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公开(公告)号：US4594291A
公开(公告)日：1986-06-10
申请号：US716279
申请日：1985-03-25
CPC分类号： C08G59/00 , C08G59/02 , C08G59/40 , C08G59/68 , Y10T428/31515
摘要： Relatively high molecular weight epoxy resins cured with conventional curing agents are disclosed wherein the relatively high molecular weight epoxy resin is prepared in the presence of the curing agents. The resultant cured epoxy resin has an improvement in Tg or toughness and the mixture prior to reaction and curing is much easier to apply as a coating or in the preparation of castings, laminates and the like as compared to applications of mixtures of relatively high molecular weight epoxy resins and the curing agents.
摘要翻译： 公开了用常规固化剂固化的相对高分子量的环氧树脂，其中在固化剂存在下制备相对高分子量的环氧树脂。 得到的固化环氧树脂具有Tg或韧性的改善，并且在反应和固化之前的混合物比用于相对高分子量的混合物时更容易作为涂层或用于制备铸件，层压材料等 环氧树脂和固化剂。
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公开(公告)号：US4895755A
公开(公告)日：1990-01-23
申请号：US259449
申请日：1988-10-14
申请人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
发明人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
CPC分类号： C08G59/30 , C07C37/62 , C07D303/24 , C08G59/066 , C08G59/3218 , H05K1/0326 , Y10T428/31522 , Y10T428/31529 , Y10T442/2434 , Y10T442/2992
摘要： Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.
摘要翻译： 公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子 到一个芳香环。 这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比， 在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。
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公开(公告)号：US4727119A
公开(公告)日：1988-02-23
申请号：US907706
申请日：1986-09-15
申请人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
发明人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
IPC分类号： C08G59/14 , C07C37/62 , C07D303/24 , C08G59/06 , C08G59/30 , C08G59/32 , C08L63/00 , H05K1/03
CPC分类号： C07D303/24 , C07C37/62 , C08G59/066 , C08G59/30 , C08G59/3218 , H05K1/0326
摘要： Halogenated aromatic epoxy resins are disclosed wherein the halogen atoms are in the meta position with respect to a glycidyl ether group attached to an aromatic ring.Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.
摘要翻译： 公开了卤化芳族环氧树脂，其中卤素原子相对于连接到芳族环上的缩水甘油醚基团处于间位。 公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子 到一个芳香环。 这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比， 在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。
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4.发明授权
公开(公告)号：US5079314A
公开(公告)日：1992-01-07
申请号：US440632
申请日：1989-11-17
CPC分类号： C08G59/621 , C08G59/08 , C08G59/3218 , C08G8/04 , C08G8/08 , C08L63/00
摘要： Phenol-aldehyde novolac resins having reduced quantities of 2-functional material are prepared by removing all or part of the 2-functional material from this product resulting from reacting phenol with an aldehyde. Epoxy novolac resins prepared from the novolac resin containing less 2-functional product exhibit increased Tg values when cured.
摘要翻译： 通过从苯酚与醛反应得到的全部或部分2-官能物质除去二官能材料量减少的酚醛酚醛清漆树脂。 由含有较少2功能产物的酚醛清漆树脂制备的环氧酚醛树脂在固化时表现出增加的Tg值。
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公开(公告)号：US4946817A
公开(公告)日：1990-08-07
申请号：US274264
申请日：1988-11-18
摘要： Latent catalysts for epoxy reactions are prepared by reacting a tetrasubstituted onium compound such as tetrabutylphosphonium acetate acetic acid complex with an acid or metal salt of an acid having a weak-nucleophilic anion such as fluoboric acid. These catalysts provide stable latent catalysts for epoxy resins for advancement or curing reactions.
摘要翻译： 用于环氧反应的潜在催化剂通过四取代的鎓化合物如乙酸四丁基乙酸盐与具有弱亲核阴离子的酸或金属盐如氟硼酸反应来制备。 这些催化剂为环氧树脂提供稳定的潜在催化剂用于进行或固化反应。
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6.发明授权Phenol-formaldehyde resins containing reduced quantities of 2-functional components and epoxy novolac resins prepared therefrom 失效苯酚 - 甲醛树脂含有由其制备的减少量的2-官能组分和环氧酚醛清漆树脂
公开(公告)号：US4755543A
公开(公告)日：1988-07-05
申请号：US16025
申请日：1987-02-18
CPC分类号： C08G59/3218 , C08G59/08 , C08G8/04 , C08L63/00
摘要： Phenol-aldehyde novolac resins having reduced quantities of 2-functional material are prepared by removing all or part of the 2-functional material from this product resulting from reacting phenol with an aldehyde. Epoxy novolac resins prepared from the novolac resin containing less 2-functional product exhibit increased Tg values when cured.
