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公开(公告)号:US08501881B2
公开(公告)日:2013-08-06
申请号:US13504975
申请日:2010-11-11
申请人: Jeannette Aumo , Pasi Matikainen , Michael Bartke , Tom Elovirta , Sameer Vijay , Mikko Lylykangas , Pertti Elo , Lauri Huhtanen
发明人: Jeannette Aumo , Pasi Matikainen , Michael Bartke , Tom Elovirta , Sameer Vijay , Mikko Lylykangas , Pertti Elo , Lauri Huhtanen
CPC分类号: C08F10/00 , C08F110/06 , C08F2410/01 , C08F4/65912 , C08F4/65927 , C08F2/00 , C08F2500/12 , C08F4/6492
摘要: The present application provides a process for polymerizing at least one olefin in the presence of a polymerization catalyst, including: (A) continuously introducing a first liquid with a transition metal compound, an organometallic compound, and a solvent and a second liquid into an emulsification stage, (B) continuously withdrawing the emulsion and directing it into a solidification stage to form a slurry with a solid polymerization catalyst component, (C) continuously recovering the solid polymerization catalyst component, (D) directing the solid polymerization catalyst component into a first prepolymerization stage with a monomer and a second liquid to form a slurry, (E) recovering a prepolymerized solid polymerization catalyst component, (F) continuously introducing the prepolymerized solid polymerization catalyst component into a second prepolymerization stage with an olefin monomer to form a prepolymerized catalyst, and (G) continuously withdrawing the prepolymerized catalyst and directing it into a subsequent polymerization stage with at least one olefin monomer.
摘要翻译: 本申请提供了在聚合催化剂存在下聚合至少一种烯烃的方法,包括:(A)将第一液体与过渡金属化合物,有机金属化合物和溶剂以及第二液体连续引入乳化剂 阶段,(B)连续地取出乳液并将其导入固化阶段以形成具有固体聚合催化剂组分的浆料,(C)连续回收固体聚合催化剂组分,(D)将固体聚合催化剂组分引入第一 预聚合阶段与单体和第二液体形成浆料,(E)回收预聚的固体聚合催化剂组分,(F)将预聚的固体聚合催化剂组分连续引入第二预聚合阶段与烯烃单体以形成预聚催化剂 ,(G)连续地取出预聚合催化剂a d使其与至少一种烯烃单体引导到随后的聚合阶段。
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公开(公告)号:US20120259076A1
公开(公告)日:2012-10-11
申请号:US13504975
申请日:2010-11-11
申请人: Jeannette Aumo , Pasi Matikainen , Michael Bartke , Tom Elovirta , Sameer Vijay , Mikko Lylykangas , Pertti Elo , Lauri Huhtanen
发明人: Jeannette Aumo , Pasi Matikainen , Michael Bartke , Tom Elovirta , Sameer Vijay , Mikko Lylykangas , Pertti Elo , Lauri Huhtanen
IPC分类号: C08F2/08 , C08F110/06
CPC分类号: C08F10/00 , C08F110/06 , C08F2410/01 , C08F4/65912 , C08F4/65927 , C08F2/00 , C08F2500/12 , C08F4/6492
摘要: The present application provides a process for polymerizing at least one olefin in the presence of a polymerization catalyst, including: (A) continuously introducing a first liquid with a transition metal compound, an organometallic compound, and a solvent and a second liquid into an emulsification stage, (B) continuously withdrawing the emulsion and directing it into a solidification stage to form a slurry with a solid polymerization catalyst component, (C) continuously recovering the solid polymerization catalyst component, (D) directing the solid polymerization catalyst component into a first prepolymerization stage with a monomer and a second liquid to form a slurry, (E) recovering a prepolymerized solid polymerization catalyst component, (F) continuously introducing the prepolymerized solid polymerization catalyst component into a second prepolymerization stage with an olefin monomer to form a prepolymerized catalyst, and (G) continuously withdrawing the prepolymerized catalyst and directing it into a subsequent polymerization stage with at least one olefin monomer.
