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公开(公告)号：US5726240A
公开(公告)日：1998-03-10
申请号：US755925
申请日：1996-11-25
IPC分类号： C08K5/29 , C08G18/70 , C08G18/76 , C08K5/1515 , C08K3/00 , C07C249/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/7664 , C08G18/70
摘要： This invention relates to mixtures of polymethylene poly(phenylisocyanate) blends with epoxides. The addition of the epoxide stabilizes the reactivity of the polyisocyanate blends such that it is no longer dependent on the acidity. It is now possible to form polyurethanes from these mixtures based on polymethylene poly(phenylisocyanate) blends wherein less catalyst is necessary.
摘要翻译： 本发明涉及多亚甲基聚异氰酸苯酯与环氧化物的混合物。 加入环氧化物稳定了多异氰酸酯共混物的反应性，使得其不再依赖于酸度。 现在可以基于聚亚甲基聚（苯基异氰酸酯）共混物从这些混合物形成聚氨酯，其中需要较少的催化剂。
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2.发明授权Method of making a coated substrate with polyurethane/urea contact adhesive formulations and the coated substrate by this method 失效通过该方法制备具有聚氨酯/脲接触粘合剂制剂的涂布基材和涂布的基材的方法公开(公告)号：US06187892B1
公开(公告)日：2001-02-13
申请号：US08483349
申请日：1995-06-07
IPC分类号： C08G1848
CPC分类号： C09J175/12 , C08G18/482 , C08G18/5024 , Y02P20/582 , Y10S528/905 , Y10T428/31551
摘要： The present invention relates to a method of making a coated substrate that requires a polyurethane/urea contact adhesive, and the coated substrates produced by this method. This invention requires a) a polyisocyanate with a functionality of less than about 4, b) optionally, a polyol blend consisting of about 95 to 100% polyether polyols with molecular weights from about 1800 to 12000 and average functionality from about 1.5 to about 4 and up to about 5% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3, and c) polyethers having at least two isocyanate reactive groups and a molecular weight of from about 1800 to about 12000 and average functionality from about 1.5 to about 4 in which at least 50% of the isocyanate reactive groups are primary and/or secondary amino groups. The weight ratio of components b) to component c) ranges from about 95:5 to about 0:100, and the amounts of components a), b), and c) are such that the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 85:100 to about 115:100 and the sum of the urethane group content plus the urea group content is from about 1 to about 12%.
摘要翻译： 本发明涉及一种制备需要聚氨酯/尿素接触粘合剂的涂布基材和通过该方法制备的涂布基材的方法。 本发明要求a）具有小于约4的官能度的多异氰酸酯，b）任选地，由约95至100％的分子量为约1800至12000的聚醚多元醇和平均官能度为约1.5至约4的多元醇共混物和 高达约5％的分子量为约60至400且平均官能度为约1.5至约3的扩链剂，以及c）具有至少两个异氰酸酯反应性基团和分子量为约1800至约12000的聚醚和平均 约1.5至约4的官能度，其中至少50％的异氰酸酯反应性基团是伯和/或仲氨基。 组分b）与组分c）的重量比范围为约95:5至约0:100，并且组分a），b）和c）的量使得异氰酸酯基团与异氰酸酯反应性的当量比 基团为约85:100至约115:100，并且氨基甲酸酯基含量加上尿素基团含量的总和为约1至约12％。
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公开(公告)号：US06562932B1
公开(公告)日：2003-05-13
申请号：US09976397
申请日：2001-10-12
申请人： Peter H. Markusch , Robert L. Cline , Richard S. Pantone , Ralf Guether , Thomas L. Sekelik , Karl W. Haider
发明人： Peter H. Markusch , Robert L. Cline , Richard S. Pantone , Ralf Guether , Thomas L. Sekelik , Karl W. Haider
IPC分类号： C08G1810
CPC分类号： C08G18/758 , B32B17/1077 , C08G18/10 , C08G18/73 , C08G18/755 , C08G18/6674 , C08G18/6685
摘要： This invention relates to a process for the production of an optically clear, light-stable polyurethane-urea elastomer having an onset softening point of at least 130° C., processed at ambient temperature and casted in a mold at an isocyanate index of 95 to 120. This process comprises reacting: A) a liquid polyisocyanate or polyisocyanate prepolymer having an NCO group content of about 5 to about 50%, an average functionality of 2 to 3, a viscosity of less than 5,000 mPa.s at 25° C.; and B) an isocyanate-reactive component; in the presence of C) at least one organometallic catalyst. The present invention also relates to the optically clear, light-stable polyurethane-urea elastomers produced by this process.
