Glycerol Ester-Free Functionalized Vegetable Oil Derivatives and Their Latex Compounds
    2.
    发明申请
    Glycerol Ester-Free Functionalized Vegetable Oil Derivatives and Their Latex Compounds 失效
    甘油无酯官能化植物油衍生物及其胶乳化合物

    公开(公告)号:US20090143527A1

    公开(公告)日:2009-06-04

    申请号:US12331115

    申请日:2008-12-09

    IPC分类号: C08F2/32

    摘要: The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.

    摘要翻译: 本发明涉及脂肪酰胺(甲基)丙烯酸酯单体,制备单体的方法和包含脂肪酰胺(甲基)丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与(甲基)丙烯酰氯或(甲基)丙烯酸反应形成脂肪酰胺(甲基)丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基(甲基)丙烯酸酯反应形成氨基甲酸酯 (甲基)丙烯酸脂肪酸酯单体。 脂肪酰胺(甲基)丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯,以增加单体和聚合物的长期稳定性。

    Glycerol ester-free functionalized vegetable oil derivatives and their latex compounds
    3.
    发明授权
    Glycerol ester-free functionalized vegetable oil derivatives and their latex compounds 失效
    不含甘油酯的官能化植物油衍生物及其胶乳化合物

    公开(公告)号:US08450414B2

    公开(公告)日:2013-05-28

    申请号:US12331115

    申请日:2008-12-09

    IPC分类号: C08F2/22

    摘要: The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.

    摘要翻译: 本发明涉及脂肪酰胺(甲基)丙烯酸酯单体,制备单体的方法和包含脂肪酰胺(甲基)丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与(甲基)丙烯酰氯或(甲基)丙烯酸反应形成脂肪酰胺(甲基)丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基(甲基)丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺(甲基)丙烯酸酯单体。 脂肪酰胺(甲基)丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯,以增加单体和聚合物的长期稳定性。

    Glycerol ester-free functionalized vegetable oil derivatives and their latex compositions
    4.
    发明申请
    Glycerol ester-free functionalized vegetable oil derivatives and their latex compositions 审中-公开
    不含甘油酯的官能化植物油衍生物及其胶乳组成

    公开(公告)号:US20080183000A1

    公开(公告)日:2008-07-31

    申请号:US11699693

    申请日:2007-01-30

    IPC分类号: C07C237/02 C11B1/10

    摘要: The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl(meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide(meth)acrylate monomer. The increased hydrophilicity of the fatty amide(meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.

    摘要翻译: 本发明涉及脂肪酰胺(甲基)丙烯酸酯单体,制备单体的方法和包含脂肪酰胺(甲基)丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与(甲基)丙烯酰氯或(甲基)丙烯酸反应形成脂肪酰胺(甲基)丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基(甲基)丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺(甲基)丙烯酸酯单体。 脂肪酰胺(甲基)丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯,以增加单体和聚合物的长期稳定性。

    Nanoencapsulation of isocyanates via aqueous media
    5.
    发明授权
    Nanoencapsulation of isocyanates via aqueous media 失效
    通过水性介质对异氰酸酯进行纳米封装

    公开(公告)号:US08680176B2

    公开(公告)日:2014-03-25

    申请号:US12047450

    申请日:2008-03-13

    IPC分类号: C08K9/00 C08G18/81

    摘要: The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.

    摘要翻译: 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面,聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面,该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可用作许多潜在应用的活性官能团。

    Nanoencapsulation of Isocyanates Via Aqueous Media
    6.
    发明申请
    Nanoencapsulation of Isocyanates Via Aqueous Media 失效
    通过水介质的异氰酸酯的纳米封装

    公开(公告)号:US20080234406A1

    公开(公告)日:2008-09-25

    申请号:US12047450

    申请日:2008-03-13

    IPC分类号: C08G18/81 C08K3/20

    摘要: The present invention provides a nanocapsule of a blocked isocyanate encapsulated within a polymeric nanosphere. In one aspect, the polymeric nanosphere is functionalized. Free isocyanate functionality is released upon thermal annealing or UV exposure of the nanospheres containing the blocked isocyanate. This present invention also provides a novel method for encapsulating isocyanates in aqueous media. In one aspect, the method comprises miniemulsion polymerization. The thermally or UV deblocked isocyanate can be used as an active functional group for many potential applications.

    摘要翻译: 本发明提供封装在聚合物纳米球内的封闭异氰酸酯的纳米胶囊。 在一个方面,聚合纳米球被官能化。 游离异氰酸酯官能度在含有封端异氰酸酯的纳米球的热退火或UV暴露时释放。 本发明还提供了一种用于将异氰酸酯包封在水性介质中的新方法。 一方面,该方法包括细乳液聚合。 热或UV去封端的异氰酸酯可以用作许多潜在应用的活性官能团。

    Latex compositions comprising functionalized vegetable oil derivatives
    7.
    发明授权
    Latex compositions comprising functionalized vegetable oil derivatives 失效
    包含官能化植物油衍生物的乳胶组合物

    公开(公告)号:US07999030B2

    公开(公告)日:2011-08-16

    申请号:US11345653

    申请日:2006-02-01

    IPC分类号: C08L37/00

    摘要: An ethylenically unsaturated vegetable oil is modified by the addition of an enophile or dienophile having an acid, ester or anhydride functionality. The modified vegetable oil is then reacted with a polyethylene glycol (PEG) derivative along with a functional vinyl monomer or a polyethylene glycol derivative that contains a vinyl functionality to form a vegetable oil derivative. The vegetable oil derivative is useful in forming latexes and coatings.

    摘要翻译: 烯属不饱和植物油通过加入具有酸,酯或酸酐官能团的亲合子或亲二烯体来改变。 然后将改性植物油与聚乙二醇(PEG)衍生物一起与功能性乙烯基单体或含有乙烯基官能团的聚乙二醇衍生物反应形成植物油衍生物。 植物油衍生物可用于形成胶乳和涂料。