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公开(公告)号：US4442290A
公开(公告)日：1984-04-10
申请号：US362651
申请日：1982-03-29
IPC分类号： C07D239/38 , C07D403/12 , C07D413/12 , C07D413/14 , C07D417/12 , C07D421/12 , C07D487/04 , G03C7/392 , G03C8/00 , C07D403/06
CPC分类号： C07D403/12 , C07D239/38 , C07D413/12 , C07D413/14 , C07D417/12 , C07D421/12 , C07D487/04 , G03C7/39252 , G03C8/00
摘要： There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
摘要翻译： 描述了由式
表示的新化合物，其中R是硫或硒; X表示形成完成五或六元杂环部分的核所必需的非金属原子; R1是H或低级烷基; R2是H或可水解基团; 并且R 3是H，烷基或可水解基团。 这些化合物可用于照相应用，并且在用碱性处理组合物水溶液处理照相元件期间提供照相用材料的受控释放。 -
公开(公告)号：US4350754A
公开(公告)日：1982-09-21
申请号：US273039
申请日：1981-06-12
IPC分类号： G03C7/00 , C07D239/38 , C07D403/06 , C07D403/12 , C07D413/06 , C07D413/12 , C07D413/14 , C07D417/12 , C07D421/12 , C07D473/36 , C07D473/38 , G03C7/392 , G03C8/00 , G03C8/10 , G03C1/40 , G03C1/10 , G03C3/00 , G03C5/54
CPC分类号： C07D403/12 , C07D239/38 , C07D413/12 , C07D413/14 , C07D417/12 , C07D421/12 , C07D473/38 , G03C7/39252 , G03C8/00 , Y10S430/161
摘要： There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
摘要翻译： 描述了由式
表示的新化合物，其中R是硫或硒; X表示形成完成五或六元杂环部分的核所必需的非金属原子; R1是H或低级烷基; R2是H或可水解基团; 并且R 3是H，烷基或可水解基团。 这些化合物可用于照相应用，并且在用碱性处理组合物水溶液处理照相元件期间提供照相用材料的受控释放。 -
公开(公告)号：US4713313A
公开(公告)日：1987-12-15
申请号：US606350
申请日：1984-05-02
IPC分类号： C07D239/54 , C07D401/06 , C07D401/14 , C07D417/06 , C07D521/00 , C07F9/6512 , G03C8/36 , G03C5/54 , G03C5/38
CPC分类号： C07D239/54 , C07D231/12 , C07D233/56 , C07D249/08 , C07D401/06 , C07D401/14 , C07D417/06 , C07F9/65122 , G03C8/365
摘要： Compounds which include a quaternary group connected to a pyrimidine residue through a linkage are disclosed. These compounds are useful as silver halide solvents in photographic products, processes and compositions.
摘要翻译： 公开了包括通过连接与嘧啶残基连接的季基的化合物。 这些化合物可用作照相产品，方法和组合物中的卤化银溶剂。
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公开(公告)号：US4847383A
公开(公告)日：1989-07-11
申请号：US693025
申请日：1985-01-18
IPC分类号： C07D233/54 , C07D403/12 , G03C8/00
CPC分类号： C07D233/64 , C07D403/12 , G03C8/00
摘要： There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.
摘要翻译： 描述了利用在碱存在下释放照相试剂的化合物的新颖的照相产品和方法。 化合物包括咪唑封闭基团并在碱中裂解以释放照相试剂。 还描述了新化合物。
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公开(公告)号：US4526965A
公开(公告)日：1985-07-02
申请号：US533265
申请日：1983-09-16
IPC分类号： C07D239/54 , G03C1/34 , G03C7/392 , G03C8/00 , G03C1/10
CPC分类号： C07D239/54 , G03C1/346 , G03C7/39252 , G03C8/00
摘要： Novel compounds which release thio- or selenourea moieties or derivatives thereof upon contact with aqueous alkaline compositions and are therefore useful in photographic applications. The compounds include, in addition to the thio- or selenourea moiety, a uracil blocking moiety and an anion.
