公开(公告)号：US20090105376A1

公开(公告)日：2009-04-23

申请号：US11578260

申请日：2005-04-11

申请人： Jan Korenstra ,  Willem Vonk ,  Cornelis Martinus van Dijk ,  Erik Trommelen ,  Duco Bodt

发明人： Jan Korenstra ,  Willem Vonk ,  Cornelis Martinus van Dijk ,  Erik Trommelen ,  Duco Bodt

IPC分类号： C08L95/00

CPC分类号： C08L95/00 ,  C08F297/04 ,  C08L53/02 ,  C08L2205/02 ,  C08L2666/24 ,  C08L53/00

摘要： A polymer modified bitumen composition, comprising 80 to 98.5 parts by weight of a bitumen and 20 to 1.5 parts by weight of a polymer composition, wherein the polymer composition comprises:(i) from 5 to 70% by weight of a linear styrenic block copolymer (SBC1) comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and having an apparent molecular weight greater than 250,000 and/or a radial styrenic block copolymer (SBC2) having three or more polymer arms attached to the residue of a cross-linking agent or multifunctional compound, comprising at least two polymer blocks each substantially made of an aromatic vinyl compound and at least one polymer block substantially made of a conjugated diene compound and wherein the polymer arms have an average apparent molecular weight greater than 125,000 and (ii) from 95 to 30% by weight of an elastomer (EI) having an apparent molecular weight in the range of 120,000 to 250,000; their use as asphalt binder or as bituminous roofing composition, hot mix asphalt compositions comprising aggregate material and pavements comprising the compacted hot mix asphalt, easy welding roll roofing membranes, comprising said bitumen roofing composition, and specific block copolymers to be used in said bitumen composition.

摘要翻译： 一种聚合物改性沥青组合物，其包含80至98.5重量份的沥青和20至1.5重量份的聚合物组合物，其中所述聚合物组合物包含：（i）5至70重量％的线性苯乙烯系嵌段共聚物 （SBC1），其包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物制成的表观分子量大于250,000的聚合物嵌段和/或径向苯乙烯嵌段共聚物（SBC2） 具有连接到交联剂或多官能化合物的残基上的三个或更多个聚合物臂，其包含至少两个基本上由芳族乙烯基化合物制成的聚合物嵌段和至少一个基本上由共轭二烯化合物制成的聚合物嵌段， 聚合物臂具有大于125,000的平均表观分子量和（ii）95至30重量％的具有表观摩尔量的弹性体（EI） 体重在12万到25万之间; 它们用作沥青粘合剂或沥青屋面组合物，包含聚集材料的热混合沥青组合物和包含压实的热拌沥青的路面，容易的焊接辊屋顶膜，包括所述沥青屋顶组合物和用于所述沥青组合物中的特定嵌段共聚物 。

公开(公告)号：US20050222305A1

公开(公告)日：2005-10-06

申请号：US10508908

申请日：2003-03-24

申请人： Erik Trommelen ,  Martin van Dijk

发明人： Erik Trommelen ,  Martin van Dijk

IPC分类号： E04D5/02 ,  C08F297/04 ,  C08L53/02 ,  C08L95/00 ,  C09D153/02 ,  C09J153/02 ,  C08J3/00

CPC分类号： C08L95/00 ,  C08F297/04 ,  C08L53/02 ,  C08L53/00

摘要： A bituminous composition which comprises a bituminous component and a block copolymer which comprises at least two blocks of a conjugated diene and at least two blocks of a monovinylaromatic hydrocarbon, being of the general formula: S1—B1—S2—B2 wherein B1 is a block of polymerized conjugated diene comprising at least 50 mole % isoprene having an apparent molecular weight of from 180,000 to 400,000, S1 and S2 are blocks of polymerized monovinylaromatic hydrocarbon having a weight average molecular weight of 12,000 to 40,000, and B2 is a block of polymerized conjugated diene comprising at least 50 mole % isoprene having an apparent molecular weight of from 15,000 to 60,000; wherein the weight ratio W of B1 over B2 is in the range of 3.0 to 12.0; and wherein the content of polymerized monovinylaromatic hydrocarbon is in the range from 10 to 35 wt. %.

