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公开(公告)号：US4913970A
公开(公告)日：1990-04-03
申请号：US237129
申请日：1988-08-29
申请人： Jack Hayward , Michael W. Orem , Gerald G. Reafler
发明人： Jack Hayward , Michael W. Orem , Gerald G. Reafler
IPC分类号： B01F17/00 , B01F17/26 , B05D1/26 , B29C67/24 , C08G18/10 , C08G18/58 , C08G18/79 , C08J7/04 , C09D175/04
CPC分类号： B01F17/0057 , B05D1/26 , B29C67/246 , C08G18/10 , C08G18/58 , C08G18/792 , C08J7/047 , C09D175/04 , C08J2367/02 , C08J2475/04 , Y10S528/905 , Y10T428/256 , Y10T428/3154 , Y10T428/31554 , Y10T428/31565 , Y10T428/31609
摘要： A tie-coat composition for preparing paint-coated, stretchable polyester which can be bonded to automobile panels. The tie-coat contains a non-ionic, fluorinated surfactant which reduces product non-uniformities.
摘要翻译： 一种用于制备涂料的可拉伸聚酯的粘结涂料组合物，其可以结合到汽车面板上。 连接涂层含有非离子型氟化表面活性剂，可降低产品的不均匀性。
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公开(公告)号：US5418128A
公开(公告)日：1995-05-23
申请号：US220850
申请日：1994-03-31
申请人： Michael W. Orem
发明人： Michael W. Orem
IPC分类号： G03C1/38
CPC分类号： G03C1/38
摘要： A coating composition for applying a layer to a photographic element which comprises gelatin, water and from 0.35 to 1 percent by weight based on the total weight of the composition of a surfactant mixture comprising from 20 to 60 percent by weight of a mixture of anionic surfactants, from 30 to 75 percent by weight of a nonionic surfactant and from 3 to 13 percent by weight of a cationic surfactant based on the total weight of surfactant mixture; the mixture of anionic surfactants comprising from 30 to 85 percent by weight of di- and tri-isopropyl naphthalene sulfonate, sodium salts and from 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt; a di-fluoroalkyl sulfosuccinate, sodium salt where alkyl is C.sub.4 -C.sub.6 ; perfluoro-octyl sulfonate(tetraethyl ammonium salt) or a perfluoro-alkyl carboxylate ammonium salt where alkyl is a mixture of C.sub.5 -C.sub.8 alkyl radicals with hexyl being the major component, based on the total weight of the anionic surfactants; the nonionic surfactant being a nonyl phenoxy poly(glycidyl) alcohol and the cationic surfactant being perfluoro-octyl sulfonamide, N-hydrogen, N-propylene trimethylammonium iodide.
摘要翻译： 一种涂料组合物，用于将照相元件施加到包含明胶，水和基于组合物总重量的0.35至1重量％的表面活性剂混合物的涂料组合物，其包含20至60重量％的阴离子表面活性剂 ，30至75重量％的非离子表面活性剂和3至13重量％的阳离子表面活性剂，基于表面活性剂混合物的总重量; 包含30至85重量％的萘磺酸二 - 和三异丙酯，钠盐和15至70重量％的二辛基磺基琥珀酸钠的阴离子表面活性剂的混合物，钠盐; 二氟烷基磺基琥珀酸盐，其中烷基是C 4 -C 6的钠盐; 全氟辛基磺酸盐（四乙基铵盐）或全氟烷基羧酸盐铵盐，其中基于阴离子表面活性剂的总重量，烷基是作为主要组分的C5-C8烷基与己基的混合物; 非离子表面活性剂为壬基苯氧基聚（缩水甘油基）醇，阳离子表面活性剂为全氟辛基磺酰胺，N-氢，N-丙烯三甲基碘化铵。
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公开(公告)号：US06911302B2
公开(公告)日：2005-06-28
申请号：US10704003
申请日：2003-11-07
申请人： Alice G. Moon , Mark P. Pavlik , Michael W. Orem
发明人： Alice G. Moon , Mark P. Pavlik , Michael W. Orem
IPC分类号： B01F17/02 , G03C1/38 , G03C1/76 , G03C1/85 , G03C1/95 , C09D101/26 , C09D189/00 , C09D103/02
CPC分类号： G03C1/385 , G03C1/32 , G03C1/38 , G03C1/85 , G03C2001/7635 , G03C2200/42
摘要： A coating composition for use in a photographic element, the composition comprising an aqueous solution of: two or more surfactants; a hydrophilic binder; and optional matte particles; wherein one of the surfactants is represented by the following Formula (I): Rf—CH2CH2—(B)y-A (I) where Rf is F(CF2CF2)n— and n is 3 and 4 or 3, 4, and 5, and the fraction of all Rf with n=3 is at least 40%; B is a divalent linking group; y is 0 or 1; and A is an anionic group with a counterion or an amphoteric group. A photographic element containing the coating composition is also disclosed.
