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    Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer
    1.
    发明授权
    Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer 失效
    具有高分子量二嵌段共聚物的高分子量嵌段共聚物的压敏粘合剂

    公开(公告)号：US07297741B2

    公开(公告)日：2007-11-20

    申请号：US10880055

    申请日：2004-06-29

    申请人： David J. St. Clair ,  Willem C. Vonk ,  Cornelis Martinus van Dijk

    发明人： David J. St. Clair ,  Willem C. Vonk ,  Cornelis Martinus van Dijk

    IPC分类号： C08L53/02

    CPC分类号： C08F297/04 ,  C08F297/044 ,  C08L95/00 ,  C08L2666/02 ,  C08L2666/24 ,  C09J153/02 ,  Y10T428/31917 ,  Y10T428/3192 ,  C08L53/00

    摘要： The present invention relates to pressure sensitive adhesive compositions prepared from novel anionic block copolymers of aromatic vinyl compounds and conjugated dienes. The block copolymers are a mixture of a high molecular weight linear and/or radial block copolymer component (SBC1 and/or SBC2), and a diblock copolymer component (D1). The block copolymer may be combined with other block copolymers, tackifying resins, oils and other components to form the adhesives of the present invention. The pressure sensitive adhesives of the present invention maintain their performance at elevated temperatures and fail cohesively making them particularly useful for die-cuttable label applications. The pressure sensitive adhesives compositions may also comprise ester plasticizers typically used for PVC and thus make adhesives particularly suitable for PVC film labels and decals.

    摘要翻译： 本发明涉及由芳族乙烯基化合物和共轭二烯的新型阴离子嵌段共聚物制备的压敏粘合剂组合物。 嵌段共聚物是高分子量线性和/或径向嵌段共聚物组分（SBC1和/或SBC2）和二嵌段共聚物组分（D1）的混合物。 嵌段共聚物可以与其它嵌段共聚物，增粘树脂，油和其它组分组合以形成本发明的粘合剂。 本发明的压敏粘合剂在升高的温度下保持它们的性能并且内聚性使其对于可切割的标签应用特别有用。 压敏粘合剂组合物还可以包含通常用于PVC的酯增塑剂，因此使粘合剂特别适用于PVC膜标签和贴花。

    Bituminous emulsions
    4.
    发明授权
    Bituminous emulsions 有权
    沥青乳液

    公开(公告)号：US09115296B2

    公开(公告)日：2015-08-25

    申请号：US11937948

    申请日：2007-11-09

    申请人： Robert Q. Kluttz ,  Keith E. Stephens ,  Willem C. Vonk ,  Jan Korenstra

    发明人： Robert Q. Kluttz ,  Keith E. Stephens ,  Willem C. Vonk ,  Jan Korenstra

    IPC分类号： C08L95/00 ,  C09D195/00 ,  C09J195/00 ,  C08L9/08 ,  C08F297/04 ,  C08F212/08 ,  C08F236/10 ,  C08F236/06 ,  C08L25/10 ,  C08L53/00 ,  C08L53/02

    CPC分类号： C09D195/005 ,  C08F212/08 ,  C08F236/06 ,  C08F236/10 ,  C08F297/04 ,  C08F297/044 ,  C08F2500/17 ,  C08L9/08 ,  C08L25/10 ,  C08L53/00 ,  C08L53/02 ,  C08L95/005 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2555/84 ,  C08L2666/24 ,  C09J195/005

    摘要： The present invention is directed to bituminous emulsions comprising bitumen, water, one or more emulsifiers systems and a diblock copolymer including one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene, wherein the conjugated diene has a peak molecular weight from 30,000 to 78,000 and a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block. A block copolymer comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, multiarm coupled block copolymers having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof, wherein each block copolymer has a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block, wherein the ratio of (i) to (ii) in the block copolymer composition is greater than 1:1.