摘要翻译： 一种沥青组合物，其包含沥青组分和嵌段共聚物，所述嵌段共聚物包含至少两个共轭二烯嵌段和至少两个单乙烯基芳烃嵌段，其具有以下通式：S 1 -B 其中B 1是包含至少50摩尔％的聚合共轭二烯的嵌段， 表观分子量为180,000至400,000的异戊二烯，S 1和S 2是重均分子量为12,000至40,000的聚合单乙烯基芳烃的嵌段，B 2是包含表观分子量为15,000至60,000的至少50摩尔％异戊二烯的聚合共轭二烯嵌段; 其中B 1和B 2之间的重量比W在3.0至12.0的范围内; 并且其中聚合的单乙烯基芳族烃的含量为10-35wt。 ％。

公开(公告)号：US20060106138A1

公开(公告)日：2006-05-18

申请号：US10538939

申请日：2003-12-15

申请人： Erik Trommelen ,  Jacques Damen ,  Jeffrey Van Hek

发明人： Erik Trommelen ,  Jacques Damen ,  Jeffrey Van Hek

IPC分类号： C08L95/00

CPC分类号： E04D5/02 ,  C08L53/02 ,  C08L95/00 ,  C08L2666/24

摘要： The invention relates to thin block copolymer modified bituminous felts, comprising at least one block copolymer, comprising at least two poly(vinyl aromatic) blocks and at least one poly(conjugated diene) block, in a weight proportion of from more than 20 to 50 wt %, relative to the weight of the block copolymer and bitumen and optionally at least one filler, in a weight proportion in the range of from 0 to 50 wt %, relative to the weight of the complete composition and wherein the respective weight proportions of block copolymer, bitumen and filler add up to 100%. The invention also relates to the block copolymer modified bituminous composition, and the use thereof in bituminous pavements, coatings and sealants.

摘要翻译： 本发明涉及薄嵌段共聚物改性沥青毡，其包含至少一种嵌段共聚物，其包含至少两个聚（乙烯基芳族化合物）嵌段和至少一种聚（共轭二烯）嵌段，其重量比例大于20至50 wt％，相对于嵌段共聚物和沥青以及任选的至少一种填料的重量，相对于完整组合物的重量，重量比为0-50wt％，并且其中各自的重量比例 嵌段共聚物，沥青和填料总计可达100％。 本发明还涉及嵌段共聚物改性沥青组合物及其在沥青路面，涂料和密封剂中的用途。

