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公开(公告)号:US09543581B2
公开(公告)日:2017-01-10
申请号:US13817324
申请日:2011-08-04
申请人: Jens Paulsen , JiHye Kim , HeonPyo Hong
发明人: Jens Paulsen , JiHye Kim , HeonPyo Hong
IPC分类号: H01M4/485 , H01M4/505 , H01M4/525 , B82Y30/00 , C01G51/04 , C01G53/04 , C04B35/01 , C04B35/628
CPC分类号: H01M4/525 , B82Y30/00 , C01G51/04 , C01G53/04 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/84 , C04B35/01 , C04B35/62813 , C04B35/62892 , C04B2235/3262 , C04B2235/3275 , C04B2235/3279 , C04B2235/44 , C04B2235/5454 , H01M4/485 , H01M4/505 , Y02E60/122 , Y02P70/54
摘要: A particulate precursor compound for manufacturing an aluminum doped lithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-hydroxide or (M)-oxyhydroxide core and a non-amorphous aluminum oxide coating layer covering the core. By providing an aluminum dry-coating process where the particulate precursor core compound is mixed with alumina powder in one or more procedures, higher doping levels of aluminum compared to the known prior art may be achieved. The crystal structure of the alumina is maintained during the coating procedures and the core of each mixed transition metal precursor particle is surrounded by a coating layer containing crystalline alumina nano particles. The aluminum concentration in the particulate precursor decreases as the size of the core increases.
摘要翻译: 用于制造可用作锂离子电池中的活性正极材料的铝掺杂锂过渡金属(M) - 氧化物粉末的颗粒前体化合物包括过渡金属(M) - 羟基氧化物或(M) - 羟基氧化物核心和非 - 无定形氧化铝覆层覆盖核心。 通过提供铝干法涂覆方法,其中颗粒前体核心化合物与氧化铝粉末以一种或多种方法混合,可以实现与已知现有技术相比较较高掺杂水平的铝。 在涂布过程中保持氧化铝的晶体结构,并且每个混合的过渡金属前体颗粒的芯被包含结晶氧化铝纳米颗粒的涂层包围。 颗粒前体中的铝浓度随着核心尺寸的增加而减小。
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公开(公告)号:US20130209885A1
公开(公告)日:2013-08-15
申请号:US13817324
申请日:2011-08-04
申请人: Jens Paulsen , JiHye Kim , HeonPyo Hong
发明人: Jens Paulsen , JiHye Kim , HeonPyo Hong
IPC分类号: H01M4/525
CPC分类号: H01M4/525 , B82Y30/00 , C01G51/04 , C01G53/04 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/84 , C04B35/01 , C04B35/62813 , C04B35/62892 , C04B2235/3262 , C04B2235/3275 , C04B2235/3279 , C04B2235/44 , C04B2235/5454 , H01M4/485 , H01M4/505 , Y02E60/122 , Y02P70/54
摘要: A particulate precursor compound for manufacturing an aluminum doped lithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-hydroxide or (M)-oxy-hydroxide core and a non-amorphous aluminum oxide coating layer covering the core. By providing an aluminum thy-coating process where the particulate precursor core compound is mixed with alumina powder in one or more procedures, higher doping levels of aluminum compared to the known prior art may be achieved. The crystal structure of the alumina is maintained during the coating procedures and the core of each mixed transition metal precursor particle is surrounded by a coating layer containing crystalline alumina nano particles. The aluminum concentration in the particulate precursor decreases as the size of the core increases.