摘要翻译： 与水性碱性组合物接触时释放硫代或硒脲部分或其衍生物的新型化合物，因此可用于照相应用。 除了硫代或硒脲部分之外，化合物还包括尿嘧啶封闭部分和阴离子。
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公开(公告)号：US4503139A
公开(公告)日：1985-03-05
申请号：US492695
申请日：1983-05-09
IPC分类号： C07D233/64 , C07D233/00 , C07D233/54 , C07D233/60 , C07D233/61 , C07D257/00 , C07D403/12 , G03C7/00 , G03C7/305 , G03C8/00 , G03C8/08 , G03C5/54 , G03C1/10 , G03C1/30 , G03C1/40
CPC分类号： C07D233/64 , C07D403/12 , G03C8/00 , Y10S430/156 , Y10S430/158 , Y10S430/16 , Y10S430/161
摘要： There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.
摘要翻译： 描述了利用在碱存在下释放照相试剂的化合物的新颖的照相产品和方法。 化合物包括咪唑封闭基团并在碱中裂解以释放照相试剂。 还描述了新化合物。
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公开(公告)号：US5445917A
公开(公告)日：1995-08-29
申请号：US319925
申请日：1994-10-07
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Mark R. Mischke , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Mark R. Mischke , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
IPC分类号： B41M5/30 , B41M5/333 , C07C49/593 , G03C1/675 , G03C1/73 , G03F7/004 , G03C1/492 , G03C1/494 , G03C1/76
CPC分类号： B41M5/30 , C07C49/593 , G03C1/73 , G03F7/0045
摘要： Acid can be generated by exposing a superacid precursor to actinic radiation effective to generate superacid from the superacid precursor and heating the superacid in admixture with a secondary acid generator capable of undergoing thermal decomposition to produce a secondary acid. The superacid catalyzes decomposition of the secondary acid generator, thus increasing the quantity of strong acid present in the medium. The resultant secondary acid can be used to effect a color change in an acid-sensitive material, so providing an imaging process.
摘要翻译： 可以通过将超强酸前体暴露于有效地从超酸前体产生超酸的加强超酸以及能够进行热分解以产生二次酸的二次酸发生物的混合物来加热超酸来产生酸。 超酸催化二次酸发生器的分解，从而增加介质中存在的强酸的量。 所得到的二次酸可用于在酸敏感材料中进行颜色变化，从而提供成像过程。
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8.发明授权Squarylium compounds, and processes and intermediates for the synthesis of these compounds 失效方酸化合物，以及用于合成这些化合物的方法和中间体公开(公告)号：US06482950B1
公开(公告)日：2002-11-19
申请号：US08479077
申请日：1995-06-06
申请人： Paulina P. Garcia , John W. Lee , John L. Marshall , Donald A. McGowan , Anthony J. Puttick , Thomas K. Spencer , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
发明人： Paulina P. Garcia , John W. Lee , John L. Marshall , Donald A. McGowan , Anthony J. Puttick , Thomas K. Spencer , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
IPC分类号： C07D47100
CPC分类号： G11B7/247 , C07D309/34 , C07D335/02 , C07D335/06 , C07D345/00 , C09B23/0025 , C09B23/0066 , C09B57/007 , G03G5/0611 , G11B7/246
摘要： Squarylium compounds of the formula: wherein Q1 and Q2 are each independently a pyrylium, thiopyrylium, selenopyrylium, benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, and R1 and R2 are each independently an aliphatic or cycloaliphatic group, can be prepared by reacting a squaric acid derivative of the formula: with a compound of the formula Q2CH2R2 in the presence of a base. The derivatives of Formula II may be prepared by condensing a 2,3,4,4-tetrahalocyclobut-2-en-1-one with a compound of the formula Q1CH2R1 in the presence of a base to produce a compound of the formula: wherein Q1 and R1 are as defined above, and X represents chlorine or bromine, and hydrolyzing the compound of Formula III. Alternatively, the derivatives of Formula II may be prepared by reacting a diester, monoacid chloride monoester or diacid chloride of squaric acid with a compound of the formula Q1CH2R1 in the presence of a base, followed by hydrolysis of the resultant monoacid chloride or monoester derivative of the compound of Formula II to the parent compound.
