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1.发明授权Process to convert biomass and refuse derived fuel to ethers and/or alcohols 失效转化生物质和将衍生的燃料转化为醚和/或醇的方法
公开(公告)号：US5504259A
公开(公告)日：1996-04-02
申请号：US968588
申请日：1992-10-29
申请人： James P. Diebold , John W. Scahill , Helena L. Chum , Robert J. Evans , Bahman Rejai , Richard L. Bain , Ralph P. Overend
发明人： James P. Diebold , John W. Scahill , Helena L. Chum , Robert J. Evans , Bahman Rejai , Richard L. Bain , Ralph P. Overend
IPC分类号： C07C29/04 , C07C41/06 , C10B49/12 , C10B53/00 , C10B53/02 , C10B53/07 , C10G1/00 , C07C41/05 , C07C1/00
摘要： A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.
摘要翻译： 用于转化选自生物质和垃圾衍生燃料（RDF）的原料的方法，以提供重组汽油组分，其包含大量选自醚，醇或其混合物的材料，其包括：将所述 原料; 使用涡流反应器或其他方式对所述干燥原料进行快速热解; 使用沸石催化剂从所述热解产生的催化裂化蒸气; 冷凝任何芳族副产物馏分; 在冷凝后催化烷基化存在于所述蒸气中的任何苯; 将任何剩余的乙烯和丙烯催化低聚成高级烯烃; 将所述烯烃异构化成反应性异烯烃; 并使所述异烯烃与醇反应以形成醚或与水反应形成醇。
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2.发明授权Phenolic compounds containing/neutral fractions extract and products derived therefrom from fractionated fast-pyrolysis oils 失效含有/中性馏分的酚类化合物提取物和从分馏的快速裂解油衍生的产物
公开(公告)号：US5223601A
公开(公告)日：1993-06-29
申请号：US647020
申请日：1991-01-29
CPC分类号： C08G8/28 , C07C37/52 , C07C37/72 , C08G8/08 , C08L61/04 , C08L97/00 , Y10T428/31906 , Y10T428/3196
摘要： A process for preparing phenol-formaldehyde novolak resins and molding compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils. The fractionation consists of a neutralization stage which can be carried out with aqueous solutions of bases or appropriate bases in the dry state, followed by solvent extraction with an organic solvent having at least a moderate solubility parameter and good hydrogen bonding capacity.Phenolic compounds-containing/neutral fractions extracts obtained by fractionating fast-pyrolysis oils from a lignocellulosic material, is such that the oil is initially in the pH range of 2-4, being neutralized with an aqueous bicarbonate base, and extracted into a solvent having a solubility parameter of approximately 8.4-9.11 [cal/cm.sup.3 ].sup.1/2 with polar components in the 1.8-3.0 range and hydrogen bonding components in the 2-4.8 range and the recovery of the product extract from the solvent with no further purification being needed for use in adhesives and molding compounds.The product extract is characterized as being a mixture of very different compounds having a wide variety of chemical functionalities, including phenolic, carbonyl, aldehyde, methoxyl, vinyl and hydroxyl. The use of the product extract on phenol-formaldehyde thermosetting resins is shown to have advantages over the conventional phenol-formaldehyde resins.
摘要翻译： 制备苯酚 - 甲醛酚醛清漆树脂的方法和其中通常在所述树脂中含有的苯酚部分被从分馏快速热解油获得的酚/中性馏分提取物代替的成型组合物。 分馏由中和阶段组成，其可以在干燥状态下用碱或适当碱的水溶液进行，然后用至少具有中等溶解度参数和良好氢键能力的有机溶剂进行溶剂萃取。 通过从木质纤维素材料中分馏快速裂解油获得的含酚化合物/中性馏分提取物使得油最初处于2-4的pH范围内，用碳酸氢盐水溶液中和，并萃取到具有 在1.8-3.0范围内极性组分的溶解度参数为约8.4-9.11 [cal / cm3] 1/2，2-4.8范围内的氢键组分和不经进一步纯化从溶剂中回收产物提取物 需要用于粘合剂和模塑料。 产品提取物的特征在于具有多种化学官能度的非常不同的化合物的混合物，包括酚类，羰基，醛，甲氧基，乙烯基和羟基。 使用产品提取物对苯酚 - 甲醛热固性树脂显示出优于常规酚醛树脂的优点。
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3.发明授权Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials 失效衍生自通过生物质材料的快速热解制备的分馏的有机和含水冷凝物的Resole树脂产物
公开(公告)号：US5235021A
公开(公告)日：1993-08-10
申请号：US806897
申请日：1991-12-16
CPC分类号： C08G8/08 , C07C37/004 , C08G8/04 , C08G8/24 , Y10T428/3196
摘要： A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.