摘要翻译： 一种用于照相元件的涂料组合物，该组合物包含两种或更多种表面活性剂的水溶液; 亲水性粘合剂; 和可选的磨砂颗粒; 其中一种表面活性剂由下式（I）表示：<？in-line-formula description =“In-line formula”end =“lead”？> R < ＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆gt; -A（I）＆lt;＆lt;行内公式描述=“在线公式”end =“ 尾“→>其中R f是F（CF 2 CH 2）n - n且n是3，并且 4或3，4和5，并且n = 3的所有R f的分数为至少40％; B是二价连接基团; y为0或1; 而A是具有抗衡离子或两性基团的阴离子基团。 还公开了含有涂料组合物的照相元件。
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4.发明授权Fluorinated surfactants in overcoat compositions and elements containing same 失效外涂层组合物中含氟表面活性剂和含有它们的元素公开(公告)号：US06875563B2
公开(公告)日：2005-04-05
申请号：US10702861
申请日：2003-11-06
申请人： Michael W. Orem , Ronald R. Andrews
发明人： Michael W. Orem , Ronald R. Andrews
摘要： A coating composition for use in forming an overcoat layer in a photographic element, said composition comprising an aqueous solution of: a mixture of two or more surfactants; a hydrophilic binder; matte beads; and a lubricating agent; wherein one of the surfactants is represented by the following Formula (I) and is the only fluorosurfactant in the composition: Rf—CH2CH2—S-(A)-D (I) where Rf is —(CF2)nCF3, n represents the number of CF2 groups and is 3 or 5 in at least 60% of the Rf groups present, and in the remainder of Rf groups n is 7, 9, or 11. A is a divalent linking group that includes substituted alkylene or alkylene (N-alkylene)amide; and D is an ionic group. A photographic element with an outermost layer containing the coating composition is also disclosed.
摘要翻译： 一种用于在照相元件中形成外涂层的涂料组合物，所述组合物包含水溶液：两种或更多种表面活性剂的混合物; 亲水性粘合剂; 哑光珠; 和润滑剂; 其中一种表面活性剂由下式（I）表示，并且是组合物中唯一的含氟表面活性剂：其中R f是 - （CF 2）n CF 3，n表示CF 2基团的数目，并且在至少60％的 Rf基团存在，Rf基团的其余部分为7,9或11.A为包含取代的亚烷基或亚烷基（N-亚烷基）酰胺的二价连接基团; 并且D是离子基团。还公开了具有包含该涂料组合物的最外层的照相元件。
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5.发明授权公开(公告)号：US06387611B2
公开(公告)日：2002-05-14
申请号：US09764665
申请日：2001-01-18
IPC分类号： G03C1498
CPC分类号： G03C1/498 , G03C1/49809 , G03C1/4989
摘要： There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate. A media milling method and a controlled precipitation method of making the dispersions are also disclosed
摘要翻译： 公开了一种氧化还原成像组合物，其包含（i）纳米颗粒状羧酸银颗粒的水性分散体，其在颗粒表面上具有作为磷酸酯的表面改性剂和（ii）有机还原剂。 特别地，表面改性剂可以是正磷酸和羟基封端的羟乙基化长链醇或羟乙基化烷基酚或其衍生物的单酯和二酯的混合物。 还公开了包括包括氧化还原成像组合物，热成像元件和光热成像组合物和元素的分散体的各种组合物。 优选的羧酸酯是长链脂肪酸的银盐，例如山嵛酸银。 还公开了制备分散体的介质研磨方法和受控沉淀法
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公开(公告)号：US6040128A
公开(公告)日：2000-03-21
申请号：US160032
申请日：1998-09-24
CPC分类号： G03C1/043 , G03C1/38 , G03C2200/03
摘要： A process of preparing a radiation-sensitive silver halide emulsion is disclosed in which a polyalkylene oxide block copolymer surfactant is employed. Dispersion of the polyalkylene oxide block copolymer surfactant in the aqueous dispersing medium is increased by the inclusion of an auxiliary surfactant. The auxiliary surfactants are selected from among those that, in the form of an aqueous solution containing 10 percent by weight of the auxiliary surfactant based on total weight of the aqueous solution, is miscible in all proportions with at least one of water and the polyalkylene oxide block copolymer surfactant.