摘要翻译: 用于制造可用作锂离子电池中的活性正极材料的掺铝锂过渡金属(M) - 氧化物粉末的颗粒前体化合物包括过渡金属(M) - 羟基氧化物或(M) - 氢氧化氢核心和 覆盖核心的非无定形氧化铝涂层。 通过提供铝涂覆方法,其中颗粒前体核心化合物与氧化铝粉末以一种或多种方法混合,可以实现与已知现有技术相比较较高掺杂水平的铝。 在涂布过程中保持氧化铝的晶体结构,并且每个混合的过渡金属前体颗粒的芯被包含结晶氧化铝纳米颗粒的涂层包围。 颗粒前体中的铝浓度随着核心尺寸的增加而减小。
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公开(公告)号:US09876226B2
公开(公告)日:2018-01-23
申请号:US13817326
申请日:2011-08-04
申请人: Jens Paulsen , JiHye Kim , HeonPyo Hong
发明人: Jens Paulsen , JiHye Kim , HeonPyo Hong
IPC分类号: H01M4/525 , C04B35/626 , C04B35/01 , C01G51/00 , C01G53/00 , C01G45/12 , H01M4/36 , H01M4/505 , H01M10/0525 , H01M10/052 , C04B35/628
CPC分类号: H01M4/525 , C01G45/1221 , C01G51/42 , C01G51/44 , C01G53/42 , C01G53/44 , C01P2002/50 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2004/84 , C01P2006/12 , C01P2006/40 , C01P2006/60 , C01P2006/80 , C04B35/01 , C04B35/62675 , C04B35/62813 , C04B2235/3203 , C04B2235/3262 , C04B2235/3275 , C04B2235/3279 , C04B2235/44 , C04B2235/5409 , C04B2235/5436 , C04B2235/5472 , C04B2235/721 , C04B2235/726 , H01M4/366 , H01M4/505 , H01M10/052 , H01M10/0525
摘要: Aluminum dry-coated and heat treated cathode material precursors. A particulate precursor compound for manufacturing an aluminum coatedlithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-oxide core and a non-amorphous aluminum oxide coating layercovering the core. By providing a heat treatment process for mixed metal precursors that may be combined with an aluminum dry-coating process, novel aluminum containing precursors that may be used to form high quality nickel based cathode materials are obtained. The aluminum dry-coated and heat treated precursors include particles have, compared to prior art precursors, relatively low impurity levels of carbonate and/or sulfide, and can be produced at lower cost.
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公开(公告)号:US20130175469A1
公开(公告)日:2013-07-11
申请号:US13817326
申请日:2011-08-04
申请人: Jens Paulsen , JiHye Kim , HeonPyo Hong
发明人: Jens Paulsen , JiHye Kim , HeonPyo Hong
IPC分类号: H01M4/525
CPC分类号: H01M4/525 , C01G45/1221 , C01G51/42 , C01G51/44 , C01G53/42 , C01G53/44 , C01P2002/50 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2004/84 , C01P2006/12 , C01P2006/40 , C01P2006/60 , C01P2006/80 , C04B35/01 , C04B35/62675 , C04B35/62813 , C04B2235/3203 , C04B2235/3262 , C04B2235/3275 , C04B2235/3279 , C04B2235/44 , C04B2235/5409 , C04B2235/5436 , C04B2235/5472 , C04B2235/721 , C04B2235/726 , H01M4/366 , H01M4/505 , H01M10/052 , H01M10/0525
摘要: Aluminum dry-coated and heat treated cathode material precursors. A particulate precursor compound for manufacturing an aluminum coated lithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-oxide core and a non-amorphous aluminum oxide coating layer covering the core. By providing a heat treatment process for mixed metal precursors that may be combined with an aluminum thy-coating process, novel aluminum containing precursors that may be used to form high quality nickel based cathode materials are obtained. The aluminum dry-coated and heat treated precursors include particles have, compared to prior art precursors, relatively low impurity levels of carbonate and/or sulfide, and can be produced at lower cost.
摘要翻译: 铝干涂和热处理阴极材料前体。 用于制造可用作锂离子电池中的活性正极材料的铝包覆的锂过渡金属(M) - 氧化物粉末的颗粒前体化合物包括过渡金属(M) - 氧化物核和非无定形氧化铝覆盖层 核心。 通过提供可与铝涂覆方法组合的混合金属前体的热处理方法,可获得可用于形成高质量镍基阴极材料的新型含铝前体。 铝干涂和热处理的前体包括与现有技术的前体相比具有相对低的碳酸盐和/或硫化物杂质水平的颗粒,并且可以以较低的成本生产。
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公开(公告)号:US09614226B2
公开(公告)日:2017-04-04
申请号:US13505582
申请日:2010-10-19
申请人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
发明人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
IPC分类号: H01M4/62 , H01M4/131 , H01M4/1391 , H01M4/36 , H01M4/525 , H01M4/13915 , H01M4/1315 , H01M10/052
CPC分类号: H01M4/62 , H01M4/131 , H01M4/1315 , H01M4/1391 , H01M4/13915 , H01M4/366 , H01M4/525 , H01M4/623 , H01M10/052 , Y02E60/122
摘要: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE.
