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公开(公告)号:US5350722A
公开(公告)日:1994-09-27
申请号:US920487
申请日:1992-08-20
CPC分类号: B01J29/7034 , C01B39/42 , B01J2229/26 , B01J2229/42 , Y10S423/33
摘要: The invention relates to a synthetic crystalline zeolite of the MTW type, characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2 in which M represents a metal cation and/or proton, n is the valency of M and x is a number between 14 and 800,b) a X-ray diagram shown in table I of the description,c) a fluorine content between approximately 0.005 and 2% by weight, said zeolite having been synthesized in a fluoride medium and accompanied by stirring.
摘要翻译: PCT No.PCT / FR91 / 01029 Sec。 371日期:1992年8月20日 102(e)日期1992年8月20日PCT 1991年12月18日PCT PCT。 出版物WO92 / 11203 本发明涉及MTW型合成结晶沸石,其特征在于:a)以下近似通式:M 2 / nO,Al 2 O 3,xSiO 2,其中M表示金属阳离子和/或质子, n是M的化合价,x是14和800之间的数字,b)描述表I所示的X射线图,c)约0.005-2重量%的氟含量,所述沸石已被合成 在氟化物介质中并伴随搅拌。
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公开(公告)号:US5171556A
公开(公告)日:1992-12-15
申请号:US743967
申请日:1991-08-12
申请人: Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
发明人: Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
CPC分类号: B01J29/7007 , C01B39/48 , B01J2229/26 , B01J2229/42
摘要: The object of the invention is a synthetic crystalline zeolite of the beta type characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2where M represents a proton and/or a metallic cationn is the valence of Mx is a number ranging from 5 to 800,b) an X-ray diffraction diagram represented in table I of the description, andc) a fluorine content ranging from about 0.005 to 2.0% by weight, said zeolite having been furthermore synthetized in a fluoride medium.
摘要翻译: 本发明的目的是一种β型合成结晶沸石,其特征在于:a)以下近似通式:M 2 / nO,Al 2 O 3,xSiO 2,其中M表示质子和/或金属阳离子n是M x的化合价 是5〜800的数,b)说明书的表I所示的X射线衍射图,c)氟含量为0.005〜2.0重量%左右,所述沸石进一步在氟化物中合成 中。
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公开(公告)号:US5215736A
公开(公告)日:1993-06-01
申请号:US860557
申请日:1992-03-30
申请人: Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Jean-Francois Joly , Christine Travers , Francis Raatz
发明人: Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Jean-Francois Joly , Christine Travers , Francis Raatz
CPC分类号: C01B33/2861 , B01J29/18 , C07C5/2724 , Y10S423/25
摘要: The object of the invention is a synthetic crystalline zeolite of the mordenite type characterized by:a) the following approximate general formula:Na.sub.2 O, Al.sub.2 O.sub.3, xSiO.sub.2 where x is a number ranging from 9 to 30, andb) an X-ray diffraction diagram represented in table I of the description,c) a fluorine content ranging from about 0.005 to 2.0% by weight,and in that it has been synthetized in a fluoride medium.The invention also relates to a process for preparing said zeolite.This zeolite can notably be utilized in adsorption and in catalysis.
摘要翻译: 本发明的目的是丝光沸石的合成结晶沸石,其特征在于:a)以下近似通式:Na 2 O,Al 2 O 3,xSiO 2,其中x为9至30的数,以及b)X射线衍射图 表示在说明书的表I中,c)氟含量范围为约0.005-2.0重量%,并且其在氟化物介质中合成。 本发明还涉及制备所述沸石的方法。 该沸石可以显着地用于吸附和催化。
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公开(公告)号:US5338525A
公开(公告)日:1994-08-16
申请号:US923880
申请日:1992-10-16
申请人: Jean-Francois Joly , Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Nathalie Brunard , Frederic Kolenda
发明人: Jean-Francois Joly , Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Nathalie Brunard , Frederic Kolenda
IPC分类号: B01J29/40 , B01J29/70 , B01J29/86 , B01J29/87 , B01J29/88 , C01B39/06 , C01B39/08 , C01B39/38 , C01B33/26 , B01J29/06
CPC分类号: C01B39/065 , B01J29/40 , B01J29/87 , C01B39/082 , C01B39/38 , B01J2229/26 , B01J2229/42
摘要: Synthetic crystalline zeolite of the MFI type and its preparation process, said zeolite being characterized by:a) the following approximate general formula:M.sup.+.sub.(x+y) [Si.sub.(96-(x+y)) Al.sub.x Ga.sub.y 0.sub.192 ].sup.(x+y).sup.- in which M represents an alkaline cation and/or ammonium cation and/or a proton, x is a number between 0 and 24, y is a number between 0 and 24, (x+y) is a number between 0.64 and 24 and preferably between 1.88 and 19.2,b) a X-ray diagram of its ammonium form shown in Table I of the description andc) a fluorine content of its ammonium form between approximately 0.01 and 2.0% by weight, said zeolite having been synthesized in a fluoride medium and in the absence of an organic agent.