摘要翻译： 公开了制备辐射敏感卤化银乳剂的方法，其中使用聚环氧烷嵌段共聚物表面活性剂。 通过添加辅助表面活性剂，聚环氧烷嵌段共聚物表面活性剂在水分散介质中的分散性增加。 辅助表面活性剂选自以水溶液的总重量计含有10重量％的辅助表面活性剂的水溶液的形式，可以与水和聚环氧烷烃中的至少一种以所有比例混溶 嵌段共聚物表面活性剂。
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公开(公告)号：US5888712A
公开(公告)日：1999-03-30
申请号：US991493
申请日：1997-12-16
CPC分类号： B41M5/426 , G03C1/85 , G03G5/104 , G03G5/14704 , G03G5/14708 , G03C1/38 , G03C1/385 , G03C1/853
摘要： The present invention is a multilayer imaging element which includes a support, one or more image-forming layers super posed on the support; and an outermost transparent electrically-conductive, non-charging, overcoat layer superposed on the support. The outermost transparent electrically-conductive, non-charging overcoat layer includes colloidal, electrically-conductive metal-containing granular particles, dispersed in a film-forming binder at a volume percentage of conductive metal-containing particles of from 20 to 80 and a first charge control agent which imparts positive charging properties and a second charge control agent which imparts negative charging properties.
摘要翻译： 本发明是一种多层成像元件，它包括一个支撑体，一个或多个成像层，超过其形成在支撑体上; 以及叠置在载体上的最外面的透明导电的，不带电的外涂层。 最外面的透明导电的不带电的外涂层包括分散在成膜粘合剂中的含导电金属的颗粒的体积百分数为20至80的胶态导电金属颗粒颗粒和第一次充电 赋予正电荷性质的控制剂和赋予负带电性的第二电荷控制剂。
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公开(公告)号：US5411844A
公开(公告)日：1995-05-02
申请号：US220985
申请日：1994-03-31
申请人： Michael W. Orem
发明人： Michael W. Orem
CPC分类号： G03C1/38 , G03C1/85 , Y10S430/136 , Y10S430/151
摘要： A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.
摘要翻译： 一种用于向照相元件施加层的涂料组合物，所得照相元件包含明胶，水和0.3至1g / 100g的组合物，表面活性剂混合物为15至70重量％的二辛基磺基琥珀酸钠，钠盐 或二氟烷基磺基琥珀酸盐，钠盐，35-75重量％的壬基苯氧基多缩水甘油，以及3-14重量％的全氟辛基亚磺酰氨基，N-氢，N-丙烯三甲基碘化铵，基于 表面活性剂混合物; 当使用磺基琥珀酸二辛酯钠盐时，其最小量为0.15gm / 100g涂料组合物。
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公开(公告)号：US5300418A
公开(公告)日：1994-04-05
申请号：US869978
申请日：1992-04-16
CPC分类号： G03C7/388
摘要： The invention relates to a melt for the coating of a layer in a photographic element and which contains water, gelatin and an anionically charged, hydrophobic group containing compound that is (a) water soluble or soluble in a solution of 5 to 20 percent of water miscible organic solvent,said melt being further characterized by containing an amount of an amphiphilic compound which is sufficient to reduce the viscosity of said melt, said compound selected from the class consisting of:Type A: Sugar (saccharidic) compounds, characterized by having one to three hydrophobic groups, each group containing from about 6 to about 22 carbon atoms, and having one or more attached hydrophilic mono- or oligosaccharidic hydrophilic chains that may or may not be terminated by a negatively charged group such as a sulfate, sulfonate or a carboxyl group; andType B: Compounds compromising a hydrophobic group having from about 6 to about 22 carbon atoms and having one or two attached hydrophilic chains comprising at least 4 oxyethylene and/or glycidyl ether groups that may or may not be terminated with a negatively charged group such as a sulfate, sulfonate or a carboxy group.and mixtures thereofThe preferred compounds for this invention are type A compounds.
