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公开(公告)号：US06380417B1
公开(公告)日：2002-04-30
申请号：US09662356
申请日：2000-09-15
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： C07C6800
CPC分类号： B01J31/0231 , B01J23/6562 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/2234 , B01J2231/34 , B01J2531/38 , B01J2531/39 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of a combination of inorganic co-catalysts containing manganese and nickel; manganese and iron; manganese and chromium; manganese and cerium; manganese and europium; manganese, cerium, and europium; manganese, iron, and europium; or manganese and thorium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various other inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的无机助催化剂的组合， 锰和镍; 锰和铁; 锰和铬; 锰和铈; 锰和铕; 锰，铈和铕; 锰，铁和铕; 或锰和钍。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种其它无机助催化剂组合。
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公开(公告)号：US6143914A
公开(公告)日：2000-11-07
申请号：US301700
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
CPC分类号： B01J31/0231 , B01J23/6562 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/2234 , C07C68/005 , B01J2231/34 , B01J2531/38 , B01J2531/39 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of a combination of inorganic co-catalysts containing manganese and nickel; manganese and iron; manganese and chromium; manganese and cerium; manganese and europium; manganese, cerium, and europium; manganese, iron, and europium; or manganese and thorium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various other inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的无机助催化剂的组合， 锰和镍; 锰和铁; 锰和铬; 锰和铈; 锰和铕 锰，铈和铕; 锰，铁和铕; 或锰和钍。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种其它无机助催化剂组合。
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公开(公告)号：US06197991B1
公开(公告)日：2001-03-06
申请号：US09301703
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： C07C6800
CPC分类号： B01J31/2234 , B01J23/622 , B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/26 , B01J31/28 , B01J31/32 , B01J2231/34 , B01J2531/44 , B01J2531/46 , B01J2531/48 , B01J2531/72 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing lead and a catalytic amount of an inorganic co-catalyst containing titanium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的含铅的无机助催化剂和 催化量的含钛的无机助催化剂。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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公开(公告)号：US06420587B2
公开(公告)日：2002-07-16
申请号：US09777818
申请日：2001-02-05
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： B01J2344
CPC分类号： B01J31/2234 , B01J23/622 , B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/26 , B01J31/28 , B01J31/32 , B01J2231/34 , B01J2531/44 , B01J2531/46 , B01J2531/48 , B01J2531/72 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing lead and a catalytic amount of an inorganic co-catalyst containing titanium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的含铅的无机助催化剂和 催化量的含钛的无机助催化剂。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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公开(公告)号：US6160154A
公开(公告)日：2000-12-12
申请号：US301698
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Marsha Mottel Grade , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Marsha Mottel Grade , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
CPC分类号： B01J31/2234 , B01J23/89 , B01J31/0231 , B01J31/0235 , B01J2231/321 , B01J2531/16 , B01J2531/38 , B01J2531/46 , B01J2531/54 , B01J2531/62 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing copper. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在包含催化量的含铜无机助催化剂的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触而使芳族羟基化合物羰基化的方法。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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6.发明授权Bromination of hydroxyaromatic compounds and further conversion to dihydroxyaromatic compounds 有权溴化羟基芳族化合物并进一步转化为二羟基芳族化合物公开(公告)号：US07045666B2
公开(公告)日：2006-05-16
申请号：US10342475
申请日：2003-01-16
申请人： Eric James Pressman , John Yaw Ofori , Grigorii Lev Soloveichik , Ryan Christopher Mills , Jonathan Lloyd Male
发明人： Eric James Pressman , John Yaw Ofori , Grigorii Lev Soloveichik , Ryan Christopher Mills , Jonathan Lloyd Male
IPC分类号： C07C39/24
摘要： Brominated hydroxyaromatic compounds such as p-bromophenol are prepared by contacting a hydroxyaromatic compound with oxygen and a bromine source such as hydrogen bromide or an alkali metal or alkaline earth metal bromide in an acidic medium, in the presence of elemental copper or a copper compound as catalyst. The brominated product of this reaction may be converted alternately to a dihydroxyaromatic compound such as hydroquinone by hydrolyses, or a dihydroxybiphenyl compound such as 4,4′-dihydroxybiphenyl by reductive coupling.
