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1.发明授权Bromination of hydroxyaromatic compounds and further conversion to dihydroxyaromatic compounds 有权溴化羟基芳族化合物并进一步转化为二羟基芳族化合物公开(公告)号：US07045666B2
公开(公告)日：2006-05-16
申请号：US10342475
申请日：2003-01-16
申请人： Eric James Pressman , John Yaw Ofori , Grigorii Lev Soloveichik , Ryan Christopher Mills , Jonathan Lloyd Male
发明人： Eric James Pressman , John Yaw Ofori , Grigorii Lev Soloveichik , Ryan Christopher Mills , Jonathan Lloyd Male
IPC分类号： C07C39/24
摘要： Brominated hydroxyaromatic compounds such as p-bromophenol are prepared by contacting a hydroxyaromatic compound with oxygen and a bromine source such as hydrogen bromide or an alkali metal or alkaline earth metal bromide in an acidic medium, in the presence of elemental copper or a copper compound as catalyst. The brominated product of this reaction may be converted alternately to a dihydroxyaromatic compound such as hydroquinone by hydrolyses, or a dihydroxybiphenyl compound such as 4,4′-dihydroxybiphenyl by reductive coupling.
摘要翻译： 通过在酸性介质中，在元素铜或铜化合物存在下使羟基芳族化合物与氧和溴源如溴化氢或碱金属或碱土金属溴化物在酸性介质中接触来制备溴对羟基芳族化合物，如 催化剂。 该反应的溴化物可以通过还原偶联来交替地转化成二羟基芳族化合物如氢醌，或二羟基联苯化合物如4,4'-二羟基联苯。
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公开(公告)号：US06982356B2
公开(公告)日：2006-01-03
申请号：US10664093
申请日：2003-09-17
IPC分类号： C07C39/24
CPC分类号： B01J31/2234 , B01J23/72 , B01J27/122 , B01J31/28 , B01J31/34 , B01J31/4015 , B01J31/403 , B01J38/48 , B01J2231/4277 , B01J2231/52 , B01J2531/16 , B01J2531/46 , B01J2531/56 , C07C37/00 , C07C37/62 , C07C37/68 , C07C37/72 , Y02P20/582 , Y02P20/584 , C07C39/27
摘要： A method for preparing hydroxyaromatic compounds brominated in the para-position, such as p-bromophenol, is disclosed. The method yields overall high process selectivity through isomeric equilibration and separation of the brominated products, thereby eliminating the need for high para selectivity in the products of catalytic oxybromination reactions of hydroxyaromatic compounds using oxygen, a bromine source, and an acidic medium in the presence of a metal catalyst. Furthermore, the invention provides an efficient method for recycling the metal catalyst, as well as reagents used in the bromination, to further reactions.
摘要翻译： 公开了一种制备在对位溴化的羟基芳族化合物的方法，例如对溴苯酚。 该方法通过异构平衡和溴化产物的分离产生总体高的工艺选择性，从而消除了在存在有氧，溴源和酸性介质的情况下，使用氧，芳族化合物和酸性介质的羟基芳族化合物的催化氧溴化反应的产物中对高选择性的需要 金属催化剂。 此外，本发明提供了将金属催化剂以及用于溴化的试剂再循环到进一步反应的有效方法。
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公开(公告)号：US06380417B1
公开(公告)日：2002-04-30
申请号：US09662356
申请日：2000-09-15
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： C07C6800
CPC分类号： B01J31/0231 , B01J23/6562 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/2234 , B01J2231/34 , B01J2531/38 , B01J2531/39 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of a combination of inorganic co-catalysts containing manganese and nickel; manganese and iron; manganese and chromium; manganese and cerium; manganese and europium; manganese, cerium, and europium; manganese, iron, and europium; or manganese and thorium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various other inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的无机助催化剂的组合， 锰和镍; 锰和铁; 锰和铬; 锰和铈; 锰和铕; 锰，铈和铕; 锰，铁和铕; 或锰和钍。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种其它无机助催化剂组合。
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公开(公告)号：US6143914A
公开(公告)日：2000-11-07
申请号：US301700
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
CPC分类号： B01J31/0231 , B01J23/6562 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/2234 , C07C68/005 , B01J2231/34 , B01J2531/38 , B01J2531/39 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of a combination of inorganic co-catalysts containing manganese and nickel; manganese and iron; manganese and chromium; manganese and cerium; manganese and europium; manganese, cerium, and europium; manganese, iron, and europium; or manganese and thorium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various other inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的无机助催化剂的组合， 锰和镍; 锰和铁; 锰和铬; 锰和铈; 锰和铕 锰，铈和铕; 锰，铁和铕; 或锰和钍。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种其它无机助催化剂组合。
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公开(公告)号：US06197991B1
公开(公告)日：2001-03-06
申请号：US09301703
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： C07C6800
CPC分类号： B01J31/2234 , B01J23/622 , B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/26 , B01J31/28 , B01J31/32 , B01J2231/34 , B01J2531/44 , B01J2531/46 , B01J2531/48 , B01J2531/72 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing lead and a catalytic amount of an inorganic co-catalyst containing titanium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的含铅的无机助催化剂和 催化量的含钛的无机助催化剂。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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公开(公告)号：US06420587B2