摘要翻译： 本发明涉及一种用于在照相元件中涂层的熔体，其包含水，明胶和含阴离子电荷的含疏水基团的化合物，其为（a）水溶性或可溶于5至20％的水溶液 所述熔体进一步的特征在于含有一定量的两亲化合物，其足以降低所述熔体的粘度，所述化合物选自以下类别：A型：糖（糖化）化合物，其特征在于具有一种 至三个疏水基团，每个基团含有约6至约22个碳原子，并且具有一个或多个连接的亲水性单糖或寡糖亲水链，其可以或可以不被带负电荷的基团例如硫酸根，磺酸根或 羧基; 和B型：损害具有约6至约22个碳原子的疏水基团并具有一个或两个连接的亲水链的化合物，其包含至少4个氧化乙烯和/或缩水甘油醚基团，其可以或可以不以带负电荷的基团 作为硫酸盐，磺酸盐或羧基。 和其混合物。用于本发明的优选化合物是A型化合物。
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公开(公告)号：US5824464A
公开(公告)日：1998-10-20
申请号：US932597
申请日：1997-09-17
申请人： Brian A. Schell , Michael W. Orem , Yongcai Wang
发明人： Brian A. Schell , Michael W. Orem , Yongcai Wang
CPC分类号： G03C1/7614 , G03C1/775 , G03C1/795 , G03C2001/7448 , G03C2001/7628 , G03C2200/36 , G03C2200/42 , Y10S430/162
摘要： The present invention is a photographic element which includes a support having a front surface and a back surface, and a silver halide imaging layer superposed on the front side of the support. A backing layer is superposed on the backside of the support and is formed by the coating and subsequent drying of an aqueous coating composition having therein a mixture of film-forming colloidal particles and non-film-forming colloidal particles and a fluoropolyether comprising more than 90 mole % units selected from the group consisting of --CF.sub.2 --CF.sub.2 --O--, --CF.sub.2 --O--, --CF(CF.sub.3)--O--, and --CF.sub.2 --CF(CF.sub.3)--O--, and a functional group selected from the group consisting of COOH, --CH.sub.2 --OH, --CH.sub.2 --COOH, --CH.sub.2 --SO.sub.3 H, --CH.sub.2 --PO.sub.3 H, --(CH.sub.2 --CH.sub.2 --O)--H, and --(CH.sub.2 --CH(CH.sub.3)--O--)--H.
摘要翻译： 本发明是一种照相元件，其包括具有前表面和后表面的支撑体和叠置在支撑体前侧上的卤化银成像层。 背衬层叠置在支撑体的背面上，并通过涂覆并随后干燥其中具有成膜胶体颗粒和非成膜胶体颗粒的混合物的水性涂料组合物和包含大于90的氟聚醚而形成 选自-CF 2 -CF 2 -O - ， - CF2-O-，-CF（CF 3）-O-和-CF 2 -CF（CF 3）-O-的摩尔％单元，和选自 由COOH，-CH 2 -OH，-CH 2 -COOH，-CH 2 -SO 3 H，-CH 2 PO 3 H， - （CH 2 -CH 2 -O）-H和 - （CH 2 -CH（CH 3）-O-）组成的组） -H。
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