205 , B01J37/0209 , B01J37/04 , B01J37/08 , B01J37/082 , B01J37/086 , C01B3/047 , C01B21/0923 , C01B21/0926 , C01P2004/04 , Y02E60/364 , Y02P20/52
Abstract: An ammonia synthesis catalyst having high activity is obtained by having a two-dimensional electride compound having a lamellar crystal structure such as Ca2N support a transition metal. However, since the two-dimensional electride compound is unstable, the stability of the catalyst is low. In addition, in cases where a two-dimensional electride compound is used as a catalyst support, it is difficult to shape the catalyst depending on reactions since the two-dimensional electride compound has poor processability. A composite which includes a transition metal, a support and a metal amide compound, wherein the support is a metal oxide or a carbonaceous support; and the metal amide compound is a metal amide compound represented by general formula (1). M(NH2)x . . . (1) (In general formula (1), M represents at least one metal atom selected from the group consisting of Li, Na, K, Be, Mg, Ca, Sr, Ba and Eu; and x represents the valence of M.)
-
Patent Agency Ranking
6.发明申请公开(公告)号：US20160361712A1
公开(公告)日：2016-12-15
申请号：US15121702
申请日：2015-02-12
Inventor： Hideo HOSONO , Michikazu HARA , Masaaki KITANO , Toshiharu YOKOYAMA , Yasunori INOUE , Shinji KAMBARA
CPC classification number: B01J27/24 , B01J23/462 , B01J23/745 , B01J23/75 , B01J27/22 , B01J35/0006 , B01J35/1009 , C01B21/0612 , C01C1/0411 , C01P2006/12 , Y02P20/52
Abstract: A catalyst is provided which is used for continuously synthesizing ammonia using a gas containing hydrogen and nitrogen as a raw material, wherein a transition metal which exhibits catalytic activity is supported by a support, and the support is a two-dimensional electride or a precursor thereof. The two-dimensional electride or the precursor thereof is a metal nitride represented by MxNyHz (M represents one or two or more of Group II metals selected from the group consisting of Mg, Ca, Sr and Ba, and x, y and z are in ranges of 1≦x≦11, 1≦y≦8, and 0≦z≦4 respectively, in which x is an integer, and y and z are not limited to an integer) or M3N2 (M is the same as above), or a metal carbide selected from the group consisting of Y2C, Sc2C, Gd2C, Tb2C, Dy2C, Ho2C and Er2C. These catalysts are used for continuously reacting nitrogen with hydrogen, which are raw materials, on the catalyst, wherein the reaction is performed in an ammonia synthesis reaction system under the preferable conditions of a reaction temperature which is equal to or higher than 100° C. and equal to or lower than 600° C., and a reaction pressure which is equal to or higher than 10 kPa and lower than 20 MPa.
Abstract translation: 提供了一种催化剂，其用于使用含有氢气和氮气的气体作为原料连续合成氨，其中具有催化活性的过渡金属由载体负载，并且载体是二维电子或其前体 。 二维电子电极或其前体是以M x N y H z表示的金属氮化物（M表示选自Mg，Ca，Sr和Ba的第II族金属中的一种或两种以上，x，y和z在 分别为1≤x≤11,1≤y≤8,0≤z≤4的范围，其中x为整数，y和z不限于整数）或M3N2（M与上述相同） 或选自Y2C，Sc2C，Gd2C，Tb2C，Dy2C，Ho2C和Er2C的金属碳化物。 这些催化剂用于使氮气与作为原料的氢气在催化剂上连续反应，其中反应在反应温度等于或高于100℃的优选条件下在氨合成反应体系中进行。 等于或低于600℃，反应压力等于或高于10kPa并低于20MPa。
-
7.发明申请公开(公告)号：US20180327272A1
公开(公告)日：2018-11-15
申请号：US15774195
申请日：2016-11-09
Inventor： Hideo HOSONO , Michikazu HARA , Masaaki KITANO , Hiroshi MIZOGUCHI , Toshiharu YOKOYAMA , Kyosuke YAMAGATA
CPC classification number: C01C1/0411 , B01J23/462 , B01J23/58 , B01J23/63 , B01J23/78 , B01J23/83 , B01J35/002 , B01J35/1009 , B01J37/04 , B01J37/08 , B01J37/18 , C01C1/04 , C01G55/008 , C01P2002/70 , Y02P20/52
Abstract: The present invention provides a supported metal catalyst, a method for synthesizing ammonia using said catalyst, and a supported metal material in which a transition metal is supported on a support, wherein the support is a metal hydride represented by general formula (1): XHn . . . (1); and in general formula (1), X represents at least one selected from the group consisting of atoms from Groups 2 and 3, and lanthanoid atoms, and n is in a range of 2
-
8.发明公开公开(公告)号：US20230241593A1
公开(公告)日：2023-08-03
申请号：US17801816
申请日：2021-02-16
Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
Inventor： Masaaki KITANO , Hideo HOSONO , Toshiharu YOKOYAMA , Jun KUJIRAI , Kiya OGASAWARA
IPC: B01J27/24 , B01J23/46 , B01J23/75 , B01J23/745 , B01J23/755 , B01J35/00 , B01J37/08 , C01C1/04
CPC classification number: B01J27/24 , B01J23/462 , B01J23/75 , B01J23/745 , B01J23/755 , B01J35/0066 , B01J37/08 , C01C1/0411
Abstract: The present invention is related to an oxynitride-hydride which is capable of achieving both stabilization and improvement of catalyst performance when used as a support, and the oxynitride-hydride can be easily synthesized. The oxynitride-hydride is represented by the following general formula (1),
AnBmOl-xNyHz (1)
wherein in the general formula (1), x represents a number represented by 0.1≤x≤3.5; y represents a number represented by 0.1≤y≤2.0; and z represents a number represented by 0.1≤z≤2.0.-
公开(公告)号：US20230083938A1
公开(公告)日：2023-03-16
申请号：US17799079
申请日：2021-02-15
Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
Inventor： Masaaki KITANO , Hideo HOSONO , Toshiharu YOKOYAMA , Kiya OGASAWARA , Yo AGAWA
Abstract: The invention is related to a layered double hydroxide electride which can be produced without high-temperature treatment, and a production method of which cost can be reduced. The layered double hydroxide electride contains electrons between layers and has an electron density of 2.0×1018 cm−3 or more. The method of producing the layered double hydroxide electride includes a step of mixing a starting layered double hydroxide with an electron exchanger for exchanging anions existing between layers of the starting layered double hydroxide for electrons to produce the layered double hydroxide electride.
-
10.发明申请公开(公告)号：US20200164348A1
公开(公告)日：2020-05-28
申请号：US16630269
申请日：2018-07-12
Inventor： Hideo HOSONO , Yutong GONG , Jlazhen WU , Masaaki KITANO , Toshiharu YOKOYAMA , Yangfan LU , Tiannan YE
Abstract: Provided are an intermetallic compound having high stability and high activity, and a catalyst using the same. A hydrogen storage/release material containing an intermetallic compound represented by formula (1): RTX . . . (1) wherein R represents a lanthanoid element, T represents a transition metal in period 4 or period 5 in the periodic table, and X represents Si, Al or Ge.
-
-
-
-
-
-
-
-
-
Search Results
11
records
(took 0.016 seconds)