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公开(公告)号:US20120261610A1
公开(公告)日:2012-10-18
申请号:US13505595
申请日:2010-10-19
申请人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
发明人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
IPC分类号: H01M4/525
CPC分类号: H01M4/62 , H01M4/131 , H01M4/1391 , H01M4/366 , H01M4/505 , H01M4/525 , H01M4/623 , H01M10/052 , Y02E60/122 , Y10T29/49115 , Y10T428/3154
摘要: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a LiF layer, where this layer consists of a reaction product of a fluorine-containing polymer and the primary particle surface. The lithium of the LiF originates from the primary particles surface. Examples of the fluorine-containing polymer are either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCodMeO2, wherein M is either one of both of Mg and Ti, with e
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公开(公告)号:US20120270104A1
公开(公告)日:2012-10-25
申请号:US13505582
申请日:2010-10-19
申请人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
发明人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
IPC分类号: H01M4/62 , H01M4/1395 , H01M4/131
CPC分类号: H01M4/62 , H01M4/131 , H01M4/1315 , H01M4/1391 , H01M4/13915 , H01M4/366 , H01M4/525 , H01M4/623 , H01M10/052 , Y02E60/122
摘要: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCOdMeO2, wherein M is either one or both of Mg and Ti, with e
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公开(公告)号:US08852452B2
公开(公告)日:2014-10-07
申请号:US13505595
申请日:2010-10-19
申请人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
发明人: Jens Paulsen , Randy De Palma , HeonPyo Hong , KyuBo Kim
IPC分类号: H01M4/88 , H01M4/36 , H01M4/62 , H01M4/525 , H01M4/131 , H01M4/505 , H01M4/1391 , H01M10/052
CPC分类号: H01M4/62 , H01M4/131 , H01M4/1391 , H01M4/366 , H01M4/505 , H01M4/525 , H01M4/623 , H01M10/052 , Y02E60/122 , Y10T29/49115 , Y10T428/3154
摘要: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a LiF layer, where this layer consists of a reaction product of a fluorine-containing polymer and the primary particle surface. The lithium of the LiF originates from the primary particles surface. Examples of the fluorine-containing polymer are either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCodMeO2, wherein M is either one of both of Mg and Ti, with e
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公开(公告)号:US09748570B2
公开(公告)日:2017-08-29
申请号:US14119924
申请日:2012-05-14
申请人: Randy De Palma , Jens Paulsen , JiHye Kim
发明人: Randy De Palma , Jens Paulsen , JiHye Kim
IPC分类号: H01M4/525 , H01M4/505 , H01M10/0525
CPC分类号: H01M4/525 , H01M4/505 , H01M10/0525
摘要: The invention relates to cathode materials for Li-ion batteries having a size dependent compositions. The lithium metal oxide powder has a general formula LiaNixCoyMnzM′mO2±eAf, with 0.9
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公开(公告)号:US09698418B2
公开(公告)日:2017-07-04
申请号:US13983596
申请日:2012-01-31
申请人: Jens Paulsen , JiHye Kim
发明人: Jens Paulsen , JiHye Kim
CPC分类号: H01M4/505 , C01D15/02 , C01G53/50 , C01P2002/54 , C01P2006/12 , H01M4/525 , H01M10/052 , H01M10/52
摘要: The invention relates to cathode materials for Li-ion batteries in the quaternary phase diagram Li[Li1/3Mn2/3]O2—LiMn1/2Ni1/2O2—LiNiO2—LiCoO2, and having a high nickel content. Also a method to manufacture these materials is disclosed. The cathode material has a general formula Lia ((Niz(Ni1/2Mn1/2)yCox)1−kAk)2−aO2, wherein x+y+z=1, 0.1≦x≦0.4, 0.36≦z≦0.50, A is a dopant, 0≦k≦0.1, and 0.95≦a≦1.05, and having a soluble base content (SBC) within 10% of the equilibrium soluble base content.
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