POLY(CARBONATE-CO-UREA) COPOLYMERS AND MELT TRANSESTERIFICATION METHOD OF PREPARING THESE COPOLYMERS
    1.
    发明申请
    POLY(CARBONATE-CO-UREA) COPOLYMERS AND MELT TRANSESTERIFICATION METHOD OF PREPARING THESE COPOLYMERS 失效
    聚(碳酸酯 - 共聚物)共聚物和制备这些共聚物的熔融纺丝方法

    公开(公告)号:US20080275209A1

    公开(公告)日:2008-11-06

    申请号:US11743761

    申请日:2007-05-03

    CPC分类号: C08G64/12 C08G63/64 C08G71/02

    摘要: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.

    摘要翻译: 本文公开了一种制备聚(碳酸酯 - 共 - 尿素)共聚物的方法,其包括在熔体中反应:(a)包含二羟基化合物的二羟基反应组分,(b)包含碳酸二芳基酯的碳酸二芳酯反应组分,(c )在至少部分反应期间(d)酯交换催化剂存在下包含脲化合物的脲反应组分,并除去酚类副产物以产生聚(碳酸酯 - 共 - 尿素)共聚物,其中脲和二羟基化合物 以摩尔比(尿素化合物的总摩尔数)/((脲化合物的总摩尔数)+(二羟基化合物的总摩尔数))小于或等于0.5。

    Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers
    5.
    发明授权
    Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers 失效
    聚(碳酸酯 - 共 - 尿素)共聚物和制备这些共聚物的熔融酯交换法

    公开(公告)号:US07666977B2

    公开(公告)日:2010-02-23

    申请号:US11743761

    申请日:2007-05-03

    IPC分类号: C08G73/00 C08G64/00

    CPC分类号: C08G64/12 C08G63/64 C08G71/02

    摘要: Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.

    摘要翻译: 本文公开了一种制备聚(碳酸酯 - 共 - 尿素)共聚物的方法,其包括在熔体中反应:(a)包含二羟基化合物的二羟基反应组分,(b)包含碳酸二芳基酯的碳酸二芳酯反应组分,(c )在至少部分反应期间(d)酯交换催化剂存在下包含脲化合物的脲反应组分,并除去酚类副产物以产生聚(碳酸酯 - 共 - 尿素)共聚物,其中脲和二羟基化合物 以摩尔比(尿素化合物的总摩尔数)/((脲化合物的总摩尔数)+(二羟基化合物的总摩尔数))小于或等于0.5。

    Methods of polymer preparation using polycyclic dihydroxy compounds
    7.
    发明授权
    Methods of polymer preparation using polycyclic dihydroxy compounds 有权
    使用多环二羟基化合物制备聚合物的方法

    公开(公告)号:US07381786B2

    公开(公告)日:2008-06-03

    申请号:US11693314

    申请日:2007-03-29

    IPC分类号: C08G63/02 C07C69/76 C07C67/00

    摘要: Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.

    摘要翻译: 本文公开了一种制备包含衍生自具有式(I)的多环二羟基化合物的结构单元的聚合物的方法,其中R 1选自氰基官能团,硝基官能团,脂族基团 具有1至10个碳的官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团,硝基官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时,每个R 3和R 4可以相同或不同,并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳,“n”是0至4的整数,“m”是0至4的整数。该方法包括使式(I)的多环二羟基化合物进行聚合。

    Polymers, polymer compositions and method of preparation
    8.
    发明授权
    Polymers, polymer compositions and method of preparation 有权
    聚合物,聚合物组合物和制备方法

    公开(公告)号:US07326763B2

    公开(公告)日:2008-02-05

    申请号:US11261279

    申请日:2005-10-28

    IPC分类号: C08G63/02

    摘要: A polymer comprises structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and R3 and R4 are independently at each occurrence a hydrogen, an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons.

    摘要翻译: 聚合物包含衍生自式(I)的多环二羟基化合物的结构单元,其中R 1选自氰基官能团,硝基官能团,具有1至10个碳的脂族官能团, 具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团,硝基官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; R 3和R 4在每次出现时独立地为氢,具有1至10个碳的脂族官能团或具有3至10个碳的脂环族官能团。