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公开(公告)号：US5079333A
公开(公告)日：1992-01-07
申请号：US552635
申请日：1990-07-13
IPC分类号： C08G79/04
CPC分类号： C08G79/04
摘要： Amine-terminated poly(arylene ether phosphine oxide) oligomers of the general formula ##STR1## where Ar' is phenyl, biphenyl, bisphenol-A, etc., can be formed by reaction of a bisphenol monomer, a dihalo triphenyl phosphine oxide monomer, and an aminophenol.
摘要翻译： 可以通过双酚单体，二卤代三苯基膦氧化物单体的反应形成通式“IMAGE”的胺封端的聚（亚芳基醚氧化膦）低聚物，其中Ar'是苯基，联苯基，双酚A等， 和氨基苯酚。
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2.发明授权Oxygen plasma resistant polymeric film and fiber forming macromolecules containing the phosphine oxide moiety 失效耐氧等离子体聚合物膜和含有氧化膦部分的纤维形成大分子
公开(公告)号：US5407528A
公开(公告)日：1995-04-18
申请号：US920989
申请日：1992-07-28
摘要： Poly(arylene ether phosphine oxide)s provide hydrolytic, thermal and oxidative stability. These materials have T.sub.g s ranging from about 190.degree.-280.degree. C., and are more self-extinguishing than other engineering thermoplastics tested when burned due to the presence of phosphorus in a substantial amount of char. Moreover, phosphorus presence played a major role in resisting aggressive oxygen plasma environments by forming a highly oxidized, non-volatile phosphorus containing surface layer.
摘要翻译： 聚（亚芳基醚氧化膦）提供水解，热和氧化稳定性。 这些材料的Tg为约190°-280℃，并且比其它工程热塑性塑料更加自熄，这是因为在大量炭中存在磷而燃烧时所测试的。 此外，通过形成高度氧化的，不挥发的含磷表面层，磷的存在在抵抗侵蚀性氧等离子体环境中起主要作用。
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3.发明授权Phosphorus containing poly(arylene ether)s useful as oxygen plasma resistant films and in nonlinear optical applications 失效含有聚（亚芳基醚）的磷可用作耐氧等离子体膜和非线性光学应用
公开(公告)号：US5387629A
公开(公告)日：1995-02-07
申请号：US99993
申请日：1993-07-30
摘要： Polymers containing the phosphine oxide moiety are identified as being particularly useful in applications where resistance to atomic oxygen etching is required and in applications where second order nonlinear optical effects will be utilized. Particularly preferred polymers for these two applications include poly(arylene ether phosphine oxide)s (PEPOS), and novel PEPOS which include phenolphthalein sub-units and derivatives thereof have been prepared.
摘要翻译： 含有氧化膦部分的聚合物被认为特别适用于需要耐原子氧蚀刻的应用，并且在使用二阶非线性光学效应的应用中。 用于这两种应用的特别优选的聚合物包括聚（亚芳基醚氧化膦）（PEPOS），并且已经制备了包括酚酞亚单元及其衍生物的新型PEPOS。
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公开(公告)号：US09782523B2
公开(公告)日：2017-10-10
申请号：US13101391
申请日：2011-05-05
CPC分类号： A61L31/18 , A61F2/92 , A61K49/12 , A61K49/126 , A61K49/128 , A61L31/06 , C08F220/00 , C08G63/00 , C08G63/08
摘要： Side-chain crystallizable (SCC) polymers are useful in various medical applications. In certain applications, heavy atom containing side-chain crystallizable polymers (HACSCCP's) are particularly useful. An example of a HACSCCP is a polymer that comprises a main chain, a plurality of crystallizable side chains, and a plurality of heavy atoms attached to the polymer. In certain configurations, the heavy atoms are present in an amount that is effective to render the polymer radiopaque. A polymeric material that includes an HACSCCP may be fabricated into a medical device useful for at least partially occluding a body cavity. For example, such a medical device may be an embolotherapy product. A polymeric material that includes a SCC polymer may also be fabricated into other medical devices, such as stents.