    摘要翻译： 本发明涉及包含沥青，水，一种或多种乳化剂体系的沥青乳液和包含一个单乙烯基芳族烃和一个共轭二烯嵌段的二嵌段共聚物，其中共轭二烯的峰值分子量为30,000至78,000 和基于共轭二烯嵌段中重复单体单元数的35至80mol％的乙烯基含量。 包含至少两个单乙烯基芳族烃嵌段和至少一个共轭二烯嵌段的嵌段共聚物，所述嵌段共聚物选自峰值分子量为二嵌段共聚物的峰分子量的1.5-3.0倍的直链三嵌段共聚物，多臂偶联 具有峰分子量为二嵌段共聚物的峰分子量的1.5至9.0倍的嵌段共聚物及其混合物，其中每个嵌段共聚物的乙烯基含量为35-80摩尔％，基于重复单体单元的数量 共轭二烯嵌段，其中嵌段共聚物组合物中（i）与（ii）的比例大于1:1。

    Block copolymer and polymer modified bituminous binder composition for use in base course asphalt paving application
    5.
    发明授权
    Block copolymer and polymer modified bituminous binder composition for use in base course asphalt paving application 有权
    用于基础沥青铺路应用的嵌段共聚物和聚合物改性沥青粘合剂组合物

    公开(公告)号：US08357735B2

    公开(公告)日：2013-01-22

    申请号：US13427651

    申请日：2012-03-22

    申请人： Erik Jan Scholten ,  Willem C. Vonk

    发明人： Erik Jan Scholten ,  Willem C. Vonk

    IPC分类号： C08L95/00 ,  B32B11/00

    CPC分类号： E01C7/265 ,  C08L25/00 ,  C08L53/02 ,  C08L95/00 ,  C08L2205/02 ,  Y10T428/31815 ,  C08L2666/24 ,  C08L2666/06

    摘要： The present invention provides a polymeric composition that includes a coupled block copolymer having a plurality of arms comprising at least two blocks of a monovinylaromatic hydrocarbon that are located on at least two of the plurality of arms, and at least one block of a conjugated diene located on at least one of the plurality of arms, and optionally one or more block copolymers comprising at least one block of monovinylaromatic hydrocarbon and at least one block of a conjugated diene, the block copolymer may be selected from linear copolymers, linear triblock copolymers, multiarm coupled block copolymers, and mixtures thereof. The molecular weight of the polymeric composition is in the range from about 100 kg/mol to about 400 kg/mol.

    摘要翻译： 本发明提供一种聚合物组合物，其包括具有多个臂的偶联嵌段共聚物，所述多个臂包含至少两个位于所述多个臂中的至少两个臂上的单乙烯基芳烃的嵌段和至少一个共轭二烯的嵌段 在多个臂中的至少一个上，以及任选的一个或多个包含至少一个单乙烯基芳烃嵌段和至少一个共轭二烯嵌段的嵌段共聚物，该嵌段共聚物可以选自线性共聚物，线性三嵌段共聚物，多元共聚物 偶联嵌段共聚物及其混合物。 聚合物组合物的分子量在约100kg / mol-约400kg / mol的范围内。

    Asphaltic coating compositions
    6.
    发明授权
    Asphaltic coating compositions 失效
    沥青涂料组合物

    公开(公告)号：US4738996A

    公开(公告)日：1988-04-19

    申请号：US846648

    申请日：1986-03-31

    申请人： Willem C. Vonk ,  Gerrit van Gooswilligen

    发明人： Willem C. Vonk ,  Gerrit van Gooswilligen

    IPC分类号： C08L95/00 ,  C09D195/00 ,  C08J3/20

    CPC分类号： C08L95/00 ,  C09D195/00

    摘要： A composition which contains (a) 80 to 99% w of a bitumen component; (b) 1 to 20% w of an elastomer; (c) 1 to 60% w of a hydrocarbon resin which has been modified to contain carboxyl, carboxylic anhydride, hydroxyl and/or amino groups; and (d) 1 to 100% w of an inorganic filler, the weight percentages being based on the total weight of the bitumen component and elastomer, is suitable for coating structures and a process for applying the composition at elevated temperature onto a suitbale structure.

