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    Polymer modified bitumen composition to be used in asphalt binders or roofing compositions
    1.
    发明申请
    Polymer modified bitumen composition to be used in asphalt binders or roofing compositions 审中-公开
    用于沥青结合料或屋顶组合物的聚合物改性沥青组合物

    公开(公告)号：US20090105376A1

    公开(公告)日：2009-04-23

    申请号：US11578260

    申请日：2005-04-11

    申请人： Jan Korenstra ,  Willem Vonk ,  Cornelis Martinus van Dijk ,  Erik Trommelen ,  Duco Bodt

    发明人： Jan Korenstra ,  Willem Vonk ,  Cornelis Martinus van Dijk ,  Erik Trommelen ,  Duco Bodt

    IPC分类号： C08L95/00

    CPC分类号： C08L95/00 ,  C08F297/04 ,  C08L53/02 ,  C08L2205/02 ,  C08L2666/24 ,  C08L53/00

    摘要： A polymer modified bitumen composition, comprising 80 to 98.5 parts by weight of a bitumen and 20 to 1.5 parts by weight of a polymer composition, wherein the polymer composition comprises:(i) from 5 to 70% by weight of a linear styrenic block copolymer (SBC1) comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and having an apparent molecular weight greater than 250,000 and/or a radial styrenic block copolymer (SBC2) having three or more polymer arms attached to the residue of a cross-linking agent or multifunctional compound, comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and wherein the polymer arms have an average apparent molecular weight greater than 125,000 and (ii) from 95 to 30% by weight of an elastomer (EI) having an apparent molecular weight in the range of 120,000 to 250,000; their use as asphalt binder or as bituminous roofing composition, hot mix asphalt compositions comprising aggregate material and pavements comprising the compacted hot mix asphalt, easy welding roll roofing membranes, comprising said bitumen roofing composition, and specific block copolymers to be used in said bitumen composition.

    摘要翻译： 一种聚合物改性沥青组合物，其包含80至98.5重量份的沥青和20至1.5重量份的聚合物组合物，其中所述聚合物组合物包含：（i）5至70重量％的线性苯乙烯系嵌段共聚物 （SBC1），其包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物制成的表观分子量大于250,000的聚合物嵌段和/或径向苯乙烯嵌段共聚物（SBC2） 具有连接到交联剂或多官能化合物的残基上的三个或更多个聚合物臂，其包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物制成的聚合物嵌段， 聚合物臂具有大于125,000的平均表观分子量和（ii）95至30重量％的具有表观摩尔量的弹性体（EI） 体重在12万到25万之间; 它们用作沥青粘合剂或沥青屋面组合物，包含聚集材料的热混合沥青组合物和包含压实的热拌沥青的路面，容易的焊接辊屋顶膜，包括所述沥青屋顶组合物和用于所述沥青组合物中的特定嵌段共聚物 。

    Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer
    4.
    发明授权
    Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer 失效
    具有高分子量二嵌段共聚物的高分子量嵌段共聚物的压敏粘合剂

    公开(公告)号：US07297741B2

    公开(公告)日：2007-11-20

    申请号：US10880055

    申请日：2004-06-29

    申请人： David J. St. Clair ,  Willem C. Vonk ,  Cornelis Martinus van Dijk

    发明人： David J. St. Clair ,  Willem C. Vonk ,  Cornelis Martinus van Dijk

    IPC分类号： C08L53/02

    CPC分类号： C08F297/04 ,  C08F297/044 ,  C08L95/00 ,  C08L2666/02 ,  C08L2666/24 ,  C09J153/02 ,  Y10T428/31917 ,  Y10T428/3192 ,  C08L53/00

    摘要： The present invention relates to pressure sensitive adhesive compositions prepared from novel anionic block copolymers of aromatic vinyl compounds and conjugated dienes. The block copolymers are a mixture of a high molecular weight linear and/or radial block copolymer component (SBC1 and/or SBC2), and a diblock copolymer component (D1). The block copolymer may be combined with other block copolymers, tackifying resins, oils and other components to form the adhesives of the present invention. The pressure sensitive adhesives of the present invention maintain their performance at elevated temperatures and fail cohesively making them particularly useful for die-cuttable label applications. The pressure sensitive adhesives compositions may also comprise ester plasticizers typically used for PVC and thus make adhesives particularly suitable for PVC film labels and decals.

    摘要翻译： 本发明涉及由芳族乙烯基化合物和共轭二烯的新型阴离子嵌段共聚物制备的压敏粘合剂组合物。 嵌段共聚物是高分子量线性和/或径向嵌段共聚物组分（SBC1和/或SBC2）和二嵌段共聚物组分（D1）的混合物。 嵌段共聚物可以与其它嵌段共聚物，增粘树脂，油和其它组分组合以形成本发明的粘合剂。 本发明的压敏粘合剂在升高的温度下保持它们的性能并且内聚性使其对于可切割的标签应用特别有用。 压敏粘合剂组合物还可以包含通常用于PVC的酯增塑剂，因此使粘合剂特别适用于PVC膜标签和贴花。

    Process for making a coupled low vinyl block copolymer composition and the resulting composition
    5.
    发明申请
    Process for making a coupled low vinyl block copolymer composition and the resulting composition 审中-公开
    制备低乙烯基嵌段共聚物组合物和所得组合物的方法

    公开(公告)号：US20070185274A1

    公开(公告)日：2007-08-09

    申请号：US11699692

    申请日：2007-01-30

    申请人： Cornelis Martinus van Dijk ,  Mark Hageman

    发明人： Cornelis Martinus van Dijk ,  Mark Hageman

    IPC分类号： C08F297/02

    CPC分类号： C08F297/04 ,  C08F297/044 ,  C08L53/02 ,  C08L2666/02

    摘要： This invention relates to a process for making a coupled, low vinyl block copolymer composition, comprising the steps of:a) reacting a living lithium-terminated polymer having the formula P-Li, where P is a copolymer chain having at least one polymer block A composed of one or more mono alkenyl arenes having 8 to 18 carbon atoms and at least one polymer block B composed of one or more conjugated dienes having 4 to 12 carbon atoms, with an alkyltrialkoxysilane coupling agent having the formula R—Si—(OR′)3, where R is selected from branched alkyl radicals having from 3 to 12 carbon atoms, and R′ is a methyl group, and where the molar ratio of Si to Li is between 0.3 and 1.0, thereby forming a coupled block copolymer composition; andb) recovering the resulting coupled, low vinyl block copolymer composition.The invention also relates to the resulting coupled, low vinyl block copolymer compositions that are free from bromine-containing contaminants.

    摘要翻译： 本发明涉及一种制备偶联的低乙烯基嵌段共聚物组合物的方法，包括以下步骤：a）使具有式P-Li的活性锂封端的聚合物反应，其中P是具有至少一个聚合物嵌段的共聚物链 A由具有8至18个碳原子的一个或多个单链烯基芳烃和由一个或多个具有4至12个碳原子的共轭二烯组成的至少一个聚合物嵌段B与具有式R-Si-的烷基三烷氧基硅烷偶联剂 '）3，其中R选自具有3至12个碳原子的支链烷基，R'是甲基，并且其中Si与Li的摩尔比在0.3和1.0之间， 从而形成偶联的嵌段共聚物组合物; 和b）回收所得的偶联的低乙烯基嵌段共聚物组合物。 本发明还涉及所得的不含溴的污染物的偶联的低乙烯基嵌段共聚物组合物。