公开(公告)日：2002-07-16
申请号：US09777818
申请日：2001-02-05
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt , James Norman Cawse , Bruce Fletcher Johnson , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
IPC分类号： B01J2344
CPC分类号： B01J31/2234 , B01J23/622 , B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/26 , B01J31/28 , B01J31/32 , B01J2231/34 , B01J2531/44 , B01J2531/46 , B01J2531/48 , B01J2531/72 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing lead and a catalytic amount of an inorganic co-catalyst containing titanium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在羰基化催化剂体系存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包括催化量的含铅的无机助催化剂和 催化量的含钛的无机助催化剂。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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公开(公告)号：US6160154A
公开(公告)日：2000-12-12
申请号：US301698
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Marsha Mottel Grade , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Bruce Fletcher Johnson , Marsha Mottel Grade , Grigorii Lev Soloveichik , John Yaw Ofori , Eric James Pressman
CPC分类号： B01J31/2234 , B01J23/89 , B01J31/0231 , B01J31/0235 , B01J2231/321 , B01J2531/16 , B01J2531/38 , B01J2531/46 , B01J2531/54 , B01J2531/62 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing copper. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在包含催化量的含铜无机助催化剂的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触而使芳族羟基化合物羰基化的方法。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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公开(公告)号：US06441215B1
公开(公告)日：2002-08-27
申请号：US09681791
申请日：2001-06-06
申请人： Kirill Vladimirovich Shalyaev , Eric James Pressman , John Edward Hallgren , John Yaw Ofori , Jonathan Lloyd Male
发明人： Kirill Vladimirovich Shalyaev , Eric James Pressman , John Edward Hallgren , John Yaw Ofori , Jonathan Lloyd Male
IPC分类号： C07C6800
摘要： The present invention is directed to a method for reducing the percent decomposition of an aromatic carbonate in a first reaction mixture comprising the aromatic carbonate, the method comprising the step of adding at least one decomposition-reducing additive to the first reaction mixture, so as to produce a second reaction mixture in which the percent of the aromatic carbonate present in the second reaction mixture after a predetermined amount of time is greater than the percent of the aromatic carbonate that would be present in the first reaction mixture in the absence of adding the decomposition-reducing additive, after the same predetermined amount of time.
摘要翻译： 本发明涉及一种降低包含芳族碳酸酯的第一反应混合物中芳族碳酸酯分解百分比的方法，该方法包括向第一反应混合物中加入至少一种分解还原添加剂，以便于 产生第二反应混合物，其中在预定时间后存在于第二反应混合物中的芳族碳酸酯的百分比大于在不加入分解的情况下将存在于第一反应混合物中的芳族碳酸酯的百分比 在相同的预定量的时间之后。
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9.发明授权Method for preparing hydroquinones and dihydroxybiphenyl compounds from mixtures of bromophenols and benzoquinones 有权从溴酚和苯醌的混合物制备氢醌和二羟基联苯化合物的方法公开(公告)号：US06815565B2
公开(公告)日：2004-11-09
申请号：US10704002
申请日：2003-11-07
IPC分类号： C07C3924
摘要： A method is described for the simultaneous preparation of p-bromophenols and p-benzoquinones, intermediates useful in the preparation of hydroquinones and 4,4′-dihydroxybiphenyls, respectively. Hydroquinones and 4,4′-dihydroxybiphenyls are useful monomers for the preparation of a variety of polymers. The method also comprises reducing the p-benzoquinone to its corresponding hydroquinone in the presence of the p-bromophenol. Limiting the amount of HBr present in the reaction mixture was shown to control the amount of benzoquinone produced. The method also allows for the recycling of many of the reagents used, thereby reducing the cost of producing each monomer.
摘要翻译： 描述了同时制备对溴苯酚和对苯醌的方法，分别用于制备氢醌和4,4'-二羟基联苯的中间体。 氢醌和4,4'-二羟基联苯是用于制备各种聚合物的有用单体。 该方法还包括在对溴苯酚的存在下将对苯醌还原成其对应的氢醌。 显示出限制反应混合物中存在的HBr的量来控制所产生的苯醌的量。 该方法还允许循环使用许多试剂，从而降低生产每种单体的成本。
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10.发明授权Lead halophenoxides and carbonylation catalyst and method for preparing and employing them 失效铅卤化物和羰基化催化剂及其制备和应用的方法公开(公告)号：US06310229B1
公开(公告)日：2001-10-30
申请号：US09466030
申请日：1999-12-20
IPC分类号： C07F724
CPC分类号： B01J31/0214 , B01J31/2208 , B01J31/28 , B01J2531/824 , C07C37/66 , C07C39/44 , C07C68/005 , C07F7/003 , C07C69/96
摘要： Lead halophenoxides, especially bromophenoxides, are prepared by the reaction of lead(II) oxides with a hydroxyaromatic compound such as phenol and a chloride or bromide salt such as an alkali metal bromide, a tetraalkylammonium bromide or a bexaalkylguanidinium bromide. They are useful in catalyst compositions for the oxidative carbonylation of hydroxyaromatic compounds to diaryl carbonates.
摘要翻译： 铅卤化物，特别是溴苯氧化物，是通过氧化铅（II）与苯乙烯等羟基芳族化合物与溴化金属盐，溴化四烷基铵或溴化苄基溴化胍等氯化物或溴化物盐的反应来制备的。 它们可用于将羟基芳族化合物氧化羰基化成碳酸二芳基酯的催化剂组合物。
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