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公开(公告)号：US08703113B2
公开(公告)日：2014-04-22
申请号：US11335771
申请日：2006-01-18
IPC分类号： A61K31/74
CPC分类号： A61L31/18 , A61F2/92 , A61K49/12 , A61K49/126 , A61K49/128 , A61L31/06 , C08F220/00 , C08G63/00 , C08G63/08
摘要： Side-chain crystallizable (SCC) polymers are useful in various medical applications. In certain applications, heavy atom containing side-chain crystallizable polymers (HACSCCP's) are particularly useful. An example of a HACSCCP is a polymer that comprises a main chain, a plurality of crystallizable side chains, and a plurality of heavy atoms attached to the polymer. In certain configurations, the heavy atoms are present in an amount that is effective to render the polymer radiopaque. A polymeric material that includes an HACSCCP may be fabricated into a medical device useful for at least partially occluding a body cavity. For example, such a medical device may be an embolotherapy product. A polymeric material that includes a SCC polymer may also be fabricated into other medical devices, such as stents.
摘要翻译： 侧链可结晶（SCC）聚合物可用于各种医疗应用。 在某些应用中，含重链原子的侧链可结晶聚合物（HACSCCP）特别有用。 HACSCCP的实例是包含主链，多个可结晶侧链和连接到聚合物上的多个重原子的聚合物。 在某些构型中，重质原子以有效使聚合物不透射线的量存在。 包括HACSCCP的聚合物材料可以制造成用于至少部分地封闭体腔的医疗装置。 例如，这种医疗装置可以是电疗产品。 包括SCC聚合物的聚合物材料也可制成其他医疗装置，例如支架。
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公开(公告)号：US20070237720A1
公开(公告)日：2007-10-11
申请号：US11399136
申请日：2006-04-06
申请人： Orlando Padilla , Andrew Morris , John Nguyen , Eric V. Schmid , Donald K. Brandom , James E. McGrath
发明人： Orlando Padilla , Andrew Morris , John Nguyen , Eric V. Schmid , Donald K. Brandom , James E. McGrath
CPC分类号： A61B17/12022 , A61B17/0467 , A61B17/12113 , A61B17/12136 , A61B17/12168 , A61B17/12172 , A61B17/12177 , A61B17/1219 , A61B2017/12054 , A61B2017/12081 , A61B2090/037 , A61K49/0442 , A61L24/001 , A61L24/0042 , A61L24/06 , A61L2430/36
摘要： The invention relates to an implantable embolic medical device comprising a non-erodible, erodible or biodegradable material. The device preferably comprises one or more longitudinal filament members of varying cross sectional shapes which may or may not be coiled to suit a particular clinical need. The embolic device is placed through lumens and cavities to reach areas in the body which require embolism to achieve a particular clinical objective.
摘要翻译： 本发明涉及可植入栓塞医疗装置，其包括不可侵蚀，可侵蚀或可生物降解的材料。 该装置优选地包括一个或多个变化的横截面形状的纵向长丝构件，其可以或可以不被卷起以适合特定的临床需要。 栓塞装置通过腔和空腔放置以到达需要栓塞的身体中实现特定临床目标的区域。
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公开(公告)号：US08383763B2
公开(公告)日：2013-02-26
申请号：US12845874
申请日：2010-07-29
申请人： James E. McGrath , Michael Hickner , Feng Wang , Yu-Seung Kim
发明人： James E. McGrath , Michael Hickner , Feng Wang , Yu-Seung Kim
IPC分类号： C08G75/20
摘要： Sulfonated polymers are made by the direct polymerization of a sulfonated monomer to form the sulfonated polymers. The types of sulfonated polymers may include polysulfones or polyimides. The sulfonated polymers can be formed into membranes that may be used in proton exchange membrane fuel cells or as ion exchange membranes. The membranes formed from the sulfonated polymers exhibit improved properties over that of Nafion®. A heteropoly acid may be added to the sulfonated polymer to form a nanocomposite membrane in which the heteropoly acid is highly dispersed. The addition of a heteropoly acid to the sulfonated polymer increases the thermal stability of the membrane, enhances the conductivity above 100° C., and reduces the water uptake of the membrane.