摘要翻译： 通过在使用载气将进料转移到反应器中以生产含酚/中性粒子的条件下，通过分解生物质材料的快速热解制备的有机和水性冷凝物，其中苯酚的一部分通常含有 所述树脂由通过分馏获得的酚/中性馏分提取物代替。
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公开(公告)号：US5413227A
公开(公告)日：1995-05-09
申请号：US956667
申请日：1992-10-05
申请人： James P. Diebold , John W. Scahill
发明人： James P. Diebold , John W. Scahill
CPC分类号： C10B49/20 , B01J19/2405 , B01J19/2465 , C10B49/12 , B01J2208/00 , B01J2219/00112 , B01J2219/00162 , Y02E50/14
摘要： An improved vortex reactor system for affecting fast pyrolysis of biomass and Refuse Derived Fuel (RDF) feed materials comprising: a vortex reactor having its axis vertically disposed in relation to a jet of a horizontally disposed steam ejector that impels feed materials from a feeder and solids from a recycle loop along with a motive gas into a top part of said reactor.
摘要翻译： 一种用于影响生物质和垃圾衍生燃料（RDF）进料的快速热解的改进的涡流反应器系统，包括：涡流反应器，其轴线相对于水平设置的蒸汽喷射器的射流垂直设置，其推动来自进料器和固体的进料 从循环回路与动力气体一起进入所述反应器的顶部。
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公开(公告)号：US4620795A
公开(公告)日：1986-11-04
申请号：US625327
申请日：1984-06-27
申请人： James P. Diebold , John W. Scahill
发明人： James P. Diebold , John W. Scahill
CPC分类号： B65D88/68
摘要： A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.
摘要翻译： 具有新颖附件的柔性鞭子或鞭子系统悬挂在料斗中，并且被引到料斗中的纤维状和不规则形状的颗粒上，以使颗粒流化并促进颗粒流过料斗。 本发明提供了基本上恒定的质量流率的微粒的流动并且使用最小的能量。
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公开(公告)号：US4764627A
公开(公告)日：1988-08-16
申请号：US34358
申请日：1987-04-06
申请人： James P. Diebold , Robert J. Evans
发明人： James P. Diebold , Robert J. Evans
IPC分类号： C07D307/36 , C07D307/06
CPC分类号： C07D307/36
摘要： A process of producing furan and derivatives thereof is disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.
摘要翻译： 公开了一种生产呋喃及其衍生物的方法。 该方法包括产生糠醛醛蒸汽，然后在有效使糠醛醛脱羰的温度和停留时间将这些蒸气通过沸石催化剂形成呋喃及其衍生物。 然后将所得的呋喃蒸汽和衍生物分离。 在优选形式中，在将生物质材料转化为液体和气体燃料的过程中产生糠醛醛蒸汽。
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公开(公告)号：US20110120312A1
公开(公告)日：2011-05-26
申请号：US12946696
申请日：2010-11-15
申请人： James P. Diebold , Arthur Lilley , Kingsbury Browne, III , Robb Ray Walt , Dustin Duncan , Michael Walker , John Steele , Michael Fields
发明人： James P. Diebold , Arthur Lilley , Kingsbury Browne, III , Robb Ray Walt , Dustin Duncan , Michael Walker , John Steele , Michael Fields
IPC分类号： B01D46/42
CPC分类号： C10J3/66 , B01D29/27 , B01D29/70 , B01D46/0072 , B01D46/0095 , C10J3/20 , C10J3/26 , C10J3/30 , C10J3/40 , C10J3/723 , C10J2200/09 , C10J2200/152 , C10J2300/0903 , C10J2300/0916 , C10J2300/092 , C10J2300/0946 , C10J2300/0956
摘要： A method and apparatus for removing fine particulate matter from a fluid stream without interrupting the overall process or flow. The flowing fluid inflates and expands the flexible filter, and particulate is deposited on the filter media while clean fluid is permitted to pass through the filter. This filter is cleaned when the fluid flow is stopped, the filter collapses, and a force is applied to distort the flexible filter media to dislodge the built-up filter cake. The dislodged filter cake falls to a location that allows undisrupted flow of the fluid after flow is restored. The shed particulate is removed to a bin for periodic collection. A plurality of filter cells can operate independently or in concert, in parallel, or in series to permit cleaning the filters without shutting off the overall fluid flow. The self-cleaning filter is low cost, has low power consumption, and exhibits low differential pressures.