摘要翻译： 本发明涉及一种生产具有至少130℃起始软化点的光学透明，轻质稳定的聚氨酯 - 脲弹性体的方法，在环境温度下加工并浇铸在异氰酸酯指数为95至 该方法包括使A）具有NCO基团含量为约5至约50％，平均官能度为2至3，25℃时粘度小于5,000mPa.s的液体多异氰酸酯或多异氰酸酯预聚物 ; 和B）异氰酸酯反应性组分; 在C）存在下至少有一种有机金属催化剂。 本发明还涉及通过该方法制备的光学透明的，轻质的聚氨酯 - 脲弹性体。
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4.发明授权
公开(公告)号：US5733966A
公开(公告)日：1998-03-31
申请号：US787066
申请日：1997-01-22
CPC分类号： C08G18/725 , C08G18/4812 , C09J175/08 , C08G2170/40 , Y02P20/582
摘要： The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.
摘要翻译： 本发明涉及高弹性聚氨酯接触粘合剂，用这些接触粘合剂涂覆基材的方法以及通过该方法生产的涂布基材。 本发明要求a）具有小于约4的官能度的多异氰酸酯和b）多元醇共混物，其包含1）约90至100％分子量为约1,800至12,000的聚醚，平均官能度为约1.5至约4，和2 ）至多约10％的分子量为约60至400且平均官能度为约1.5至约3的扩链剂。组分a）和b）的官能度和量使得交联之间的分子量为约7,000 至约16,000，异氰酸酯基与异氰酸酯反应性基团的当量比为约80:100至约120：100，氨基甲酸酯基含量为约1至约8％。 组分a）和b）中的至少一种优选具有大于约2.2的官能度。
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5.发明授权Removable polyurethane adhesives with improved temperature resistance properties 失效具有改善耐温性能的可拆卸聚氨酯胶粘剂
公开(公告)号：US6040028A
公开(公告)日：2000-03-21
申请号：US6129
申请日：1998-01-13
IPC分类号： C08G18/48 , C08G18/75 , C08L75/08 , C09J7/02 , C09J175/08
CPC分类号： C09J175/08 , C08G18/4812 , C08G18/758 , C09J7/0207 , C08G2170/40 , C08L75/08 , C09J2475/00 , Y02P20/582 , Y10T428/1476 , Y10T428/28 , Y10T428/2896
摘要： The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.
摘要翻译： 本发明涉及高弹性聚氨酯接触粘合剂，用这些接触粘合剂涂覆基材的方法以及通过该方法生产的涂布基材。 本发明要求a）具有小于约4的官能度的多异氰酸酯和b）多元醇共混物，其包含1）约90至100％分子量为约1,800至12,000的聚醚，平均官能度为约1.5至约4，和2 ）至多约10％的分子量为约60至400且平均官能度为约1.5至约3的扩链剂。组分a）和b）的官能度和量使得交联之间的分子量为约7,000 至约16,000，异氰酸酯基与异氰酸酯反应性基团的当量比为约80:100至约120：100，氨基甲酸酯基含量为约1至约8％。 组分a）和b）中的至少一种优选具有大于约2.2的官能度。
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公开(公告)号：US6140381A
公开(公告)日：2000-10-31
申请号：US326831
申请日：1999-06-07
CPC分类号： C08G18/242 , C08G18/7664 , C08G18/8019
摘要： This invention relates to a process for the production of a polyurethane backing and air frothed foam on a substrate comprising the steps of a) mixing a polyisocyanate and a polyol blend in the presence of a catalyst to form a reaction mixture, b) applying the reaction mixture to a substrate, and c) curing the reaction mixture to form a polyurethane backing an/or an air frothed foam on the substrate. Suitable catalyst compositions for the present invention include those corresponding to the formula: ##STR1## wherein: each R: independently represents a linear or branched C.sub.1 to C.sub.24 (preferably from 5 to 16 carbon atoms and most preferably from 8 to 12 carbon atoms) alkyl group, or a cyclic group containing from 4 to 24 carbon atoms (preferably from 5 to 16 carbon atoms and most preferably from 8 to 12 carbon atoms).
摘要翻译： 本发明涉及在基材上生产聚氨酯背衬和空气起沫泡沫的方法，包括以下步骤：a）在催化剂存在下混合多异氰酸酯和多元醇共混物以形成反应混合物，b） 混合物到基材中，和c）固化反应混合物以在基材上形成/或空气泡沫的聚氨酯背衬。 适用于本发明的催化剂组合物包括对应于下式的那些：其中：每个R 3独立地表示直链或支链C 1 -C 24（优选5至16个碳原子，最优选8至12个碳原子）烷基，或 含有4至24个碳原子（优选5至16个碳原子，最优选8至12个碳原子）的环状基团。
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公开(公告)号：US06617412B2
公开(公告)日：2003-09-09
申请号：US09976610
申请日：2001-10-12
申请人： Peter H. Markusch , Robert L. Cline
发明人： Peter H. Markusch , Robert L. Cline
IPC分类号： C08G1840
CPC分类号： C08G18/3206 , C05G3/0023 , C05G3/0029 , C08G18/48
摘要： This invention relates to fertilizer encapsulation with polyurethanes wherein the isocyanate-reactive composition contains sulfur. The process of the present invention comprises applying a polyisocyanate composition to fertilizer particles, applying an isocyanate-reactive composition which contains sulfur to the polyisocyanate coated fertilizer particles, or applying an isocyanate-reactive composition which contains sulfur to fertilizer particles and then applying a polyisocyanate composition to the isocyanate-reactive coated fertilizer particles, and repeating these steps as necessary to form sulfur containing polyurethane encapsulated fertilizer particles.
