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1.发明授权Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent 有权使用半结晶，支化或偶联的成核剂聚丙烯结晶公开(公告)号：US06927256B2
公开(公告)日：2005-08-09
申请号：US10289145
申请日：2002-11-05
IPC分类号： B32B27/32 , C07F7/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J5/18 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L101/00 , C09K3/10 , D01F6/06 , D01F6/30 , D01F6/46 , C08F8/00 , C08L9/00 , C08L27/04 , C08L33/14 , C08L45/00
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2023/44 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. In another embodiment, the copolymer is characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene, and as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 一种使丙烯均聚物或共聚物成核的方法，该方法包括在成核条件下将丙烯聚合物与半结晶支化或偶联的聚合物成核剂接触。 在一个实施方案中，丙烯均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的大约相同强度的峰的13 C NMR峰。 在另一个实施方案中，共聚物的特征在于包含至少约60重量％（wt％）的衍生自丙烯的单元，并且具有至少一个以下性质：（i）13 C NMR 对应于约14.6和约15.7ppm的区域误差的峰，约等于强度的峰，（ii）当共聚单体含量即来自乙烯和/或不饱和单体的单元时，B值大于约1.4 共聚物的共聚单体为至少约3重量％，（iii）偏度指数S≈大于约-1.20，（iv）具有T
和（v）报告比用齐格勒 - 纳塔（ZN）催化剂制备的可比共聚物更多的γ型晶体的X射线衍射图。 -
2.发明授权Impact resistance polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers 失效结晶聚丙烯和部分结晶的低分子量冲击改性剂的抗冲击聚合物共混物公开(公告)号：US07250471B2
公开(公告)日：2007-07-31
申请号：US11359091
申请日：2006-02-22
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64044 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 表现出良好抗冲击性的聚合物共混物包括分子量低于基体聚合物的结晶聚丙烯基质和部分结晶共聚物抗冲改性剂。 基质聚合物可以包含任何结晶丙烯均聚物或共聚物。 抗冲击改性共聚物的特征在于包含至少约60重量％（wt％）衍生自丙烯的单元，在某些实施方案中，具有至少一个，优选两个或更多个以下性质：（i） 对应于约14.6和约15.7ppm的区域误差的13 C NMR峰值，大约相等强度的峰值，（ii）当共聚物的共聚单体含量在...时，B值大于约1.4 至少约3重量％，（iii）偏度指数大于约-1.20，（iv）具有基本上保持的T曲线的DSC曲线 相同和最大值随着共聚物中共聚单体的量的增加而减小，和（v）报告比用齐格勒制备的可比共聚物更多的γ型晶体的X射线衍射图 -Natta（ZN）催化剂。
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3.发明授权Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers 有权结晶聚丙烯和部分结晶的低分子量冲击改性剂的抗冲击聚合物共混物公开(公告)号：US07109269B2
公开(公告)日：2006-09-19
申请号：US10884420
申请日：2004-07-02
IPC分类号： C08F8/00 , C08L9/00 , C08L23/00 , C08L23/04 , C08L25/02 , B29B11/18 , B29C39/14 , B29C41/24 , B29C43/22 , D01D5/00
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64044 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 表现出良好抗冲击性的聚合物共混物包括分子量低于基体聚合物的结晶聚丙烯基质和部分结晶共聚物抗冲改性剂。 基质聚合物可以包含任何结晶丙烯均聚物或共聚物。 抗冲击改性共聚物的特征在于包含至少约60重量％（wt％）衍生自丙烯的单元，在某些实施方案中，具有至少一个，优选两个或更多个以下性质：（i） 对应于约14.6和约15.7ppm的区域误差的13 C NMR峰值，大约相等强度的峰值，（ii）当共聚物的共聚单体含量在...时，B值大于约1.4 至少约3重量％，（iii）偏度指数大于约-1.20，（iv）具有基本上保持的T曲线的DSC曲线 相同和最大值随着共聚物中共聚单体的量的增加而减小，和（v）报告比用齐格勒制备的可比共聚物更多的γ型晶体的X射线衍射图 -Natta（ZN）催化剂。
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4.发明授权Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent 失效使用半结晶，支化或偶联的成核剂聚丙烯结晶公开(公告)号：US07250470B2
公开(公告)日：2007-07-31
申请号：US11359020
申请日：2006-02-22