公开(公告)号：US20050187327A1

公开(公告)日：2005-08-25

申请号：US11062000

申请日：2005-02-18

申请人： Erik Trommelen ,  Jacques Damen

发明人： Erik Trommelen ,  Jacques Damen

IPC分类号： C08K3/00 ,  C08L1/02 ,  C08L53/02 ,  C08L57/02 ,  C08L91/00 ,  C08L95/00 ,  E04D5/02 ,  C08K3/26 ,  C08K3/04

CPC分类号： E04D5/02 ,  C08L53/02 ,  C08L95/00 ,  C08L2666/24

摘要： The invention provides a colorable roofing membrane comprising fibrous material and a non-bituminous binder comprising: i. a bitumen-like compound having a penetration value of at least 30 units at 25° C., and comprising at least a hydrogenated petroleum resin (a) or comprising at least a hydrogenated petroleum resin (a) and an oil (b), ii. from 10 to 25 parts by weight on 100 parts of the bitumen-like compound of a hydrogenated styrenic block copolymer (c) of formula A-C-A or (A-C′)n—X, wherein A stands for a polymer block of a vinyl aromatic monomer, X stands for a coupling moiety, n stands for an integer of 2 to 20, and C respectively C′ stand for a polymer block of a conjugated diene monomer, hydrogenated to an extent of at least 50% wherein the total amount of A in block copolymer (c) is in the range of from 22 to 40 weight % and wherein the block copolymer has an apparent molecular weight of from 140,000 to 300,000 (A-C-A), respectively of from n*70,000 to n*150,000 ((A-C′)n—X), wherein component i. and ii. together form 50 to 70% by weight of the total binder, the remainder of the binder being based on iii. from 30 to 50% by weight on the total binder of a pigment and/or filler, and iv. from 0 to 4% by weight on the total binder of a UV stabilizer. The invention also provides the non-bituminous, colorable binder composition for making the roofing membrane.

摘要翻译： 本发明提供了一种可着色的屋顶膜，其包括纤维材料和非沥青粘合剂，其包含： 在25℃下具有至少30单位的渗透值的沥青状化合物，并且至少包含氢化石油树脂（a）或至少包含氢化石油树脂（a）和油（b），ii 。 相对于100份式ACA或（A-C'）n -X的氢化苯乙烯类嵌段共聚物（c）的沥青样化合物，10至25重量份，其中A代表 乙烯基芳族单体的聚合物嵌段，X表示偶联部分，n表示2〜20的整数，C表示共轭二烯单体的聚合物嵌段C，氢化至少为50 ％，其中嵌段共聚物（c）中的A的总量在22至40重量％的范围内，其中嵌段共聚物的表观分子量分别为14,000至300,000（ACA），分别为n * 70,000至 n * 150,000（（A-C'）N -X），其中组分i。 和ii。 一起形成总粘合剂的50〜70重量％，其余的粘合剂基于iii。 相对于颜料和/或填料的总粘合剂为30〜50重量％，iv。 相对于UV稳定剂的总粘合剂为0至4重量％。 本发明还提供了用于制造屋顶膜的非沥青可着色粘合剂组合物。

公开(公告)号：US20070185245A1

公开(公告)日：2007-08-09

申请号：US10555125

申请日：2004-04-28

申请人： Erik Trommelen ,  Jaques Damen

发明人： Erik Trommelen ,  Jaques Damen

IPC分类号： C08L95/00

CPC分类号： C08L95/00 ,  C08K2003/2237 ,  C08K2003/265 ,  C08L23/00 ,  C08L25/10 ,  C08L91/00 ,  C08L2555/50 ,  C08L2555/84 ,  C08L2555/86 ,  D06N5/003

摘要： The present invention concerns a colorable composition comprising a bitumen-like compound having a PEN value of at least 30 dmm at 25° C., and comprising at least a hydrogenated petroleum resin (a) or comprising at least a hydrogenated petroleum resin (a) and an oil (b) and a mixture of thermoplastic elastomers comprising:—one or more engineering thermoplastics (c1) having a melt index of I to 50 at 2.16 kg/12300C (determined in accordance with ASTM D1238), and/or a styrenic block copolymer (c2) of formula A-B-A or (A-B)n-X, wherein A stands for a polymer block of a vinyl aromatic monomer, B stands for a polymer block of a conjugated diene monomer, X stands for a coupling moiety, and n stands for an integer of 2 to 20, wherein the weight ratio of (c1) to (c2) varies from 100:0 to 0:100; and—a hydrogenated styrenic block copolymer (d) of formula A-C-A or (A-C)n-X, wherein A, X, and n have the previously given meanings and C stands for a polymer block of a conjugated diene monomer, hydrogenated to an extent of at least 50% wherein the weight ratio of (c), being the total of (c1) and (c2), to (d) varies from 95:5 to 5:95, the total amount of A in block copolymers (c2) and (d) is in the range of from 10 to 45 weight % and wherein the block copolymers have an apparent molecular weight of from 100,000 to 600,000, and the content of said mixture of (c) and (d) being in the range from 5 to 35 wt % based on the composition, and its use as roofing membrane/roofing felt, as well as colored roofing membranes/roofing felts made thereof.