摘要翻译： 下式的方酸化合物：其中Q1和Q2各自独立地是吡喃鎓，硫代吡喃鎓，硒代吡喃鎓，苯并吡喃鎓，苯并硫代吡喃鎓或苯并硒吡喃鎓核，R1和R2各自独立地是脂族或脂环族基团，可以通过将 式中：在碱的存在下使用式Q2CH2R2的化合物。 式II的衍生物可以通过在碱的存在下将2,3,4,4-四卤代环丁-2-烯-1-酮与式Q1CH2R1的化合物缩合来制备下式的化合物：其中 Q1和R1如上定义，X表示氯或溴，并水解式III化合物。 或者，式II的衍生物可以通过在碱的存在下使方酸的二酯，单酰氯单酯或二酸氯化物与式Q1CH2R1的化合物反应制备，然后水解所得的单酰氯或单酯衍生物 式II化合物与母体化合物。
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9.发明授权
公开(公告)号：US5977351A
公开(公告)日：1999-11-02
申请号：US65350
申请日：1993-05-20
申请人： Peter K. Chu , Serajul Haque , Anthony J. Puttick , Socorro M. Ramos , Robert P. Short , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
发明人： Peter K. Chu , Serajul Haque , Anthony J. Puttick , Socorro M. Ramos , Robert P. Short , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
IPC分类号： B41M5/26 , B41M5/385 , B41M5/392 , B41M5/40 , B41M5/46 , C09B57/00 , C09B57/02 , G11B7/244 , C07D345/00 , C07D311/04 , C07D335/04
CPC分类号： C09B57/007 , B41M5/465 , C09B57/02 , G11B7/244 , B41M5/26 , B41M5/3854 , B41M5/392
摘要： Dyes comprising an inner salt of a compound of the formula:Q.sup.1 =Z-Q.sup.2wherein:Q.sup.1 is a 4-(benz[b]-4H-pyrylium)methylidene, 4-(benz[b]-4H-thiopyrylium)methylidene or 4-(benz[b]-4H-selenopyrylium)methylidene grouping;Z is a 1,3-(2-hydroxy-4-oxo-2-cyclobutylidene) hydroxide or 1,3-(2-hydroxy-4,5-dioxo-2-cyclopentylidene) hydroxide ring; andQ.sup.2 is a 4-(benz[b]-4H-pyran-4-ylidene)methyl, 4-(benz[b]-4H-thiopyran-4-ylidene)methyl or 4-(benz[b]-4H-selenopyran-4-ylidene)methyl grouping;wherein at least one of the groupings Q.sup.1 and Q.sup.2 carries at its 2-position a substituent in which a non-aromatic carbon atom is bonded directly to the benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, subject to the proviso that if this 2-substituent contains an aromatic nucleus, this aromatic nucleus is not conjugated with the benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus to which it is attached, are useful as visible and near infra-red absorbers, having high extinction coefficients and improved solubility in polymeric media.
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10.发明授权Squarylium compounds, and processes and intermediates for the synthesis of these compounds 失效方酸化合物，以及用于合成这些化合物的方法和中间体
公开(公告)号：US5919950A
公开(公告)日：1999-07-06
申请号：US52212
申请日：1993-04-23
申请人： Paulina P. Garcia , John W. Lee , John L. Marshall , Donald A. McGowan , Anthony J. Puttick , Thomas K. Spencer , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
发明人： Paulina P. Garcia , John W. Lee , John L. Marshall , Donald A. McGowan , Anthony J. Puttick , Thomas K. Spencer , Stephen G. Stroud , Stephen J. Telfer , Michael J. Zuraw
IPC分类号： C07D309/32 , C07D309/34 , C07D335/02 , C07D335/06 , C07D345/00 , C07D421/10 , C09B23/01 , C09B57/00 , G03G5/06 , G11B7/246 , G11B7/247 , C07D335/00
CPC分类号： G11B7/247 , C07D309/34 , C07D335/02 , C07D335/06 , C07D345/00 , C09B23/0025 , C09B23/0066 , C09B57/007 , G03G5/0611 , G11B7/246
摘要： Squarylium compounds of the formula: ##STR1## wherein Q.sup.1 and Q.sup.2 are each independently a pyrylium, thiopyrylium, selenopyrylium, benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, and R.sup.1 and R.sup.2 are each independently an aliphatic or cycloaliphatic group, can be prepared by reacting a squaric acid derivative of the formula: ##STR2## with a compound of the formula Q.sup.2 CH.sub.2 R.sup.2 in the presence of a base.
摘要翻译： 下式的方酸化合物：其中Q1和Q2各自独立地是吡喃鎓，硫代吡喃鎓，硒代吡喃鎓，苯并吡喃鎓，苯并硫代吡喃鎓或苯并硒吡喃鎓核，R1和R2各自独立地是脂族或脂环族基团，可以通过将 式中：在碱的存在下使用式Q2CH2R2的化合物。
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