摘要翻译： 一种用于从流体流中除去细颗粒物质而不中断整个过程或流动的方法和装置。 流动的流体膨胀和膨胀柔性过滤器，并且颗粒沉积在过滤介质上，同时允许清洁流体通过过滤器。 当流体流动停止时，该过滤器被清洁，过滤器塌陷，并且施加力以扭曲柔性过滤介质以移除积聚的滤饼。 移动的滤饼落在允许流体恢复后液体不间断流动的位置。 脱落的颗粒被移除到箱中以进行定期收集。 多个过滤器单元可以独立地或一致地并行地或串联操作，以允许清洁过滤器而不关闭整个流体流动。 自清洁过滤器成本低，功耗低，差压差。
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公开(公告)号：US4023354A
公开(公告)日：1977-05-17
申请号：US200247
申请日：1971-11-18
申请人： Ronald F. Vetter , James P. Diebold , George F. Sieg , Howard W. Gerrish, Jr. , Howard H. Payne , Elmer J. Rhyn , Irvin F. Witcosky
发明人： Ronald F. Vetter , James P. Diebold , George F. Sieg , Howard W. Gerrish, Jr. , Howard H. Payne , Elmer J. Rhyn , Irvin F. Witcosky
摘要： Slurried rocket propellants and a spinning rocket motor wherein the propents have viscosities which enable them to form central cores when spun in spinning rocket motors, the motor having a diaphragm-like base plate which assists in transferring forward momentum through the propellant.
摘要翻译： 制浆火箭推进剂和旋转火箭发动机，其中推进剂具有粘度，使得它们能够在纺丝火箭发动机中旋转时形成中心芯，该电动机具有有助于将推进动力传递通过推进剂的隔膜状基板。
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公开(公告)号：US4115999A
公开(公告)日：1978-09-26
申请号：US558194
申请日：1975-03-13
申请人： James P. Diebold
发明人： James P. Diebold
摘要： Thin pieces of high energy propellant are potted in a potting material suchs isocyanates cured hydroxy terminated polybutadiene, hydroxy terminated polybutadiene, polyurethane, polyester or polysulfide so that they will primarily end burn. The result is a composite structure that can be used to produce cool gases suitable for use in gas generator applications.
摘要翻译： 薄型高能推进剂被灌封在灌封材料中，例如异氰酸酯固化的羟基封端的聚丁二烯，羟基封端的聚丁二烯，聚氨酯，聚酯或多硫化物，使得它们将主要结束烧伤。 结果是可用于生产适用于气体发生器应用的冷气体的复合结构。
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公开(公告)号：US08529661B2
公开(公告)日：2013-09-10
申请号：US12946696
申请日：2010-11-15
申请人： James P. Diebold , Arthur Lilley , Kingsbury Browne, III , Robb Ray Walt , Dustin Duncan , Michael Walker , John Steele , Michael Fields
发明人： James P. Diebold , Arthur Lilley , Kingsbury Browne, III , Robb Ray Walt , Dustin Duncan , Michael Walker , John Steele , Michael Fields
IPC分类号： B01D46/00
CPC分类号： C10J3/66 , B01D29/27 , B01D29/70 , B01D46/0072 , B01D46/0095 , C10J3/20 , C10J3/26 , C10J3/30 , C10J3/40 , C10J3/723 , C10J2200/09 , C10J2200/152 , C10J2300/0903 , C10J2300/0916 , C10J2300/092 , C10J2300/0946 , C10J2300/0956
摘要： A method and apparatus for removing fine particulate matter from a fluid stream without interrupting the overall process or flow. The flowing fluid inflates and expands the flexible filter, and particulate is deposited on the filter media while clean fluid is permitted to pass through the filter. This filter is cleaned when the fluid flow is stopped, the filter collapses, and a force is applied to distort the flexible filter media to dislodge the built-up filter cake. The dislodged filter cake falls to a location that allows undisrupted flow of the fluid after flow is restored. The shed particulate is removed to a bin for periodic collection. A plurality of filter cells can operate independently or in concert, in parallel, or in series to permit cleaning the filters without shutting off the overall fluid flow. The self-cleaning filter is low cost, has low power consumption, and exhibits low differential pressures.
摘要翻译： 一种用于从流体流中除去细颗粒物质而不中断整个过程或流动的方法和装置。 流动的流体膨胀和膨胀柔性过滤器，并且颗粒沉积在过滤介质上，同时允许清洁流体通过过滤器。 当流体流动停止时，该过滤器被清洁，过滤器塌陷，并且施加力以扭曲柔性过滤介质以移除积聚的滤饼。 移动的滤饼落在允许流体恢复后液体不间断流动的位置。 脱落的颗粒被移除到箱中以进行定期收集。 多个过滤器单元可以独立地或一致地并行地或串联操作，以允许清洁过滤器而不关闭整个流体流动。 自清洁过滤器成本低，功耗低，差压差。
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