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2023/44 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. In another embodiment, the copolymer is characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene, and as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 一种使丙烯均聚物或共聚物成核的方法，该方法包括在成核条件下将丙烯聚合物与半结晶支化或偶联的聚合物成核剂接触。 在一个实施方案中，丙烯均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的大约相同强度的峰的13 C NMR峰。 在另一个实施方案中，共聚物的特征在于包含至少约60重量％（wt％）的衍生自丙烯的单元，并且具有至少一个以下性质：（i）13 C NMR 对应于约14.6和约15.7ppm的区域误差的峰，约等于强度的峰，（ii）当共聚单体含量即来自乙烯和/或不饱和单体的单元时，B值大于约1.4 共聚物的共聚单体为至少约3重量％，（iii）偏度指数S≈大于约-1.20，（iv）具有T
和（v）报告比用齐格勒 - 纳塔（ZN）催化剂制备的可比共聚物更多的γ型晶体的X射线衍射图。 -
5.发明授权Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent 有权使用半结晶，支化或偶联的成核剂聚丙烯结晶公开(公告)号：US07060754B2
公开(公告)日：2006-06-13
申请号：US10914800
申请日：2004-08-10
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2023/44 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. In another embodiment, the copolymer is characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene, and as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 一种使丙烯均聚物或共聚物成核的方法，该方法包括在成核条件下将丙烯聚合物与半结晶支化或偶联的聚合物成核剂接触。 在一个实施方案中，丙烯均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的大约相同强度的峰的13 C NMR峰。 在另一个实施方案中，共聚物的特征在于包含至少约60重量％（wt％）的衍生自丙烯的单元，并且具有至少一个以下性质：（i）13 C NMR 对应于约14.6和约15.7ppm的区域误差的峰，约等于强度的峰，（ii）当共聚单体含量即来自乙烯和/或不饱和单体的单元时，B值大于约1.4 共聚物的共聚单体为至少约3重量％，（iii）偏度指数S≈大于约-1.20，（iv）具有T
和（v）报告比用齐格勒 - 纳塔（ZN）催化剂制备的可比共聚物更多的γ型晶体的X射线衍射图。 -
6.发明授权Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers 有权结晶聚丙烯和部分结晶的低分子量冲击改性剂的抗冲击聚合物共混物公开(公告)号：US06943215B2
公开(公告)日：2005-09-13
申请号：US10289122
申请日：2002-11-05
IPC分类号： B32B27/32 , C07F7/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J5/18 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L101/00 , C09K3/10 , D01F6/06 , D01F6/30 , D01F6/46 , C08F8/00 , C08L23/00 , C08L23/04 , C08L27/00
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , C08F4/64044 , C08F4/64144 , C08L2666/06 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F2500/15 , C08F2500/26 , C08F2500/03 , C08F2500/08
摘要： Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 表现出良好抗冲击性的聚合物共混物包括分子量低于基体聚合物的结晶聚丙烯基质和部分结晶共聚物抗冲改性剂。 基质聚合物可以包含任何结晶丙烯均聚物或共聚物。 抗冲击改性共聚物的特征在于包含至少约60重量％（wt％）衍生自丙烯的单元，在某些实施方案中，具有至少一个，优选两个或更多个以下性质：（i） 对应于约14.6和约15.7ppm的区域误差的13 C NMR峰，大约相等强度的峰，（ii）当共聚物的共聚单体含量在...时，B值大于约1.4 至少约3重量％，（iii）偏度指数大于约-1.20，（iv）具有基本上保持的T曲线的DSC曲线 相同和最大值随着共聚物中共聚单体的量的增加而减小，和（v）报告比用齐格勒制备的可比共聚物更多的γ型晶体的X射线衍射图 -Natta（ZN）催化剂。
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公开(公告)号：US07344775B2
公开(公告)日：2008-03-18
申请号：US11669342
申请日：2007-01-31
IPC分类号： D01F6/30 , C08F210/06
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F110/06 , C08F210/06 , C08F2420/02 , Y10T428/2904 , Y10T428/2913 , Y10T428/2915 , Y10T428/2929 , Y10T442/3065 , Y10T442/608 , C08F4/64044 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F210/16 , C08F2500/15 , C08F2500/08 , C08F2500/03 , C08F2500/26
摘要： Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. The copolymers are characterized as (A) comprising at least about 60 weight percent (wt %) of units derived from propylene, and (B) having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 包含丙烯均聚物或丙烯与乙烯和一种或多种不饱和共聚单体中的至少一种的共聚物的纤维显示出所需的性质。 均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的大约相同强度的峰的13 C NMR峰。 共聚物的特征在于包含至少约60重量％（wt％）来自丙烯的单元的（A），和（B）具有以下特性中的至少一个：（i） 对应于约14.6和约15.7ppm的区域误差的NMR峰值，约等于强度的峰，（ii）当共聚物的共聚单体含量为至少约3重量％时，B值大于约1.4，（ iii）偏度指数S≈大于约-1.20，（iv）具有保持基本相同的T曲线，以及（ⅳ） 随着共聚物中共聚单体的量的增加而降低，和（v）比用齐格勒 - 纳塔（ZN）催化剂制备的可比较的共聚物报告更多的γ型晶体的X射线衍射图谱。
