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公开(公告)号：US08680176B2
公开(公告)日：2014-03-25
申请号：US12047450
申请日：2008-03-13
CPC分类号： C08G18/8077 , B82Y30/00 , C08K9/10
摘要： The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.
摘要翻译： 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面，聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面，该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可用作许多潜在应用的活性官能团。
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公开(公告)号：US20080234406A1
公开(公告)日：2008-09-25
申请号：US12047450
申请日：2008-03-13
CPC分类号： C08G18/8077 , B82Y30/00 , C08K9/10
摘要： The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.
摘要翻译： 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面，聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面，该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可以用作许多潜在应用的活性官能团。
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3.发明申请Glycerol Ester-Free Functionalized Vegetable Oil Derivatives and Their Latex Compounds 失效甘油无酯官能化植物油衍生物及其胶乳化合物公开(公告)号：US20090143527A1
公开(公告)日：2009-06-04
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/32
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 （甲基）丙烯酸脂肪酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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4.发明授权Glycerol ester-free functionalized vegetable oil derivatives and their latex compounds 失效不含甘油酯的官能化植物油衍生物及其胶乳化合物公开(公告)号：US08450414B2
公开(公告)日：2013-05-28
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/22
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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公开(公告)号：US20100089287A1
公开(公告)日：2010-04-15
申请号：US12586739
申请日：2009-09-25
IPC分类号： C09J189/00 , C09J197/00
CPC分类号： C12Q1/6883 , C12Q2600/106 , C12Q2600/156
摘要： The present invention provides a soy protein-based adhesive composition and a process for making the composition that may be used in particleboards and similar wood composite systems and that is formed from an aqueous mixture of calcium oxide, pine oil, protein, lignin, and acid. The preferred protein is an enzymatically-modified soy protein and the preferred enzyme is urease.
摘要翻译： 本发明提供了一种大豆蛋白质粘合剂组合物和制备该组合物的方法，该组合物可用于刨花板和类似的木材复合体系，并且由氧化钙，松油，蛋白质，木质素和酸的水性混合物形成 。 优选的蛋白质是酶改性的大豆蛋白，优选的酶是脲酶。
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6.发明申请Glycerol ester-free functionalized vegetable oil derivatives and their latex compositions 审中-公开不含甘油酯的官能化植物油衍生物及其胶乳组成公开(公告)号：US20080183000A1
公开(公告)日：2008-07-31
申请号：US11699693
申请日：2007-01-30
IPC分类号： C07C237/02 , C11B1/10
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl(meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide(meth)acrylate monomer. The increased hydrophilicity of the fatty amide(meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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公开(公告)号：US07786194B2
公开(公告)日：2010-08-31
申请号：US10594470
申请日：2004-04-02
IPC分类号： C08L89/00 , C09J189/00
CPC分类号： A01G13/02 , A01N3/00 , A01N3/04 , C08F220/06 , C08F220/26 , C08F220/56 , C08F222/1006
摘要： Certain exemplary embodiments comprise a composition prepared from a Class 1 member, a Class 2 member, and a Class 3 member, said Class 1 member contributing approximately 0.1 percent to approximately 10 percent by dry weight of said composition, said Class 2 member contributing approximately 1 percent to approximately 10 percent by dry weight of said composition, and said Class 3 member contributing an amount up to a balance by dry weight of said composition.
摘要翻译： 某些示例性实施方案包括由1类成员，2类成员和3类成员制备的组合物，所述1类成员占所述组合物的干重约0.1％至约10％，所述2级成员贡献约1 百分比至所述组合物的干重约10％，并且所述3级构件通过所述组合物的干重贡献量达到平衡。
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公开(公告)号：US06790271B2
公开(公告)日：2004-09-14
申请号：US10193697
申请日：2002-07-11
IPC分类号： C08L8900
CPC分类号： C08L97/02 , C08L89/00 , C08L91/00 , C08L91/06 , C08L2666/02 , C09J189/00 , C08L2666/26
摘要： A soy protein based adhesive useful in particleboards and other composites is formed from a mixture of soy protein isolate, a polyol plasticizer and a vegetable oil derivative. The preferred plasticizer is glycerol and the preferred vegetable oil derivative is the maleinized methyl ester of tung oil.
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公开(公告)号：US07081159B2
公开(公告)日：2006-07-25
申请号：US11083118
申请日：2005-03-17
申请人： Shelby F. Thames , Boris G. Sankovich , Jeanne N. Shera , Robert B. Thompson , Sharathkumar K. Mendon , James M. Evans
发明人： Shelby F. Thames , Boris G. Sankovich , Jeanne N. Shera , Robert B. Thompson , Sharathkumar K. Mendon , James M. Evans
IPC分类号： C09J189/00
CPC分类号： C09J189/00 , B27N3/002 , C08L89/00 , C08L91/06 , C08L97/005 , C08L97/02 , C08L2666/02 , Y10T428/254 , C08L2666/26
摘要： An adhesive composition that can be used in particleboards and other composites is formed from an aqueous mixture of soy protein, zinc sulfate heptahydrate, calcium oxide, sodium benzoate, pine oil, wax emulsion and non-sulfonated kraft lignin. In a second embodiment the composition further includes an acid.
摘要翻译： 可用于刨花板和其它复合材料的粘合剂组合物由大豆蛋白，七水硫酸锌，氧化钙，苯甲酸钠，松油，蜡乳液和非磺化硫酸盐木质素的水性混合物形成。 在第二个实施方案中，组合物还包含酸。
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