    摘要翻译： 含有（a）80-99％w的沥青组分的组合物; （b）1〜20重量％的弹性体; （c）1至60％重量的经改性以含羧基，羧酸酐，羟基和/或氨基的烃树脂; 和（d）1至100％w的无机填料，其重量百分比基于沥青组分和弹性体的总重量，适用于涂覆结构和将组合物在升高的温度下施加到口袋结构上的方法。

    Structure coating method with asphaltic compositions
    8.
    发明授权
    Structure coating method with asphaltic compositions 失效
    具有沥青组合物的结构涂层方法

    公开(公告)号：US4749622A

    公开(公告)日：1988-06-07

    申请号：US102950

    申请日：1987-09-24

    申请人： Willem C. Vonk ,  Gerrit V. Gooswilligen

    发明人： Willem C. Vonk ,  Gerrit V. Gooswilligen

    IPC分类号： C08L95/00 ,  B32B11/00 ,  B05D1/36

    CPC分类号： C08L95/00 ,  Y10T428/1386 ,  Y10T428/1393 ,  Y10T428/31717 ,  Y10T428/31815

    摘要： A composition which contains (a) 80 to 99% w of a bitumen component; (b) 1 to 20% w of an elastomer; (c) 1 to 60% w of a hydrocarbon resin which has been modified to contain carboxyl, carboxylic anhydride, hydroxyl and/or amino groups; and (d) 1 to 100% w of an inorganic filler, the weight percentages being based on the total weight of the bitumen component and elastomer, is suitable for coating structures and a process for applying the composition at elevated temperature onto a suitable structure.

    摘要翻译： 含有（a）80-99％w的沥青组分的组合物; （b）1〜20重量％的弹性体; （c）1至60％重量的经改性以含羧基，羧酸酐，羟基和/或氨基的烃树脂; 和（d）1至100％w的无机填料，其重量百分比基于沥青组分和弹性体的总重量，适用于涂覆结构和将组合物在升高的温度下施加到合适结构上的方法。

    BLOCK COPOLYMER AND POLYMER MODIFIED BITUMINOUS BINDER COMPOSITION FOR USE IN BASE COURSE ASPHALT PAVING APPLICATION
    9.
    发明申请
    BLOCK COPOLYMER AND POLYMER MODIFIED BITUMINOUS BINDER COMPOSITION FOR USE IN BASE COURSE ASPHALT PAVING APPLICATION 审中-公开
    嵌段共聚物和聚合物修饰的BITUMINOUS BINDER组合物用于基础课程ASPHALT PAVING应用

    公开(公告)号：US20110034594A1

    公开(公告)日：2011-02-10

    申请号：US12937666

    申请日：2008-04-17

    申请人： Erik Jan Scholten ,  Willem C. Vonk

    发明人： Erik Jan Scholten ,  Willem C. Vonk

    IPC分类号： E01C7/26 ,  C08F236/10

    CPC分类号： E01C7/265 ,  C08L25/00 ,  C08L53/02 ,  C08L95/00 ,  C08L2205/02 ,  Y10T428/31815 ,  C08L2666/24 ,  C08L2666/06

    摘要： The present invention provides a polymeric composition that includes a coupled block copolymer having a plurality of arms comprising at least two blocks of a monovinylaromatic hydrocarbon that are located on at least two of the plurality of arms, and at least one block of a conjugated diene located on at least one of the plurality of arms, and optionally one or more block copolymers comprising at least one block of monovinylaromatic hydrocarbon and at least one block of a conjugated diene, the block copolymer may be selected from linear copolymers, linear triblock copolymers, multiarm coupled block copolymers, and mixtures thereof. The molecular weight of the polymeric composition is in the range from about 100 kg/mol to about 400 kg/mol.

    摘要翻译： 本发明提供一种聚合物组合物，其包括具有多个臂的偶联嵌段共聚物，所述多个臂包含至少两个位于所述多个臂中的至少两个臂上的单乙烯基芳烃的嵌段和至少一个共轭二烯的嵌段 在多个臂中的至少一个上，以及任选的一个或多个包含至少一个单乙烯基芳烃嵌段和至少一个共轭二烯嵌段的嵌段共聚物，该嵌段共聚物可以选自线性共聚物，线性三嵌段共聚物，多元共聚物 偶联嵌段共聚物及其混合物。 聚合物组合物的分子量在约100kg / mol-约400kg / mol的范围内。