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公开(公告)号：US08680176B2
公开(公告)日：2014-03-25
申请号：US12047450
申请日：2008-03-13
CPC分类号： C08G18/8077 , B82Y30/00 , C08K9/10
摘要： The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.
摘要翻译： 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面，聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面，该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可用作许多潜在应用的活性官能团。
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2.发明授权Glycerol ester-free functionalized vegetable oil derivatives and their latex compounds 失效不含甘油酯的官能化植物油衍生物及其胶乳化合物公开(公告)号：US08450414B2
公开(公告)日：2013-05-28
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/22
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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3.发明申请公开(公告)号：US20120097194A1
公开(公告)日：2012-04-26
申请号：US13004279
申请日：2011-01-11
摘要： Disclosed herein are materials including a polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a coating, a textile finish or a wax; a filler for such a polymeric material or a surface treatment, which includes an enzyme such as an esterase (e.g., a lipolytic enzyme, an organophosphorus compound degradation enzyme), wherein the enzyme decontaminates a chemical from the surface of the material. Also disclosed herein are methods of cleaning a surface of a material that comprises an enzyme.
摘要翻译： 本文公开了包括聚合材料如涂料，塑料，层压材料，复合材料，弹性体，粘合剂或密封剂的材料; 表面处理如涂层，纺织品或蜡; 用于这种聚合材料或表面处理的填料，其包括酶如酯酶（例如，脂解酶，有机磷化合物降解酶），其中酶从材料的表面去除化学物质。 本文还公开了清洁包含酶的材料的表面的方法。
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4.发明申请Visual Assays for Coatings Incorporating Bioactive Enzymes for Catalytic Functions 审中-公开用于催化功能的包含生物活性酶的涂料的视觉测定公开(公告)号：US20110250626A1
公开(公告)日：2011-10-13
申请号：US13085061
申请日：2011-04-12
CPC分类号： C09D189/00 , A01N63/02 , C08L89/00 , C09D5/14 , C09D5/1637 , C09D7/65 , C12Q1/34 , C12Q1/44 , C12Q1/61 , A01N37/46 , A01N25/10
摘要： Disclosed herein are materials such as a coating, comprising a lipolytic enzyme or organophosphrous compound degrading enzyme. Also disclosed herein are methods of visually detecting enzyme activity in a coating by contacting the coating with a substrate of an enzyme and a visual indicator that changes appearance upon production of a product of enzyme activity on a tack-free coating surface.
摘要翻译： 本文公开了包含脂肪分解酶或有机磷化合物降解酶的包衣的材料。 本文还公开了通过使涂层与酶的底物和在无粘性涂层表面产生酶活性产物时改变外观的视觉指示剂相接触来目视检测涂层中的酶活性的方法。
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公开(公告)号：US20100089287A1
公开(公告)日：2010-04-15
申请号：US12586739
申请日：2009-09-25
IPC分类号： C09J189/00 , C09J197/00
CPC分类号： C12Q1/6883 , C12Q2600/106 , C12Q2600/156
摘要： The present invention provides a soy protein-based adhesive composition and a process for making the composition that may be used in particleboards and similar wood composite systems and that is formed from an aqueous mixture of calcium oxide, pine oil, protein, lignin, and acid. The preferred protein is an enzymatically-modified soy protein and the preferred enzyme is urease.
摘要翻译： 本发明提供了一种大豆蛋白质粘合剂组合物和制备该组合物的方法，该组合物可用于刨花板和类似的木材复合体系，并且由氧化钙，松油，蛋白质，木质素和酸的水性混合物形成 。 优选的蛋白质是酶改性的大豆蛋白，优选的酶是脲酶。
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公开(公告)号：US07999030B2
公开(公告)日：2011-08-16
申请号：US11345653
申请日：2006-02-01
IPC分类号： C08L37/00
CPC分类号： C09D5/02 , C08H3/00 , C08L91/00 , C09D191/00
摘要： An ethylenically unsaturated vegetable oil is modified by the addition of an enophile or dienophile having an acid, ester or anhydride functionality. The modified vegetable oil is then reacted with a polyethylene glycol (PEG) derivative along with a functional vinyl monomer or a polyethylene glycol derivative that contains a vinyl functionality to form a vegetable oil derivative. The vegetable oil derivative is useful in forming latexes and coatings.
摘要翻译： 烯属不饱和植物油通过加入具有酸，酯或酸酐官能团的亲合子或亲二烯体来改变。 然后将改性植物油与聚乙二醇（PEG）衍生物一起与功能性乙烯基单体或含有乙烯基官能团的聚乙二醇衍生物反应形成植物油衍生物。 植物油衍生物可用于形成胶乳和涂料。
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公开(公告)号：US20080234406A1
公开(公告)日：2008-09-25
申请号：US12047450
申请日：2008-03-13
CPC分类号： C08G18/8077 , B82Y30/00 , C08K9/10
摘要： The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.
摘要翻译： 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面，聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面，该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可以用作许多潜在应用的活性官能团。
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8.发明申请Glycerol ester-free functionalized vegetable oil derivatives and their latex compositions 审中-公开不含甘油酯的官能化植物油衍生物及其胶乳组成公开(公告)号：US20080183000A1
公开(公告)日：2008-07-31
申请号：US11699693
申请日：2007-01-30
IPC分类号： C07C237/02 , C11B1/10
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl(meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide(meth)acrylate monomer. The increased hydrophilicity of the fatty amide(meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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9.发明申请Glycerol Ester-Free Functionalized Vegetable Oil Derivatives and Their Latex Compounds 失效甘油无酯官能化植物油衍生物及其胶乳化合物公开(公告)号：US20090143527A1
公开(公告)日：2009-06-04
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/32
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 （甲基）丙烯酸脂肪酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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10.发明授权Powder coatings produced with crosslinkers capable of curing at low temperatures and coated articles produced therefrom 失效由能够在低温下固化的交联剂生产的粉末涂料和由其制备的涂覆制品公开(公告)号：US06891012B2
公开(公告)日：2005-05-10
申请号：US10444579
申请日：2003-05-23
IPC分类号： C09D137/00 , C08G18/80 , C09D5/03 , C09D175/04
CPC分类号： C08G18/8093 , C08G2150/20 , Y10T428/31551
摘要： A solid isocyanate-based composition having a glass transition temperature of at least 30° C. is produced by at least partially blocking the isocyanate groups of a polyisocyanate with a compound corresponding to the specified Formula I. This blocked isocyanate composition is useful in the production of powder coatings which are capable of being cured at temperatures of from 80 to 220° C.
摘要翻译： 玻璃化转变温度至少为30℃的固体异氰酸酯基组合物通过至少部分地用对应于特定式I的化合物来阻断多异氰酸酯的异氰酸酯基来制备。该封闭的异氰酸酯组合物可用于生产 的粉末涂料，其能够在80-220℃的温度下固化。
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