摘要翻译: PCT No.PCT / FR91 / 01068 Sec。 371日期:1992年10月16日 102(e)日期1992年10月16日PCT 1991年12月24日PCT公布。 出版物WO92 / 12096 日本1992年7月23日。MFI型合成结晶沸石及其制备方法,所述沸石的特征在于:a)以下近似通式:M +(x + y)[Si(96-(x + y)) (x + y) - 其中M表示碱性阳离子和/或铵阳离子和/或质子,x为0至24之间的数,y为0至24之间的数,(x + y)为 数字在0.64和24之间,优选在1.88和19.2之间,b)其描述的表I所示的铵形式的X射线图,c)其铵形式的氟含量在约0.01和2.0重量%之间, 所述沸石已经在氟化物介质中合成,并且在不存在有机试剂的情况下。
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公开(公告)号:US4982046A
公开(公告)日:1991-01-01
申请号:US372599
申请日:1989-06-28
IPC分类号: C01B39/00 , B01J29/00 , B01J29/04 , B01J29/65 , B01J29/68 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , C01B37/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/12 , C01B39/44 , C01B39/46 , C07B61/00 , C07C1/00 , C07C2/12 , C07C11/02 , C07C67/00 , C08F4/00 , C08F4/06 , C08F4/60 , C08F10/00 , C08F210/16 , C10G50/00
CPC分类号: B01J29/04 , B01J29/65 , B01J29/655 , B01J29/68 , B01J29/87 , C01B37/02 , C01B39/065 , C01B39/082 , C01B39/12 , C01B39/445 , C07C2/12 , B01J2229/26 , B01J2229/42 , C07C2529/89 , Y10S423/23
摘要: Olefin oligomerization employing as a catalyst(a) a ferrierite of the following approximate formula:M.sub.x/n (T.sup.III O.sub.2).sub.x (Si.sup.IV O.sub.2).sub.36-x whereT.sup.III represents at least one element selected from the group of boron (B.sup.III), aluminum (Al.sup.III), gallium (Ga.sup.III) and iron (Fe.sup.III);x ranges from 0.05 to 6.6;M is a compensation cation; andn is the valence of M;(b) an X-ray diffraction diagram shown in Table 1 of the description;(c) a fluorine content after synthesis ranging from about 0.01 to 1.6% by weight; and(d) a Si.sup.IV /T.sup.III molar ratio of at least about 4.75.
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公开(公告)号:US4853203A
公开(公告)日:1989-08-01
申请号:US124122
申请日:1987-11-23
IPC分类号: C01B39/00 , B01J29/00 , B01J29/04 , B01J29/65 , B01J29/68 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , C01B37/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/12 , C01B39/44 , C01B39/46 , C07B61/00 , C07C1/00 , C07C2/12 , C07C11/02 , C07C67/00 , C08F4/00 , C08F4/06 , C08F4/60 , C08F10/00 , C08F210/16 , C10G50/00
CPC分类号: B01J29/04 , B01J29/65 , B01J29/655 , B01J29/68 , B01J29/87 , C01B37/02 , C01B39/065 , C01B39/082 , C01B39/12 , C01B39/445 , C07C2/12 , B01J2229/26 , B01J2229/42 , C07C2529/89 , Y10S423/23
摘要: New ferrierites are disclosed as well as their process of manufacture.According to the invention, these new ferrierites are characterized by:(a) The following approximate formula:M.sub.x/n (T.sup.III O.sub.2).sub.x (Si.sup.IV O.sub.2).sub.36-xwherein T.sup.III is at least one element selected from the group formed of boron (B.sup.III),aluminum (Al.sup.III),gallium (Ga.sup.III) and iron (Fe.sup.III)x ranges from 0.05 and 6.6M is a compensation cationn is the valence of M.(b) A particular X-ray diagram,(c) A fluorine content after synthesis ranging from about 0.01 to 1.6% by weight, and(d) A Si.sup.IV /T.sup.III molar ratio of at least 4.75.
摘要翻译: 公开了新的镁碱石及其制造工艺。 根据本发明,这些新的镁碱沸石的特征在于:(a)以下近似式:Mx / n(TIIIO2)x(SiIVO2)36-x其中TIII是选自由硼(BIII)形成的组中的至少一种元素, ,铝(AlIII),镓(GaIII)和铁(FeIII)x的范围为0.05和6.6 M是补偿阳离子,n是M的化合价。(b)特定X射线图,(c) 合成范围为约0.01至1.6重量%,(d)SiIV / TIII摩尔比为至少4.75。
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