摘要翻译: 本申请提供了在聚合催化剂存在下聚合至少一种烯烃的方法,包括:(A)将第一液体与过渡金属化合物,有机金属化合物和溶剂以及第二液体连续引入乳化剂 阶段,(B)连续地取出乳液并将其导入固化阶段以形成具有固体聚合催化剂组分的浆料,(C)连续回收固体聚合催化剂组分,(D)将固体聚合催化剂组分引入第一 预聚合阶段与单体和第二液体形成浆料,(E)回收预聚的固体聚合催化剂组分,(F)将预聚的固体聚合催化剂组分连续引入第二预聚合阶段与烯烃单体以形成预聚催化剂 ,(G)连续地取出预聚合催化剂a d使其与至少一种烯烃单体引导到随后的聚合阶段。
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公开(公告)号:US20090208681A1
公开(公告)日:2009-08-20
申请号:US11988387
申请日:2006-07-10
申请人: Eberhard Ernst , Petri Lehmus , Michael Bartke , Lauri Huhtanen
发明人: Eberhard Ernst , Petri Lehmus , Michael Bartke , Lauri Huhtanen
IPC分类号: B32B1/02 , C08F110/06 , C08F4/42 , C08F4/52 , C08F2/34
CPC分类号: C08F110/06 , C08F4/65927 , C08F10/00 , Y10T428/1324 , Y10T428/1352 , C08F4/65912 , C08F2500/12 , C08F2500/03 , C08F2500/26 , C08F2500/05
摘要: A polypropylene with a low amount of impurities, in particular a low amount of aluminum and boron residues.
摘要翻译: 具有少量杂质的聚丙烯,特别是少量的铝和硼残余物。
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公开(公告)号:US07718563B2
公开(公告)日:2010-05-18
申请号:US12044350
申请日:2008-03-07
申请人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
发明人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
IPC分类号: C08F4/42 , C08F4/6192 , B01J31/00 , B01J31/22
CPC分类号: C08F10/00 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2/22
摘要: The invention provides a process for producing an olefin polymerization catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.
摘要翻译: 本发明提供了一种生产烯烃聚合催化剂的方法,其包括过渡金属或锕系元素或镧系元素的有机金属化合物,其为固体催化剂颗粒形式,包括形成液体/液体乳液体系,其包含一种或多种 更多的催化剂组分分散在与其不混溶的溶剂中; 并固化所述分散相以将所述液滴转化成包含催化剂的固体颗粒,并任选地回收所述颗粒。
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公开(公告)号:US07341971B2
公开(公告)日:2008-03-11
申请号:US10499760
申请日:2002-12-18
申请人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
发明人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
CPC分类号: C08F10/00 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2/22
摘要: The invention provides a process for producing an olefin polymerization catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.
摘要翻译: 本发明提供了一种生产烯烃聚合催化剂的方法,其包括过渡金属或锕系元素或镧系元素的有机金属化合物,其为固体催化剂颗粒形式,包括形成液体/液体乳液体系,其包含一种或多种 更多的催化剂组分分散在与其不混溶的溶剂中; 并固化所述分散相以将所述液滴转化成包含催化剂的固体颗粒,并任选地回收所述颗粒。
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公开(公告)号:US07531478B2
公开(公告)日:2009-05-12
申请号:US10499761
申请日:2002-12-18
申请人: Peter Denifl , Erik Van Praet , Michael Bartke
发明人: Peter Denifl , Erik Van Praet , Michael Bartke
CPC分类号: C08F10/02 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , C08F2/14 , C08F4/65916 , C08F2500/18 , C08F210/14
摘要: The invention provides a process for producing an olefin polymerisation catalyst, comprising suspending a porous particulate support material in a liquid/liquid two phase system, which comprises a solution of one or more catalyst components and an inert solvent immiscible therewith, to impregnate said solution into the pores of said support material, wherein the active transition metal concentration in the support is from 0.001 to 10% by weight of the dry catalyst system.