摘要翻译： 通过在酸性介质中，在元素铜或铜化合物存在下使羟基芳族化合物与氧和溴源如溴化氢或碱金属或碱土金属溴化物在酸性介质中接触来制备溴对羟基芳族化合物，如 催化剂。 该反应的溴化物可以通过还原偶联来交替地转化成二羟基芳族化合物如氢醌，或二羟基联苯化合物如4,4'-二羟基联苯。
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7.发明授权Catalyst composition for producing diaryl carbonates using carboxylic acid amide as promoter 失效用羧酸酰胺作助催化剂生产碳酸二芳酯的催化剂组合物公开(公告)号：US06346499B1
公开(公告)日：2002-02-12
申请号：US09686741
申请日：2000-10-11
申请人： Bruce Fletcher Johnson , Grigorii Lev Soloveichik , Eric James Pressman , Kirill Vladimirovich Shalyaev
发明人： Bruce Fletcher Johnson , Grigorii Lev Soloveichik , Eric James Pressman , Kirill Vladimirovich Shalyaev
IPC分类号： B01J3100
CPC分类号： B01J31/2234 , B01J31/0247 , B01J31/2239 , B01J31/26 , B01J2531/16 , B01J2531/38 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a metal from Groups 8-10 of the Periodic Table having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; at least one carboxylic acid amide such as N-methylpyrrolidone or dimethylacetamide; and a cocatalyst which is a compound of one or more metals including copper, titanium, zinc, lead, cerium and manganese.
摘要翻译： 羟基芳族化合物如苯酚在含有原子序数至少为44，优选钯的周期表第8-10族的金属的催化剂体系存在下，用氧和一氧化碳羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 至少一种羧酸酰胺如N-甲基吡咯烷酮或二甲基乙酰胺; 和作为一种或多种金属的化合物的助催化剂，包括铜，钛，锌，铅，铈和锰。
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8.发明授权Catalyst composition and method for producing diaryl carbonates using nitrile as promoter 有权催化剂组合物和使用腈作助催化剂生产碳酸二芳酯的方法公开(公告)号：US06403821B1
公开(公告)日：2002-06-11
申请号：US09677179
申请日：2000-10-02
申请人： Eric James Pressman , Grigorii Lev Soloveichik , Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev
发明人： Eric James Pressman , Grigorii Lev Soloveichik , Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev
IPC分类号： C07C6996
CPC分类号： B01J31/2239 , B01J31/0235 , B01J31/2234 , B01J31/26 , B01J2231/321 , B01J2531/38 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and a promoter compound which is at least one C2-8 aliphatic or C7-10 aromatic mono- or dinitrile, preferably acetonitrile or adiponitrile. The catalyst system also preferably contains a compound of a non-Group VIIIB metal, preferably lead.
摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种C 2-8脂族或C 7-10芳族单或二腈，优选乙腈或己二腈的促进剂化合物。 催化剂体系还优选含有非ⅧB族金属化合物，优选含铅。
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公开(公告)号：US06265340B1
公开(公告)日：2001-07-24
申请号：US09699005
申请日：2000-10-30
申请人： Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Eric James Pressman
发明人： Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Eric James Pressman
IPC分类号： B01J3100
CPC分类号： B01J31/0222 , B01J31/2234 , B01J31/2239 , B01J2531/16 , B01J2531/26 , B01J2531/44 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one sulfone such as sulfolane. The catalyst system also preferably contains a compound of another metal, preferably lead.
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公开(公告)号：US06215014B1
公开(公告)日：2001-04-10
申请号：US09383424
申请日：1999-08-27
申请人： Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Eric James Pressman
发明人： Bruce Fletcher Johnson , Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Eric James Pressman
IPC分类号： C07C6800
CPC分类号： B01J31/0222 , B01J31/2234 , B01J31/2239 , B01J2531/16 , B01J2531/26 , B01J2531/44 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one sulfone such as sulfolane. The catalyst system also preferably contains a compound of another metal, preferably lead.
摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种砜如环丁砜。 催化剂体系还优选含有另一种金属的化合物，优选含有铅。
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