摘要翻译： 本发明涉及一种可着色组合物，其包含在25℃下具有至少30dmm的PEN值的沥青样化合物，并且至少包含氢化石油树脂（a）或至少包含氢化石油树脂（a） 和油（b）和热塑性弹性体的混合物，其包含： - 一种或多种在2.16kg / 12300℃（根据ASTM D1238测定）下熔体指数为I至50的工程热塑性塑料（c1）和/或苯乙烯 式ABA或（AB）n -X的嵌段共聚物（c2），其中A表示乙烯基芳族单体的聚合物嵌段，B表示共轭二烯单体的聚合物嵌段，X表示 对于偶联部分，n表示2至20的整数，其中（c1）至（c2）的重量比从100:0变化到0:100; 和式ACA或（AC）n -X的氢化苯乙烯嵌段共聚物（d），其中A，X和n具有预先给出的含义，C代表共轭的聚合物嵌段 二烯单体，氢化至至少50％的程度，其中（c）的总重量比（c1）和（c2）至（d）的比例在95:5至5:95之间变化，总量 的嵌段共聚物（c2）和（d）中的A在10〜45重量％的范围内，其中嵌段共聚物的表观分子量为100,000〜600,000，所述（c）和 （d）基于组合物在5至35重量％的范围内，并且其用作屋顶膜/屋顶毡，以及由其制成的彩色屋顶膜/屋顶毡。

公开(公告)号：US20060052489A1

公开(公告)日：2006-03-09

申请号：US10537686

申请日：2003-12-18

申请人： Erik Trommelen ,  Duco Bodt ,  Jan Korenstra ,  Johan Plantinga

发明人： Erik Trommelen ,  Duco Bodt ,  Jan Korenstra ,  Johan Plantinga

IPC分类号： C08L95/00

CPC分类号： C08L95/00 ,  C08L53/00 ,  C08L53/02 ,  C08L2666/24

摘要： The present invention relates to a bituminous composition, comprising a bituminous component and a block copolymer, wherein the block copolymer comprises at least two terminal poly(vinyl aromatic) blocks and at least one poly(conjugated diene) central block, wherein said poly(conjugated diene) central block(s) is (are) obtained by substantially random copolymerization of butadiene and isoprene a molar ratio between butadiene and isoprene in the range or from 1:2 to 9:1; wherein the poly(vinyl aromatic) content (PSC) is in the range of from 20 to 30 wt %, wherein the content of a possibly accompanying diblock comprising a poly(vinyl aromatic) block and a poly(butadiene/isoprene) block is at most 25 mole %, wherein the 1,2-addition (vinyl content) of the polymerized conjugated dienes is in the range of from 10 to 80%, and wherein the apparent molecular weight of the complete block copolymer is in the range of 310,000 to 380,000.

摘要翻译： 本发明涉及一种沥青组合物，其包含沥青组分和嵌段共聚物，其中所述嵌段共聚物包含至少两个末端聚（乙烯基芳族）嵌段和至少一个聚（共轭二烯）中心嵌段，其中所述聚（共轭二烯） 二烯）中间嵌段通过丁二烯和异戊二烯的基本上无规共聚而获得，丁二烯和异戊二烯之间的摩尔比在1:2至9:1的范围内; 其中所述聚（乙烯基芳族化合物）含量（PSC）在20至30重量％的范围内，其中包含聚（乙烯基芳族）嵌段和聚（丁二烯/异戊二烯）嵌段的可能伴随的二嵌段的含量为 最多25摩尔％，其中聚合的共轭二烯的1,2-加成（乙烯基含量）在10〜80％的范围内，其中完全嵌段共聚物的表观分子量在31万〜 38万。