摘要翻译： 本发明涉及具有聚氨酯的肥料封装，其中异氰酸酯反应性组合物含有硫。 本发明的方法包括将多异氰酸酯组合物施加到肥料颗粒上，将含有硫的异氰酸酯反应性组合物施加到多异氰酸酯涂覆的肥料颗粒上，或将含有硫的异氰酸酯反应性组合物施用于肥料颗粒，然后施加多异氰酸酯组合物 涉及异氰酸酯反应性包被的肥料颗粒，并根据需要重复这些步骤以形成含硫聚氨酯包封的肥料颗粒。
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8.发明授权Process for the production of polyurea encapsulated fertilizer particles and the encapsulated fertilizer particles produced by this process 失效用于生产聚脲包封的肥料颗粒和通过该方法生产的包封的肥料颗粒的方法
公开(公告)号：US5851261A
公开(公告)日：1998-12-22
申请号：US777426
申请日：1996-12-30
申请人： Peter H. Markusch , Robert L. Cline
发明人： Peter H. Markusch , Robert L. Cline
CPC分类号： C08G18/5024 , C05G3/0029
摘要： This invention relates to a process for the production of polyurea encapsulated fertilizer particles. These are produced by applying an isocyanate-reactive component which contains at least two amine groups to fertilizer particles to form amine coated particles, and applying a polyisocyanate component to the amine coated particles to form polyurea coated particles. These steps may optionally be repeated in successive order. The resultant polyurea encapsulated fertilizer particles contain from about 0.5 to 15% by weight of polyurea, based on the total weight of the encapsulated fertilizer particles. Instead of using an amine group containing isocyanate-reactive component, water can be applied first.
摘要翻译： 本发明涉及一种生产聚脲包封肥料颗粒的方法。 这些是通过将含有至少两个胺基的异氰酸酯反应性组分施用于肥料颗粒以形成胺包被的颗粒并将多异氰酸酯组分施加到胺涂覆的颗粒上以形成聚脲涂覆的颗粒来制备的。 这些步骤可以可选地以连续的顺序重复。 基于所包封的肥料颗粒的总重量，所得聚脲包封的肥料颗粒含有约0.5至15重量％的聚脲。 代替使用含有异氰酸酯反应性组分的胺基，可以首先施加水。
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公开(公告)号：US08340990B2
公开(公告)日：2012-12-25
申请号：US12219437
申请日：2008-07-22
IPC分类号： G06Q10/00
CPC分类号： G06Q10/08 , G06Q10/06315 , G06Q50/28
摘要： A method for supply chain design may include identifying nodes, links connecting the nodes, and replenishment strategies for moving materials along the links, in a supply chain. The method may also include determining a value indicative of the complexity of the supply chain based on a characteristic of the nodes, links, and replenishment strategies. The method may also include identifying whether core competencies of the nodes are underutilized. The method may also include reducing the complexity of the supply chain to increase utilization of the core competencies of the nodes.
摘要翻译： 供应链设计的方法可以包括识别节点，连接节点的链接以及在供应链中沿着链接移动材料的补货策略。 该方法还可以包括基于节点，链接和补充策略的特征来确定指示供应链的复杂性的值。 该方法还可以包括识别节点的核心竞争力是否未被充分利用。 该方法还可以包括降低供应链的复杂性以增加节点的核心竞争力的利用。
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公开(公告)号：US20100023363A1
公开(公告)日：2010-01-28
申请号：US12219437
申请日：2008-07-22
IPC分类号： G06Q10/00
CPC分类号： G06Q10/08 , G06Q10/06315 , G06Q50/28
摘要： A method for supply chain design may include identifying nodes, links connecting the nodes, and replenishment strategies for moving materials along the links, in a supply chain. The method may also include determining a value indicative of the complexity of the supply chain based on a characteristic of the nodes, links, and replenishment strategies. The method may also include identifying whether core competencies of the nodes are underutilized. The method may also include reducing the complexity of the supply chain to increase utilization of the core competencies of the nodes.
摘要翻译： 供应链设计的方法可以包括识别节点，连接节点的链接以及在供应链中沿着链接移动材料的补货策略。 该方法还可以包括基于节点，链接和补充策略的特征来确定指示供应链的复杂性的值。 该方法还可以包括识别节点的核心竞争力是否未被充分利用。 该方法还可以包括降低供应链的复杂性以增加节点的核心竞争力的利用。
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