摘要翻译: 本发明提供了一种生产烯烃聚合催化剂的方法,包括将多孔颗粒载体材料悬浮在液体/液体两相体系中,液相/液体两相体系包含一种或多种催化剂组分和与其不混溶的惰性溶剂的溶液,以将所述溶液浸渍 所述载体材料的孔隙,其中载体中的活性过渡金属浓度为干燥催化剂体系的0.001至10重量%。
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公开(公告)号:US08222175B2
公开(公告)日:2012-07-17
申请号:US11794600
申请日:2005-12-22
申请人: Michael Bartke , Peter Denifl
发明人: Michael Bartke , Peter Denifl
IPC分类号: C08F4/602 , C08F4/6592 , B01J31/22
CPC分类号: C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65908 , C08F2500/18 , C08F2500/24
摘要: This invention relates to a process for the preparation of an olefin polymerization catalyst, to the use of the catalyst in olefin polymerization and to the catalyst and polymers obtained. In particular, the invention relates to the preparation of a catalyst comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC) by a semi-continuous or continuous process.
摘要翻译: 本发明涉及烯烃聚合催化剂的制备方法,烯烃聚合中催化剂的用途以及获得的催化剂和聚合物。 特别地,本发明涉及通过半连续或连续方法制备包含周期表(IUPAC)的第3至10族的过渡金属的有机金属化合物的催化剂。
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公开(公告)号:US20090012247A1
公开(公告)日:2009-01-08
申请号:US11794600
申请日:2005-12-22
申请人: Michael Bartke , Peter Denifl
发明人: Michael Bartke , Peter Denifl
CPC分类号: C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65908 , C08F2500/18 , C08F2500/24
摘要: This invention relates to a process for the preparation of an olefin polymerisation catalyst, to the use of the catalyst in olefin polymerisation and to the catalyst and polymers obtained. In particular, the invention relates to the preparation of a catalyst comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC) by a semi-continuous or continuous process.
摘要翻译: 本发明涉及烯烃聚合催化剂的制备方法,烯烃聚合中催化剂的用途以及获得的催化剂和聚合物。 特别地,本发明涉及通过半连续或连续方法制备包含周期表(IUPAC)的第3至10族的过渡金属的有机金属化合物的催化剂。
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公开(公告)号:US20080275200A1
公开(公告)日:2008-11-06
申请号:US12044350
申请日:2008-03-07
申请人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
发明人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
CPC分类号: C08F10/00 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2/22
摘要: The invention provides a process for producing an olefin polymerisation catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.
摘要翻译: 本发明提供了一种生产烯烃聚合催化剂的方法,其包括固体催化剂颗粒形式的过渡金属或锕系元素或镧系元素的有机金属化合物,其包括形成液体/液体乳液体系,其包含一种或多种 更多的催化剂组分分散在与其不混溶的溶剂中; 并固化所述分散相以将所述液滴转化成包含催化剂的固体颗粒,并任选地回收所述颗粒。
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公开(公告)号:US20080064835A1
公开(公告)日:2008-03-13
申请号:US11940053
申请日:2007-11-14
申请人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
发明人: Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
CPC分类号: C08F10/00 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2/22
摘要: The invention provides a process for producing an olefin polymerisation catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.
摘要翻译: 本发明提供了一种生产烯烃聚合催化剂的方法,其包括固体催化剂颗粒形式的过渡金属或锕系元素或镧系元素的有机金属化合物,其包括形成液体/液体乳液体系,其包含一种或多种 更多的催化剂组分分散在与其不混溶的溶剂中; 并固化所述分散相以将所述液滴转化成包含催化剂的固体颗粒,并任选地回收所述颗粒。
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