摘要翻译： 通过从苯酚与醛反应得到的全部或部分2-官能物质除去二官能材料量减少的酚醛酚醛清漆树脂。 由含有较少2功能产物的酚醛清漆树脂制备的环氧酚醛树脂在固化时表现出增加的Tg值。
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公开(公告)号：US5151496A
公开(公告)日：1992-09-29
申请号：US823636
申请日：1991-12-18
CPC分类号： C08G59/3218 , C08G59/08 , C08G59/621 , C08G8/08
摘要： The 2-functional component of substituted phenol-aldehyde novolac resins is reduced. Epoxy novolac resins prepared from the novolac resin containing reduced quantities of 2-functional product exhibit increased Tg values when cured.
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8.发明授权Substituted phenol-formaldehyde novolac resins containing reduced quantities of 2-functional components and epoxy novolac resins prepared therefrom 失效含有由其制备的减少量的2-官能组分和环氧酚醛清漆树脂的取代苯酚 - 甲醛酚醛清漆树脂
公开(公告)号：US5106923A
公开(公告)日：1992-04-21
申请号：US658968
申请日：1991-02-21
CPC分类号： C08G59/3218 , C08G59/025 , C08G59/08 , C08G59/621 , C08G8/08
摘要： The 2-functional component of substituted phenol-aldehyde novolac resins is reduced. Epoxy novolac resins prepared from the novolac resin containing reduced quantities of 2-functional product exhibit increased Tg values when cured.
摘要翻译： 取代酚醛酚醛清漆树脂的2官能组分被还原。 含有减少量2-功能产物的酚醛清漆树脂制备的环氧酚醛树脂在固化时表现出增加的Tg值。
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9.发明授权Latent, curable, catalyzed mixtures of epoxy-containing and phenolic hydroxyl-containing compounds 失效潜在，可固化，催化的含环氧基和含酚羟基化合物的混合物
公开(公告)号：US4925901A
公开(公告)日：1990-05-15
申请号：US274250
申请日：1988-11-18
CPC分类号： C08G59/066 , B29C67/246 , C08G59/621 , C08G59/68
摘要： Storage stable compositions are disclosed which comprise an epoxide containing compound, a phenolic hydroxyl containing compound, and a catalyst compound for catalyzing the reaction between epoxide groups and aromatic hydroxyl groups which catalyst comprises the product resulting from contacting an onium salt, amine, or amine salt with an acid or a salt of an acid having a weak nucleophilic anion.
摘要翻译： 公开了包含含环氧化物的化合物，含酚羟基的化合物和用于催化环氧基和芳族羟基之间的反应的催化剂化合物的储存稳定的组合物，该催化剂包括由鎓盐，胺或胺盐 与酸或具有弱亲核阴离子的酸的盐。
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10.发明授权Latent, curable, catalyzed mixtures of epoxy-containing and phenolic-hydroxyl-containing compounds containing compounds or complexes formed from contacting organic phosphines or arsines with weak nucleophilic acids 失效含有环氧化合物和含酚羟基化合物的潜在的，可固化的，催化的混合物，其含有由有机膦或胂与弱亲核酸接触形成的化合物或络合物
公开(公告)号：US5140079A
公开(公告)日：1992-08-18
申请号：US685332
申请日：1991-04-15
CPC分类号： C08G59/688 , B01J31/0267 , B01J31/0272 , C07F9/50 , C07F9/743 , C08G59/68
摘要： The products resulting from contacting an organic phosphine or arsine with an inorganic acid having a weak nucleophilic anion provide for relatively stable compositions when admixed with a compound containing an average of more than one vicinal epoxide group per molecule and which optionally contains a compound containing an average of more than one phenolic hydroxyl group per molecule.
摘要翻译： 通过使有机膦或胂与具有弱亲核阴离子的无机酸接触而产生的产物在与每分子平均含有多于一个邻位环氧基的化合物混合时提供相对稳定的组合物，并且任选地含有含有平均值的化合物 每个分子多于一个酚羟基。
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