摘要翻译： 磺化聚合物通过磺化单体的直接聚合制成磺化聚合物。 磺化聚合物的类型可以包括聚砜或聚酰亚胺。 磺化聚合物可以形成为可用于质子交换膜燃料电池或作为离子交换膜的膜。 由磺化聚合物形成的膜表现出比Nafion®改善的性能。 可以将杂多酸加入到磺化聚合物中以形成杂多酸高度分散的纳米复合膜。 向磺化聚合物中加入杂多酸增加了膜的热稳定性，提高了100℃以上的电导率，并降低了膜的吸水率。
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公开(公告)号：US07473714B2
公开(公告)日：2009-01-06
申请号：US11119353
申请日：2005-05-02
申请人： Brian R. Einsla , James E. McGrath
发明人： Brian R. Einsla , James E. McGrath
CPC分类号： C08J5/2256 , C08G65/48 , C08G75/23 , C08J2371/12 , C08J2381/06
摘要： A family of polymers having pendent sulfonate moieties connected to polymeric main chain phenyl groups are described. These polymers are prepared by the steps of polymerization (using a monomer with a phenyl with an alkoxy substitution), deportation by converting the alkoxy to a hydroxyl, and functionalization of the polymer with a pendant sulfonate group. As an example, sulfonated poly(arylene ether sulfone) copolymers with pendent sulfonic acid groups are synthesized by the direct copolymerization of methoxy-containing poly(arylene ether sulfone)s, then converting the methoxy groups to the reactive hydroxyl form, and finally functionalizing the hydroxyl form with proton-conducting sites through nucleophilic substitution. The family of polymers may have application in proton exchange membranes and in other applications.
摘要翻译： 描述了具有连接到聚合主链苯基的侧链磺酸酯部分的聚合物族。 这些聚合物通过聚合（使用具有烷氧基取代基的苯基）的单体，通过将烷氧基转化为羟基而进行递送的步骤，以及用磺酸侧基官能化聚合物来制备。 作为例子，通过直接共聚含甲氧基的聚（亚芳基醚砜），然后将甲氧基转化为反应性羟基，合成具有侧链磺酸基的磺化聚（亚芳基醚砜）共聚物，最后使 羟基与质子传导位点通过亲核取代。 聚合物族可以用于质子交换膜和其它应用中。
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9.发明授权Highly conductive thermoplastic composites for rapid production of fuel cell bipolar plates 失效用于快速生产燃料电池双极板的高导电性热塑性复合材料公开(公告)号：US07365121B2
公开(公告)日：2008-04-29
申请号：US10779804
申请日：2004-02-18
申请人： Jianhua Huang , Donald G. Baird , James E. McGrath
发明人： Jianhua Huang , Donald G. Baird , James E. McGrath
CPC分类号： C08K7/02
摘要： A low cost method of fabricating bipolar plates for use in fuel cells utilizes a wet lay process for combining graphite particles, thermoplastic fibers, and reinforcing fibers to produce a plurality of formable sheets. The formable sheets are then molded into a bipolar plates with features impressed therein via the molding process. The bipolar plates formed by the process have conductivity in excess of 150 S/cm and have sufficient mechanical strength to be used in fuel cells. The bipolar plates can be formed as a skin/core laminate where a second polymer material is used on the skin surface which provides for enhanced conductivity, chemical resistance, and resistance to gas permeation.
摘要翻译： 制造用于燃料电池的双极板的低成本方法利用湿式铺设方法来组合石墨颗粒，热塑性纤维和增强纤维，以生产多个可成形片材。 然后将可成形片材模制成具有通过模制工艺在其中印刷的特征的双极板。 通过该方法形成的双极板具有超过150S / cm的电导率并且具有足够的机械强度以用于燃料电池。 双极板可以形成为皮肤/芯层压板，其中在皮肤表面上使用第二聚合物材料，其提供增强的导电性，耐化学性和耐气体渗透性。
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公开(公告)号：US07067083B2
公开(公告)日：2006-06-27
申请号：US11105898
申请日：2005-04-13
CPC分类号： C08G79/04
摘要： High refractive index, melt processable polyphosphonates and methods for preparing the same are provided. These polymers are particularly useful for optical and ophthalmic parts, such as lenses. A method of preparing optical and ophthalmic lenses by injection molding the polymers of the present invention into the form of the optical or ophthalmic lenses is also provided.
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