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公开(公告)号：US06924342B2
公开(公告)日：2005-08-02
申请号：US10100557
申请日：2002-03-15
IPC分类号： C08F2/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F290/04 , C08L23/04 , C08L23/06 , C08L23/08 , C08F4/44 , B01J31/38 , C08F4/72
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymerization process comprises contacting one or more olefinic comonomers in the presence of at least a high molecular weight catalyst and at least a low molecular weight catalyst in a single reactor, and effectuating the polymerization of the olefinic comonomers in the reactor to obtain an olefin polymer. Preferably, both catalysts have the ability to incorporate a substantially similar amount of comonomers in the olefin polymer. The polymers produced by the process may have a relatively higher level of long chain branching while maintaining a relatively narrow molecular weight distribution, i.e., MWD less than about 6. These interpolymers may exhibit processability similar to or better than LDPE but have physical properties similar to metallocene catalyzed polymers.
摘要翻译： 聚合方法包括在单个反应器中在至少一种高分子量催化剂和至少一种低分子量催化剂的存在下使一种或多种烯属共聚单体接触，并使反应器中烯属共聚单体的聚合得到烯烃聚合物 。 优选地，两种催化剂具有在烯烃聚合物中引入基本相似量的共聚单体的能力。 通过该方法生产的聚合物可以具有相对较高水平的长链支化，同时保持相对窄的分子量分布，即MWD小于约6.这些互聚物可以表现出与LDPE相似或优于LDPE的加工性能，但具有类似于 茂金属催化聚合物。
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公开(公告)号：USRE42276E1
公开(公告)日：2011-04-05
申请号：US12604905
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译： 聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。 一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约12.5，y大于或等于 一些聚合物的特征在于满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约3，y大于或等于约4.5，以及 分子量分布大于3.还公开了制备聚合物的方法。
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公开(公告)号：US07897679B2
公开(公告)日：2011-03-01
申请号：US11769491
申请日：2007-06-27
IPC分类号： C08K5/01
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , Y10T428/31909 , C08F4/659 , C08F4/65904 , C08F4/64144 , C08L2666/04 , C08L2666/06 , C08F2500/12 , C08F2500/20 , C08F2500/15 , C08F2500/24 , C08F2500/26 , C08F2500/03 , C08F2500/08 , C08F2/001
摘要： Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta catalyst These polypropylene polymers are made using a nonmetallocene, metal-centered, heteroaryl ligand catalyst. These polymers can be blended with other polymers, and are useful in the manufacture of films, sheets, foams, fibers and molded articles.
摘要翻译： 包含丙烯，乙烯和/或一种或多种不饱和共聚单体的独特共聚物的特征在于具有以下特性中的至少一个，优选多于一个：（i）对应于约14.6和约约14.6的区域误差的13 C NMR峰 15.7ppm，当共聚物的共聚单体含量为至少约3重量％时，约等于强度的峰，（ii）B值大于约1.4，（iii）偏度指数为6，大于约-1.20 ，（iv）具有保持基本相同的Tme的DSC曲线和随着共聚物中共聚单体的量增加而减小的Tmax，以及（v）报告更多的γ型晶体的X射线衍射图比 用齐格勒 - 纳塔催化剂制备的可比共聚物这些聚丙烯聚合物使用非金属茂金属中心的杂芳基配体催化剂制备。 这些聚合物可以与其它聚合物共混，并且可用于制造薄膜，片材，泡沫，纤维和模制品。
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